Synthesis of graphene oxide/metal–organic frameworks hybrid materials for enhanced removal of Methylene blue in acidic and alkaline solutions

Zhao Shuaiqi; Chen Ding; Wei Fuhua; Chen Nini; Liang Zhao; Luo Yun

摘要

Abstract <section xml:id="jctb5419-sec-0001" numbered="no"> <title type="main">BACKGROUND >Dye wastewater is causing a serious problem to the environment and to human health. A considerable amount of colored wastewater is generated from many industries. Moreover, many dyes in the wastewater are believed to be toxic and even carcinogenic. Therefore, the removal of dyes from wastewater is necessary and urgent. </section> <section xml:id="jctb5419-sec-0002" numbered="no"> <title type="main">RESULTS > The adsorption kinetics, isotherms and intra‐particle diffusion model were determined from experimental data, and the results indicated that the pseudo‐second‐order kinetic model and the Langmuir adsorption isotherm matched well the adsorption of MB onto GO/MOFs. Thermodynamic parameters revealed that the adsorption of MB by GO/MOFs was spontaneous and exothermic. The adsorption capacity was greatly improved in acidic or alkaline aqueous solution. The maximum adsorption capacity of GO/MOFs reached 274?mg g ‐1 , higher than most previously reported adsorbents. Also, the adsorbent could be used at least five times after washing with ethanol. </section> <section xml:id="jctb5419-sec-0003" numbered="no"> <title type="main">CONCLUSION >A microwave‐assisted ball milling method was used successfully to synthesize Ni‐MOFs and GO/MOFs. Because of electrostatic interaction and acid–base interaction, both acidic and alkaline aqueous solutions were found to favor the adsorption of MB by GO/MOFs, this being different from previous reports. GO/MOFs also showed acceptable reusability after being regenerated by ethanol. All the results suggest that MOFs prepared by microwave‐assisted ball </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <title type =“main”>抽象</ title> <section XML：ID =“JCTB5419-SEC-0001”编号=“否”> <标题类型=“main”>背景</标题> >染料废水导致环境和人类健康的严重问题。许多行业产生了相当数量的彩色废水。此外，许多废水中的许多染料被认为是有毒的甚至致癌性。因此，需要从废水中取出染料，是必要的和迫切的。</ p> </ section> <章节XML：ID =“JCTB5419-SEC-0002”编号=“否”> <标题类型=“main”>结果< /标题> >吸附动力学，等温线和粒子崩解模型是从实验数据确定的，结果表明，伪二阶动力学模型和朗米尔吸附等温线匹配了MB对去/的吸附/ mofs。热力学参数显示，GO / MOF的MB吸附是自发性和放热的。酸性或碱性水溶液中的吸附能力大大提高。 Go / Mofs的最大吸附能力达到274×mg g -1 </ sup>，高于大多数先前报告的吸附剂。而且，吸附剂可以在用乙醇洗涤后至少五次使用。 </ p> </段> <部分XML：ID =“JCTB5419-SEC-0003”编号=“否”> <标题类型=“main”>结论</标题> >微波辅助球铣削方法已成功用于合成Ni-Mofs和Go / Mofs。由于静电相互作用和酸碱相互作用，发现酸性和碱性水溶液均有利于通过去/ MOF吸附MB，这与先前的报道不同。在被乙醇再生后，GO / MOF也显示出可接受的可重用性。所有结果表明，MOF由微波辅助球制备 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-33908/'>《Journal of Chemical Technology & Biotechnology》</a> <b style="margin: 0 2px;">|</b><span>2018年第3期</span><b style="margin: 0 2px;">|</b><span>共12页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Shuaiqi&option=202" target="_blank" rel="nofollow">Zhao Shuaiqi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Ding&option=202" target="_blank" rel="nofollow">Chen Ding;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wei Fuhua&option=202" target="_blank" rel="nofollow">Wei Fuhua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Nini&option=202" target="_blank" rel="nofollow">Chen Nini;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liang Zhao&option=202" target="_blank" rel="nofollow">Liang Zhao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Luo Yun&option=202" target="_blank" rel="nofollow">Luo Yun;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>College of Materials Science and EngineeringHunan UniversityChangsha China;</p> <p>College of Materials Science and EngineeringHunan UniversityChangsha China;</p> <p>College of Materials Science and EngineeringHunan UniversityChangsha China;</p> <p>College of Materials Science and EngineeringHunan UniversityChangsha China;</p> <p>College of Materials Science and EngineeringHunan UniversityChangsha China;</p> <p>College of Materials Science and EngineeringHunan UniversityChangsha China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/180.html" title="生物工程学（生物技术）">生物工程学（生物技术）;</a><a href="https://www.zhangqiaokeyan.com/clc/20827.html" title="生物化学过程">生物化学过程;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=adsorption&option=203" rel="nofollow">adsorption;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=methylene blue&option=203" rel="nofollow">methylene blue;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=microwave‐assisted ball milling&option=203" rel="nofollow">microwave‐assisted ball milling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=metal–organic frameworks&option=203" rel="nofollow">metal–organic frameworks;</a> </p> <div class="translation"> 机译：吸附;亚甲基蓝色;微波辅助球磨;金属 - 有机框架; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025422810.html">Synthesis of graphene oxide/metal–organic frameworks hybrid materials for enhanced removal of Methylene blue in acidic and alkaline solutions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Shuaiqi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhao Shuaiqi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Ding&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen Ding,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wei Fuhua&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wei Fuhua,</a> <a href="/journal-foreign-33908/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Chemical Technology & Biotechnology .</a> <span>2018</span><span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：石墨烯氧化物/金属 - 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