Synthesis and characterization of shale stabilizer based on polyethylene glycol grafted nano-silica composite in water-based drilling fluids

摘要

In order to solve wellbore instability problems in the drilling process, high-performance shale stabilizers in waterbased drilling fluids are essential. In this paper, a novel shale stabilizer based on polyethylene glycol grafted nanosilica composite (PEG-NS) was successfully synthesized. Conventional techniques were used to characterize PEGNS including Flourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), transmission electron microscopy (TEM), particle size distribution (PSD) and thermogravimetric analysis (TGA). The results showed that the structure of PEG-NS was in agreement with the design objective. The particle size of PEG-NS ranged from 110 to 434 nm, and PEG-NS had good thermal stability. Pressure transmission test, pore structure characterization of shale, rolling recovery test were applied to evaluate the comprehensive performance of PEGNS as a novel shale stabilizer. The experimental data indicated that PEG-NS could effectively retard the pore pressure transmission and reduce the permeability of shale sample. PEG-NS could adsorb onto the shale surface and a dense plugging film could finally coat on it. Moreover, PEG-NS also exhibited better inhibition performance compared with that of potassium chloride (KCl) and polymeric alcohol (JHC) at the same concentration. Hence, PEG-NS could be a good shale stabilizer in water-based drilling fluids for drilling reactive shale formations.