PALLADIUM-CATALYZED ASYMMETRIC HALOIMINOLACTONIZATION OF alpha-ALLYLMALONAMIDES

Kuriyama Masami; Yamamoto Kosuke; Ishimaru Keiko; Fujimura Noriyuki; Minato Daishiro; Onomura Osamu

首页> 外文期刊>Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry >PALLADIUM-CATALYZED ASYMMETRIC HALOIMINOLACTONIZATION OF alpha-ALLYLMALONAMIDES

【24h】

PALLADIUM-CATALYZED ASYMMETRIC HALOIMINOLACTONIZATION OF alpha-ALLYLMALONAMIDES

机译：钯催化的α-烯丙基酰胺的不对称卤素酰胺化

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A catalyst composed of 10 mol% of Pd(OAc)(2) and (R,R)-PhBox was proven to be effective in the asymmetric haloiminolactonization of alpha-allylmalon-amides with N-halosuccinimides, giving the dihalogenated cyclic products with good diastereomeric ratio (up to 89/11) and enantiomeric excess (up to 72% ee).

机译：已证明由10摩尔％的Pd（OAC）（2）（2）和（R）和（R，R）-Hbox组成的催化剂在α-烯丙基酰胺与N-卤素琥珀酰亚胺的不对称卤素酰胺化中有效，使二卤化环状产物具有良好非对映异构率（高达89/11）和对映体过量（高达72％）。

著录项

来源
《Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry》 |2018年第2期|共11页
作者
Kuriyama Masami; Yamamoto Kosuke; Ishimaru Keiko; Fujimura Noriyuki; Minato Daishiro; Onomura Osamu;
展开▼
作者单位

Nagasaki Univ Grad Sch Biomed Sci Nagasaki 8528521 Japan;

Nagasaki Univ Grad Sch Biomed Sci Nagasaki 8528521 Japan;

Nagasaki Univ Grad Sch Biomed Sci Nagasaki 8528521 Japan;

Nagasaki Univ Grad Sch Biomed Sci Nagasaki 8528521 Japan;

Nagasaki Univ Grad Sch Biomed Sci Nagasaki 8528521 Japan;

Nagasaki Univ Grad Sch Biomed Sci Nagasaki 8528521 Japan;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. PALLADIUM-CATALYZED ASYMMETRIC HALOIMINOLACTONIZATION OF alpha-ALLYLMALONAMIDES [J] . Kuriyama Masami, Yamamoto Kosuke, Ishimaru Keiko, Heterocycles: An International Journal for Reviews and Communications in Heterocyclic Chemistry . 2018,第2期

机译：钯催化的α-烯丙基酰胺的不对称卤素酰胺化
2. Novel Chiral Ligands for Palladium-catalyzed Asymmetric Allylic Alkylation/Asymmetric Tsuji-Trost Reaction: A Review [J] . Noreen Samar, Zahoor Ameer Fawad, Ahmad Sajjad, Current organic chemistry . 2019,第11期

机译：新型手性配体用于钯催化的不对称烯丙基烷基化/不对称Tsuji-Trost反应：综述
3. Kinetic Resolution of 2?Substituted 2,3-Dihydro-4-pyridones by Palladium-Catalyzed Asymmetric Allylic Alkylation: Catalytic Asymmetric Total Synthesis of Indolizidine (-)-209I [J] . Shunpei Nobusue, Hiroshi Yamane, Hirokazu Miyoshi, Organic letters . 2014,第7期

机译：钯催化的不对称烯丙基烷基化反应2？取代的2,3-二氢-4-吡啶酮的动力学拆分：吲哚并咪唑（-）-209I的催化不对称全合成
4. Synthesis of Optically Active Spiro Compounds via Palladium-catalyzed Asymmetric Amidation [C] . Kazuhiro Takenaka, Noriyuki Itoh, Hiroaki Sasai Symposium on Organometallic Chemistry . 2007

机译：通过钯催化的不对称扫描合成光学活性螺旋化合物
5. Design and synthesis of novel chiral arsines for asymmetric Wittig reactions and palladium-catalyzed asymmetric allylic alkylation and asymmetric Heck reactions. [D] . Wu, Huafeng. 2004

机译：设计和合成用于不对称Wittig反应和钯催化的不对称烯丙基烷基化和不对称Heck反应的新型手性ral。
6. Palladium-Catalyzed Asymmetric Ring Expansion of Allenylcyclobutanols: An Asymmetric Wagner-Meerwein Shift [O] . Barry M. Trost, Jia Xie -1

机译：钯催化的烯基环丁醇的不对称环扩环：不对称的Wagner-Meerwein位移
7. Asymmetric Induction Reactions. VII. Palladium-Catalyzed Asymmetric Sulfonylations of alpha;, gamma;-Disubstituted Allylic Acetates with Chiral Phosphine Ligands [O] . Kazushige HIRASAWA, Masatoshi KAWAMATA, Kunio HIROI 1994

机译：不对称感应反应。 VII。钯催化α，γ-二取代的烯丙基醋酸乙酸乙酸乙酸钯催化的不对称硫酸盐

PALLADIUM-CATALYZED ASYMMETRIC HALOIMINOLACTONIZATION OF alpha-ALLYLMALONAMIDES

摘要

著录项

相似文献

相关主题

期刊订阅