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首页> 外文期刊>Journal of Solid State Chemistry >A Zn-MOF with 8-fold interpenetrating structure constructed with N,N '-bis(4-carbozylbenzyl)-4-aminotoluene ligands, sensors and selective adsorption of dyes
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A Zn-MOF with 8-fold interpenetrating structure constructed with N,N '-bis(4-carbozylbenzyl)-4-aminotoluene ligands, sensors and selective adsorption of dyes

机译:具有8倍的互穿结构的Zn-MOF,其构成用N,N'-BIS(4-碳氮苄基)-4-氨基甲苯配体,传感器和选择性吸附染料

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摘要

A novel metal-organic framework {[Zn2L2(bibp)(2)]center dot H2O}(n) (L = N,N'-bis(4-carbozylbenzyl)-4-aminotoluene)(MOF 1) was synthesized and characterized, the structure presenting an 8-fold interpenetrating diamondoid networks with [4+4] mode, which exhibits high thermostability and two kinds of intertwined left- or right-handed double-helical chains. Additionally, the luminescence investigations reveal that 1 can sensitively detect Fe(III) ions in water. Furthermore, dye adsorption experiment results indicated that 1 can efficiently adsorb methyl orange(MO).
机译:合成并合成了一种新型金属 - 有机框架(Zn2L2(Bibp)(2)]中心点H2O}(N)(L = N,N'-Bis(4-碳氮苄基)-4-氨基甲苯)(MOF 1) ,呈现具有[4 + 4]模式的8倍的互穿的Diamondoid网络的结构,其表现出高热稳定性和两种交织的左或右手双螺旋链。 另外,发光调查显示,1可以敏感地检测水中的Fe(III)离子。 此外,染料吸附实验结果表明,1可以有效地吸附甲基橙(Mo)。

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