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Design of a novel co-electrospinning system with flat spinneret for producing helical nanofibers

机译:具有螺旋纳米纤维的扁平喷丝螺纹新型共电纺丝系统的设计

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A kind of biomimetic fibers of helical structures at nanoscale has attracted increasing interest. In this study, a novel co-electrospinning setup with a designed flat spinneret, used for the fabrication of helical nanofibers, is reported in this study. Poly(m-phenylene isophthalamide) (Nomex) and Thermoplastic polyurethane (TPU) are chosen as the two components in co-electrospinning. To display the efficiency for producing helical fibers, a generally used core-shell needle spinneret is used for comparison. The effect of the uniformity of electric field distribution created by these two types of spinnerets on the jet motion and the resultant helical fibers is developed, with systematical simulation and experimental research. The results showed that the co-electrospinning system with the newly designed flat spinneret can produce helical nanofibers efficiently. Compared with the needle spinneret, the flat spinneret created more uniform electric field, leading to better morphology and structure of the resultant helical fibers. In addition, an approach to achieve the scale-up of this co-electrospinning system is developed. This novel design is expected to provide a promising method to fabricate nanofiber materials with helical structures. (c) 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019
机译:纳米尺度螺旋结构的一种仿真纤维引起了越来越多的兴趣。在该研究中,在本研究中报道了一种用于制造螺旋纳米纤维的设计平坦喷丝器的新型共静纺丝设置。选择聚(M-亚苯基苯甲酸苯胺)(NOMEx)和热塑性聚氨酯(TPU)作为共同静电纺丝中的两个组分。为了显示螺旋纤维的生产效率,通常使用芯 - 壳针刺喷丝器进行比较。通过系统模拟和实验研究,开发了通过这两种类型的喷丝头产生的电场分布的均匀性的效果,具有系统模拟和实验研究。结果表明,具有新设计的扁平喷丝头的共电纺丝系统可以有效地产生螺旋型纳米纤维。与针纺纱机相比,扁平的喷丝网形成了更均匀的电场,导致所得螺旋纤维的更好的形态和结构。此外,开发了一种实现该共静电纺丝系统的扩展的方法。这种新颖的设计预计提供了一种具有螺旋结构的纳米纤维材料的有希望的方法。 (c)2019 Wiley期刊,Inc.J.Colom。 SCI。,B部分:聚合物。物理。 2019年

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