Synthesis, optical properties and application of Y7O6F9:Er3+ for sensing the chip temperature of a light emitting diode

摘要

Submicron-sized Er3+ doped Y7O6F9 phosphors were synthesized via the precipitation method and a subsequent annealing process. The influence of the Er3+ doping concentrations and the heating temperature on the luminescence of Y7O6F9:Er3+ was investigated under the excitation of the Er(3+ 4)G(11/2) level at 378 nm. Upon raising the Er3+ doping concentration, both the intensity and lifetime of the Er3+ green emission at 547 nm originating from S-4(3/2) I-4(15/2) decrease, which is proved to be caused by energy transfer via cross relaxation between two neighboring Er3+ ions. The thermal sensing properties of Y7O6F9:Er3+ were evaluated using the temperature dependent intensity ratio between the H-2(11/2)-I-4(15/2) and S-4(3/2)-I-4(15/2) transitions of Er3+ under 378 nm excitation. The experimental results show that the thermal sensitivity decreased with an increase in the Er3+ doping content, which is caused by the increased energy transfer probability among Er3+. The increased energy transfer of Er3+ reduces the thermalized population of Er3+ in the H-2(11/2) levels, which in turn decreases the thermal sensitivity. The applicability of Er3+ doped Y7O6F9 as a thermal sensor was demonstrated by measuring the chip temperature of a 1 W InGaN type near-ultraviolet light emitting diode (n-UV LED).