Preparation and spectroscopic study of 1:2 adducts of dimethyltin(IV)dichloride with aromatic N-oxides (IQNO, 4-CIQNO, 4-MeQNO, 6-MeOQNO and 4-PhPyNO). Crystal and molecular structure of trans-dichlorodimethyl bis(4-phenylpyridine-N-oxide)TiN(IV)

H.Papadaki; J.C.Jeffery

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Preparation and spectroscopic study of 1:2 adducts of dimethyltin(IV)dichloride with aromatic N-oxides (IQNO, 4-CIQNO, 4-MeQNO, 6-MeOQNO and 4-PhPyNO). Crystal and molecular structure of trans-dichlorodimethyl bis(4-phenylpyridine-N-oxide)TiN(IV)

机译：用芳族N-氧化物（IQNO，4-CIQNO，4-MEQNO，6-MEOQNO和4-PHPYNO）的1：2二甲基锡（IV）二氯乙烯加合物的制备和光谱研究。反式二氯二甲基双（4-苯基吡啶-N-氧化物）锡（IV）的晶体和分子结构

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Five adducts of general formula Me_2SnCl_2L_2[L=IQNO(isoquinoline-N-oxide), 4-CIQNO, 4-MeQNO, 6-MeOQNO (6-methoxyquinoline-N-oxide) and 4-PhPyNO (4-Phenylpyridine-N-oxide)] have been prepared by the addition of Lto chloroform solutions of Me_2SnCl_2. The adducts have beencharacterized by analysis and spectroscopic (IR, ~(1)H, ~(13)C andMossbauer) data. Structural predictions were derived from~(119)Sn NMR parameters such as ~(1)J(~(119)Sn-~(13)C) and~(2)J(~(119)Sn-~(1)H). The single crystal diffraction study of thadduct Me_2SnCl_2(4-PhPyNO)_2 shows the metal to be six-coordinate in an all trans-octahedral configurations; Sn-O and Sn-Cl distances are 2.227(2) and 2.5774(9) A, respectively, and theCH_3-Sn-CH_3 bond angle is 180.0beg.

机译：通式ME_2SNCL_2L_2 [L = IQNO（异喹啉-N-氧化物），4-CIQNO，4-MEQNO，6-MEOQNO（6-甲氧基喹啉-N氧化物）和4-PHPYNO（4-苯基吡啶-N-氧化物）]通过加入LTO氯仿溶液的ME_2SNCL_2制备。通过分析和光谱（IR，〜（1）H，〜（13）C和MOSSBauer）数据已经进行了比较。结构预测来自〜（119）Sn NMR参数，例如〜（1）J（〜（119）Sn-（13）c）和〜（2）j（〜（119）sn-（1）h ）。 Thadduct Me_2sncl_2（4-phpyno）_2的单晶衍射研究显示金属在所有反式八面体配置中为六个坐标; SN-O和SN-CL距离分别为2.227（2）和2.5774（9）A，并且TheCh_3-SN-CH_3键合角为180.0beg。

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《Journal of Coordination Chemistry》 |1999年第4期|共14页
作者
H.Papadaki; J.C.Jeffery;
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正文语种 eng
中图分类无机化学;
关键词
Crystal structure; quinoline-N-oxide; 4-phenylpyridine-N-oxide;

机译：晶体结构;喹啉-N-氧化物;4-苯基吡啶-N-氧化物;

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1. Preparation and spectroscopic study of 1:2 adducts of dimethyltin(IV)dichloride with aromatic N-oxides (IQNO, 4-CIQNO, 4-MeQNO, 6-MeOQNO and 4-PhPyNO). Crystal and molecular structure of trans-dichlorodimethyl bis(4-phenylpyridine-N-oxide)TiN(IV) [J] . H.Papadaki, J.C.Jeffery Journal of Coordination Chemistry . 1999,第4期

机译：用芳族N-氧化物（IQNO，4-CIQNO，4-MEQNO，6-MEOQNO和4-PHPYNO）的1：2二甲基锡（IV）二氯乙烯加合物的制备和光谱研究。反式二氯二甲基双（4-苯基吡啶-N-氧化物）锡（IV）的晶体和分子结构
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3. Synthesis and thermodynamic studies of the dinuclear adducts between dimethyltin(IV) dichloride with SalenH₂ and MII(Salen) complexes in chloroform [J] . Mozaffar Asadia* Khosrow Aein Jamshida amp, Ali Hossein Kyanfarb Journal of Co-ordination Chemistry . 2008,第7期

机译：二氯二甲基锡（IV）与SalenH _{2 和M II （Salen）络合物在氯仿中的二核加合物的合成和热力学研究}
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机译：双NN-双（2-甲氧基乙基）基）二硫代氨基甲酸酯-κ2的不同配位几何SS二苯基锡（IV）和双 N-（2-甲氧基乙基）-N-甲基二硫氨基甲酸酯-κ2SS diphenyltin（IV）：晶体结构和Hirshfeld表面分析
6. Different coordination modes for disulfoxides towards diorganotin(IV) dichlorides. X-ray crystal structures of 1,2-cis-bis-(phenylsulfinyl)ethene (rac-,cis-cbpse) and adducts [{Ph2SnCl2(meso-bpse)}n] and [{n-Bu2SnCl2(pdtd)}2] [O] . SOUSA, Gerimário F. de, ELLENA, Javier, MALTA, Valéria R. S., 2009

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Preparation and spectroscopic study of 1:2 adducts of dimethyltin(IV)dichloride with aromatic N-oxides (IQNO, 4-CIQNO, 4-MeQNO, 6-MeOQNO and 4-PhPyNO). Crystal and molecular structure of trans-dichlorodimethyl bis(4-phenylpyridine-N-oxide)TiN(IV)

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