首页> 外文期刊>Journal of Physical Organic Chemistry >Reaction of glycine with glyoxylate: Competing transaminations, aldol reactions, and decarboxylations

【24h】

Reaction of glycine with glyoxylate: Competing transaminations, aldol reactions, and decarboxylations

机译：甘氨酸与乙醛酸甲酸盐的反应：竞争剪突，醛醇反应和脱羧

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract > The reactions of glycine, a simple amino acid, with glyoxylate, a simple α‐oxocarboxylate, were investigated in water as a function of time, pH, and temperature and followed using a combination of quantitative 13 C nuclear magnetic resonance and high‐resolution mass spectrometry. Three sets of experiments are reported: (1) reaction of 13 C‐labeled glycine with unlabeled glyoxylate, (2) reaction of unlabeled glycine with 13 C‐labeled glyoxylate, and (3) the reaction of 13 C‐labeled glycine with 13 C‐labeled glyoxylate. Competing transaminations, aldol reactions, and decarboxylations were observed; the mechanistic description for each of these processes is presented. 3‐Hydroxy‐2‐aminosuccinate, a product of reaction between glycine and glyoxylate, was shown to promote both the decarboxylation of glyoxylate and transamination of glyoxylate to glycine. These observations may have implications for the mechanism of attenuation of ethylene glycol toxicity. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract type =“main”xml：lang =“en”> <标题类型=“main”>摘录</标题> >甘氨酸，一个简单的氨基酸，用乙醛酸，简单的α-氧化羧酸盐，作为时间，pH和温度的函数在水中进行研究，然后使用定量 13-sup> c核磁共振和高分辨率质谱法的组合。报道了三组实验：（1） 13 + C-标记的甘油的反应，其中未标记的乙酰甲磺酸盐，（2）与 13-sup> c-标记的乙醛酸甲酸酯，和（3）用 13-sup> C-标记的乙醛酸甲磺酸甲酸酯的甘油混合物的反应。观察到竞争的映敏，醛醇反应和脱羧;提出了每个过程的机械描述。 3-羟基-2-氨基琥珀酸盐，显示甘氨酸和乙醛酸甲酸盐之间的反应产物，以促进乙醛酸甲磺酸盐的脱羧和乙醛酰化到甘氨酸中的脱羧。这些观察结果可能对乙二醇毒性衰减的机制有影响。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-35546/'>《Journal of Physical Organic Chemistry》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Conley Mark&option=202" target="_blank" rel="nofollow">Conley Mark;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mojica Mike&option=202" target="_blank" rel="nofollow">Mojica Mike;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mohammed Fiaz&option=202" target="_blank" rel="nofollow">Mohammed Fiaz;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Ke&option=202" target="_blank" rel="nofollow">Chen Ke;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Napoline Jonathan W.&option=202" target="_blank" rel="nofollow">Napoline Jonathan W.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pollet Pamela&option=202" target="_blank" rel="nofollow">Pollet Pamela;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Jing&option=202" target="_blank" rel="nofollow">Wang Jing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Krishnamurthy Ramanarayanan&option=202" target="_blank" rel="nofollow">Krishnamurthy Ramanarayanan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liotta Charles L.&option=202" target="_blank" rel="nofollow">Liotta Charles L.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>School of Chemical and Biomolecular EngineeringGeorgia Institute of TechnologyAtlanta GA 30332 USA;</p> <p>School of Chemistry and BiochemistryGeorgia Institute of TechnologyAtlanta GA 30332 USA;</p> <p>School of Chemical and Biomolecular EngineeringGeorgia Institute of TechnologyAtlanta GA 30332 USA;</p> <p>School of Chemistry and BiochemistryGeorgia Institute of TechnologyAtlanta GA 30332 USA;</p> <p>School of Chemistry and BiochemistryGeorgia Institute of TechnologyAtlanta GA 30332 USA;</p> <p>School of Chemistry and BiochemistryGeorgia Institute of TechnologyAtlanta GA 30332 USA;</p> <p>Department of Chemistry and BiochemistryJackson State UniversityJackson MS 39217 USA;</p> <p>Department of ChemistryThe Scripps Research InstituteLa Jolla CA 92037 USA;</p> <p>School of Chemistry and BiochemistryGeorgia Institute of TechnologyAtlanta GA 30332 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4796.html" title="有机化学一般性问题">有机化学一般性问题;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=aldol reaction&option=203" rel="nofollow">aldol reaction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=decarboxylation&option=203" rel="nofollow">decarboxylation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=transamination&option=203" rel="nofollow">transamination;</a> </p> <div class="translation"> 机译：醛醇反应;脱羧;崩解; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025793522.html">Reaction of glycine with glyoxylate: Competing transaminations, aldol reactions, and decarboxylations</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Conley Mark&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Conley Mark,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mojica Mike&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mojica Mike,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mohammed Fiaz&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mohammed Fiaz,</a> <a href="/journal-foreign-35546/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Physical Organic Chemistry .</a> <span>2017</span><span>,第12期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：甘氨酸与乙醛酸甲酸盐的反应：竞争剪突，醛醇反应和脱羧</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019022600.html">Synthetic utility of bowl-shaped tris(2,6-diphenylbenzyl)silyl glyoxylate as a stable glyoxylate: application to highly diastereoselective aldol reactions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Seiji Shirakawa&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Seiji Shirakawa,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Keiji Maruoka&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Keiji Maruoka </a> <a href="/journal-foreign-30441/" target="_blank" rel="nofollow" class="tuijian_authcolor">Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry .</a> <span>2003</span><span>,第2期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：碗形三（2,6-二苯基苄基）甲硅烷基乙氧基化物的合成实用性：在高度非对映选择性醛醇缩合反应中的应用</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704015202692.html">pH-controlled reaction divergence of decarboxylation versus fragmentation in reactions of dihydroxyfumarate with glyoxylate and formaldehyde: parallels to biological pathways</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Butch Christopher J.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Butch Christopher J.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Jing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Jing,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gu Jiande&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gu Jiande,</a> <a href="/journal-foreign-35546/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Physical Organic Chemistry .</a> <span>2016</span><span>,第7期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在二羟基富马酸酯与乙醛酸酯和甲醛的反应中，pH控制的脱羧与片段化反应差异：与生物途径相似</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-279020_thesis/0705016086509.html">MECHANISTIC INVESTIGATION INTO THE DECARBOXYLATION OF AROMATIC CARBOXYLIC ACIDS AND THEIR ROLE IN RETROGRESSIVE REACTIONS</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Phillip F. Britt&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Phillip F. Britt,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=A. C. Buchanan III&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">A. C. Buchanan III </a> <a href="/conference-foreign-279020/" target="_blank" rel="nofollow" class="tuijian_authcolor">National Meeting Exhibition .</a> <span>2012</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：芳族羧酸脱羧及其在倒退反应中的作用的机械研究及其作用</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061657225.html">I. Catalytic redox-initiated glycolate aldol additions of silyl glyoxylates. II. Diastereoselective de novo synthesis of pentasubstituted γ-butyrolactones from silyl glyoxylates and ketones via double Reformatsky reactions. III. Progress toward the total synthesis of leustroducsin B</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Greszler, Stephen Nathaniel&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Greszler, Stephen Nathaniel </a> <span>2010</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：I.甲硅烷基乙醛酸酯的催化氧化还原引发的乙醇酸酯醛醇加成物。二。通过双重Reformatsky反应从甲硅烷基乙醛酸酯和酮进行非对映选择性从头合成五取代的γ-丁内酯。三，全合成杜鹃花素B的研究进展</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040005967703.html">One-pot Synthesis of Lactams Using Domino Reactions: Combination of Schmidt Reaction with Sakurai and Aldol Reactions</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chan Woo Huh&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chan Woo Huh,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gagandeep K. Somal&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gagandeep K. Somal,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Christopher E. Katz&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Christopher E. Katz,</a> <span>-1</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用多米诺反应的内酰胺的单壶合成：Schmidt与Sakurai和Aldol反应的组合</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100062008639.html">ALDOL REACTIONS OF UNSUBSTITUTED β-LACTAMS. STUDIES OF A β-GLYCINE ENOLATE EQUIVALENT†</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=David R. Williams&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">David R. Williams,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Andrew F. Donnell&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Andrew F. Donnell,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=David C. Kammler&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">David C. Kammler </a> <span>2015</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：未取代的β-内酰胺的aLDOL反应。 β-GLYCINE ENOLaTE等效研究†</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_physical-testing-chemical-analysis-part-bchemical-analysis_thesis/0201212573476.html">离子色谱法测定氧气氧化乙二醛制备乙醛酸反应介质中乙醛酸和甲酸</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=牛宇岚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 牛宇岚</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李瑞丰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李瑞丰</a> <span> <a href="/journal-cn-7677/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 理化检验-化学分册 </a> </span> <span> . 2009</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangzhou-chemical-industry_thesis/0201280177821.html">金催化剂催化乙二醛制乙醛酸反应条件的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王晓莉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王晓莉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=包双成&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,包双成</a> <span> <a href="/journal-cn-9125/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广州化工 </a> </span> <span> . 2020</span><span>,第020期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-nanjing-tech-university-natural-science-edition_thesis/0201210038647.html">微反应器中硝酸氧化乙二醛制备乙醛酸</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王超&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王超</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=邓秋林&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,邓秋林</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈超&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈超</a> <span> <a href="/journal-cn-7573/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 南京工业大学学报（自然科学版） </a> </span> <span> . 2018</span><span>,第001期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_shandong-chemical-industry_thesis/0201247951198.html">乙二醛催化氧化反应萃取制备乙醛酸的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=华静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 华静</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘少文&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘少文</a> <span> <a href="/journal-cn-9186/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 山东化工 </a> </span> <span> . 2018</span><span>,第011期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangdong-chemical-industry_thesis/0201246311089.html">乙二醛合成乙醛酸反应条件探讨</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王文生&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王文生</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘涛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=付建&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,付建</a> <span> <a href="/journal-cn-9122/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东化工 </a> </span> <span> . 2017</span><span>,第020期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-19643_thesis/020222262620.html">丙烯醛水合制1，3-丙二醇的反应本征动力学研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=原宇航&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 原宇航</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵志宏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵志宏</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周柳茵&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,周柳茵</a> <span> <a href="/conference-cn-19643/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化工学会精细化工专业委员会第111次学术会议、第九届丙烯酸科技发展与应用研讨会暨全国丙烯酸行业年会 </a> <span> <span> . 2008</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314938873.html">水相中酰胺与醛的氧化酰化反应及α-羰基羧酸的脱羧酰化偶联反应的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨春&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨春</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120105678975.html">在苏氨酸醛缩酶和脱羧酶的存在下由甘氨酸和醛出发制备对映异构富集的β－氨基醇的方法</a> <b>[P]</b> . <span> 中国专利： CN101473039A </span> <span> . 2009-07-01</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061202001780.html">从含乙醛酸和乙二醛的水性反应介质中分离乙醛酸的方法</a> <b>[P]</b> . <span> 中国专利： CN103896760B </span> <span> . 2016.04.13</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130409451235.html">retro-aldol reaction product, and, method for producing a retro-aldol reaction product</a> <b>[P]</b> . <span> 外国专利：  BR112015021778A2 </span> <span> . 2017-07-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：逆醛醇缩合反应产物，以及制备逆醛醇缩合反应产物的方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130430520082.html">Reagents for asymmetric allylation, aldol, and tandem aldol and allyation reactions</a> <b>[P]</b> . <span> 外国专利：  US7534905B2 </span> <span> . 2009-05-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于不对称烯丙基化，羟醛和串联羟醛和烯丙基化反应的试剂 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130437222842.html">REAGENTS FOR ASYMMETRIC ALLYLATION, ALDOL, AND TANDEM ALDOL AND ALLYLATION REACTIONS</a> <b>[P]</b> . <span> 外国专利：  EP1480988A4 </span> <span> . 2006-03-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：不对称烯丙基化，ALDOL和串联ALDOL和烯丙基化反应的试剂 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704025793522','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);">回到顶部</a> </li> <li class="shouye"> <a href="/">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html">关于掌桥</a></li> <li><a href="/help/helpmap.html">资源导航</a></li> <li><a href="/help/helpguide.html">新手指南</a></li> <li><a href="/help/helpcenter.html">常见问题</a></li> <li><a href="/sitemap.html">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704025793522down" data-source="7," data-out-id="h3UGQxWvLTP3Dv3stFn6M/C/zBSZX9443/ClGBtUvLdjcdkrsNXwENDNsIE5v1Eq," data-f-source-id="7" data-title="Reaction of glycine with glyoxylate: Competing transaminations, aldol reactions, and decarboxylations" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="35546" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Reaction of glycine with glyoxylate: Competing transaminations, aldol reactions, and decarboxylations"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.7"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>