首页> 外文期刊>Journal of Surfactants and Detergents >Reaction between Zinc and Hydrochloric Acid in Solutions Containing Alkyltrimethylammonium Bromide Cn TAB (n?=?8, 10, and 12) Cationic Surfactants: Influence of Surfactant Chain Length

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Reaction between Zinc and Hydrochloric Acid in Solutions Containing Alkyltrimethylammonium Bromide Cn TAB (n?=?8, 10, and 12) Cationic Surfactants: Influence of Surfactant Chain Length

机译：含锌与盐酸在含有烷基三甲基溴化铵CN突片的溶液中的反应（n？=α8,10和12）阳离子表面活性剂：表面活性剂链长度的影响

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Abstract > The influence of C <sub>n</sub> TAB cationic surfactant chain length ( n ?=?8, 10, and 12) on the reaction rate of zinc powder and 0.1?M HCl hydrochloric acid in aqueous solutions was determined at room temperature. Solutions of single surfactants consisting of dodecyl, decyl, and octyl‐trimethyl‐ammonium bromide surfactants C <sub>n</sub> TAB were prepared at room temperature. From the surface tension and conductivity measurements, the critical micelle concentration (CMC) values of the three surfactants were obtained in the presence and absence of the acid. No significant change was observed for CMC values in pure water and in 0.01?M HCl. Adsorption of C <sub>n</sub> TAB surfactants onto 1% wt./vol zinc (in powder form), using surface tension measurements, was then investigated. The adsorption tendency of C <sub>n</sub> TAB surfactants onto zinc powder followed the order: C <sub>8</sub> TAB??C <sub>10</sub> TAB??C <sub>12</sub> TAB. The role of surfactants in the reaction rate between zinc powder and 0.1?M?M HCl was then investigated using conductivity measurements. A significant difference in the reaction rate was found depending on the surfactant chain length. Reaction times of 3830, 4963, 14,172, and 20,053?s were found for the zinc reaction with (0.1?M HCl), (0.1?M HCl?+?40?mM C <sub>8</sub> TAB), (0.1?M HCl?+?40?mM C <sub>10</sub> TAB), and (0.1?M HCl?+?40?mM C <sub>12</sub> TAB), respectively, suggesting a significant dependency of the reaction rate on the C <sub>n</sub> TAB chain length. Finally, some corrosion parameters such as the corrosion rate, corrosion inhibition efficiency, and their dependency on C <sub>n</sub> TAB chain length were presented and discussed. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > c的影响 <sub> n </ sub> 标签阳离子表面活性剂链长（ n </ i> 在室温下测定锌粉的反应速率，在室温下测定锌粉的反应速率和0.1μl盐酸中的0.1·m HCl盐酸。由十二烷基，癸基和辛基三甲基 - 溴化铵表面活性剂C组成的单表面活性剂的溶液 <sub> n </ sub> 在室温下制备标签。从表面张力和电导率测量，在存在和不存在酸的情况下获得三种表面活性剂的临界胶束浓度（CMC）值。纯水中的CMC值没有观察到显着变化，并在0.01μmHCl中。吸附C. <sub> n </ sub> 然后研究了使用表面张力测量的1％wt./vol锌（粉末形式）上的表面活性剂。 C的吸附趋势 <sub> n </ sub> 标签表面活性剂在锌粉上遵循订单：C <sub> 8 </ sub> 标签？＆？c <sub> 10 </ sub> 标签？＆？c <sub> 12 </ sub> 标签。然后使用电导测量研究表面活性剂在锌粉和0.1Ω·m≤MHCl之间的反应速率中的作用。根据表面活性剂链长度发现反应速率的显着差异。对锌反应（0.1ΩmHCl）的锌反应发现3830,4963,14,172和20,053℃的反应时间，（0.1≤MHCl+ +40Ω·mm c <sub> 8 </ sub> 标签），（0.1？M HCl？+？40？mm c <sub> 10 </ sub> 标签），（0.1？M HCl？+？40？mm C. <sub> 12 </ sub> 标签）分别表示对C对反应速率的显着依赖性 <sub> n </ sub> 标签链长度。最后，一些腐蚀参数，如腐蚀速率，腐蚀抑制效率及其对C的依赖性 <sub> n </ sub> 介绍和讨论了标签链长度。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35863/'>《Journal of Surfactants and Detergents》</a> <b style="margin: 0 2px;">|</b><span>2019年第4期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Altwaiq Abdelmnim M.&option=202" target="_blank" rel="nofollow">Altwaiq Abdelmnim M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abdel‐Rahem Rami A.&option=202" target="_blank" rel="nofollow">Abdel‐Rahem Rami A.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemistry College of arts and SciencesUniversity of PetraP.O. Box: 961343 Amman 11196 Jordan;</p> <p>Department of Chemistry College of arts and SciencesUniversity of PetraP.O. Box: 961343 Amman 11196 Jordan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4818.html" title="表面现象的物理化学">表面现象的物理化学;</a><a href="https://www.zhangqiaokeyan.com/clc/7878.html" title="表面活性剂">表面活性剂;</a><a href="https://www.zhangqiaokeyan.com/clc/1844.html" title="油脂和蜡的化学加工工业、肥皂工业">油脂和蜡的化学加工工业、肥皂工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cationic surfactants&option=203" rel="nofollow">Cationic surfactants;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Corrosion inhibition&option=203" rel="nofollow">Corrosion inhibition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Conductivity&option=203" rel="nofollow">Conductivity;</a> </p> <div class="translation"> 机译：阳离子表面活性剂;腐蚀抑制;电导率; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025864163.html">Reaction between Zinc and Hydrochloric Acid in Solutions Containing Alkyltrimethylammonium Bromide Cn TAB (n?=?8, 10, and 12) Cationic Surfactants: Influence of Surfactant Chain Length</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Altwaiq Abdelmnim M.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Altwaiq Abdelmnim M.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Abdel‐Rahem Rami A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Abdel‐Rahem Rami A. </a> <a href="/journal-foreign-35863/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Surfactants and Detergents .</a> <span>2019</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含锌与盐酸在含有烷基三甲基溴化铵CN突片的溶液中的反应（n？=α8,10和12）阳离子表面活性剂：表面活性剂链长度的影响</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704013860953.html">Micellar Parameters in Solutions with Cationic Surfactants and N,N-Dimethyldodecan-1-amine Oxide: Influence of Cationic Surfactant Chain Length</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rami A. 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href="/academic-journal-cn_acta-chimica-sinica_thesis/0201272179529.html">在十六烷基三甲基溴化铵(CTAB)溶液中水杨酸酯水解反应动力学研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=隋华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 隋华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李干佐&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李干佐</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨博&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨博</a> <span> <a href="/journal-cn-53859/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学学报 </a> </span> <span> . 2000</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-58793_thesis/020222554576.html">十六烷基三甲基溴化铵在0.5mol/LNaCl溶液中对铝合金阳极的阻化研究</a> <b>[C]</b> <span> <a 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</li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061203357796.html">利用十六烷基三甲基溴化铵和十二烷基三甲基溴化铵提高苹果中多酚氧化酶活性的方法</a> <b>[P]</b> . <span> 中国专利： CN105734025B </span> <span> . 2019.06.21</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120108213770.html">利用十六烷基三甲基溴化铵和十二烷基三甲基溴化铵提高苹果中多酚氧化酶活性的方法</a> <b>[P]</b> . <span> 中国专利： CN105734025A </span> <span> . 2016-07-06</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130419714717.html">METHOD FOR PRODUCING CRUDE OIL USING CATIONIC SURFACTANTS COMPRISING A HYDROPHOBIC BLOCK HAVING A CHAIN LENGTH OF 6 - 10 CARBON ATOMS</a> <b>[P]</b> . <span> 外国专利：  EP2544810A2 </span> <span> . 2013-01-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用阳离子表面活性剂生产粗油的方法，阳离子表面活性剂包含链长为6-10的碳原子的疏水性嵌段 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130421172000.html">Was used a cationic surfactant having a hydrophobic block having a chain length of 10 carbon atoms of six, a method for generation of a mineral oil</a> <b>[P]</b> . <span> 外国专利：  JP2013521122A </span> <span> . 2013-06-10</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用具有10个碳原子的碳原子数为6的疏水性嵌段的阳离子表面活性剂，矿物油的生成方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130420287644.html">METHOD FOR PRODUCING CRUDE OIL USING CATIONIC SURFACTANTS COMPRISING A HYDROPHOBIC BLOCK HAVING A CHAIN LENGTH OF 6 - 10 CARBON ATOMS.</a> <b>[P]</b> . <span> 外国专利：  MX2012010277A </span> <span> . 2012-11-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: 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