Occurrence features and gas content analysis of marine and continental shales: A comparative study of Longmaxi Formation and Yanchang Formation

摘要

To study the occurrence state and content of shale gas in different depositional environments, 15 marine shale samples from Longmaxi Formation in the Sichuan Basin and 15 continental shale samples from Yanchang Formation in the Ordos Basin were sampled. Then a series of experiments, including X-ray diffraction analysis, TOC content analysis, R-o measurement, NMR measurements, FE-ESEM observation, low-pressure N-2 adsorption, and CH4 isothermal adsorption were conducted. In general, shale gas in Yanchang formation has the characteristics of primary adsorbed gas, moderate free gas, and non-ignorable dissolved gas, whereas shale gas in Longmaxi formation has the characteristics of joint dominated free gas and adsorbed gas, as well as negligible dissolved gas. Both macroscopic accumulation pattern and microscopic occurrence model show four stages in the whole thermal evolution, that is, adsorption, pore filling, fracture filling and accumulation. By analyzing the affecting factors of shale gas adsorption, conclusions can be drawn that geological characteristics, mineral compositions, pore structure features and formation conditions have influence on adsorbed gas content to various degrees. Cause analyses reveal that differences in occurrence state and gas content between marine and continental shales are immediately affected by the differences of organic matter type, thermal maturity, brittle minerals content, carbonate content, SSA, PD, porosity, gas saturation, residual oil quantity, as well as T&P, indirectly controlled by sedimentary environment and tectonic movement.