Preparation of high purity zinc from zinc oxide ore by vacuum carbothermic reduction

摘要

AbstractEffects of the yield and quality of Zn were investigated by vacuum carbothermic reduction from zinc oxide ore. Results indicate that initial moles ratio of C/ZnTotal, pressure of system, reaction time affect significantly the Zn yield from zinc oxide ore, while sintering temperature and sintering time have important influences on the quality of Zn. The optimal operating conditions are obtained as follows: the sintering temperature 973?K, the sintering time 50?min, the molar ratio of C/ZnTotal2.5, the reaction temperature 1173?K, the pressure system lower than 20?kPa, the reaction time 50?min. Under the optimal conditions, the yield and purity of Zn are more than 95% and 99.995% respectively, suggesting the vacuum carbothermic reduction is a promising method to extract high-purity zinc from zinc oxide ore.Highlights?Preparing high-purity zinc from zinc oxide ore by vacuum carbothermic reduction in an experimental setup designed by ourselves with classification condensation.?The reaction temperature is 1173?K which is 150–350°C lower than that