Recent Advances in the Buchwald-Hartwig Amination Reaction Enabled by the Application of Sterically Demanding Phosphine Ancillary Ligands

Rylan J. Lundgren; Mark Stradiotto

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Recent Advances in the Buchwald-Hartwig Amination Reaction Enabled by the Application of Sterically Demanding Phosphine Ancillary Ligands

机译：应用立体要求的膦辅助配体实现布赫瓦尔德-哈特维格胺胺化反应的最新进展

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This review highlights a selection of important recent developments in the catalysis of the Buchwald-Hartwig amination reaction. These developments have been enabled through the use of sterically demanding phosphine ancillary ligands. Our aim is to inform the reader of recent methodology advances, and to encourage further development and understanding within the field of ancillary ligand design.

机译：这篇综述着重介绍了布赫瓦尔德-哈特维格胺胺化反应催化的近期重要进展。通过使用空间要求严格的膦辅助配体，可以实现这些发展。我们的目的是向读者介绍最新的方法学进展，并鼓励在辅助配体设计领域内的进一步发展和理解。

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《Aldrichimica acta 》 |2012年第3期| 共7页
作者
Rylan J. Lundgren; Mark Stradiotto;
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正文语种 eng
中图分类有机化学 ;
关键词
amination; catalysis; cross-coupling; ligand design; palladium.;

机译：胺化;催化;交叉偶联;配体设计;钯;

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1. Recent Advances in the Buchwald-Hartwig Amination Reaction Enabled by the Application of Sterically Demanding Phosphine Ancillary Ligands [J] . Rylan J. Lundgren, Mark Stradiotto Aldrichimica acta . 2012 ,第3期

机译：应用立体要求的膦辅助配体实现布赫瓦尔德-哈特维格胺胺化反应的最新进展
2. Trineopentylphosphine: A conformationally flexible ligand for the coupling of sterically demanding substrates in the Buchwald-Hartwig amination and suzuki-miyaura reaction [J] . Raders S.M., Moore J.N., Parks J.K., The Journal of Organic Chemistry . 2013 ,第10期

机译：Trineopentylphosphine：一种构象灵活的配体，用于在Buchwald-Hartwig胺化和Suzuki-miyaura反应中耦合空间要求性底物
3. Air-stable and highly efficient indenyl-derived phosphine ligand: Application to Buchwald-Hartwig amination reactions [J] . Xiaowei Hao, Jia Yuan, Guang-Ao Yu, Journal of Organometallic Chemistry . 2012 ,第Null期

机译：空气稳定且高效的茚基膦配体：在布赫瓦尔德-哈特维格胺胺化反应中的应用
4. Ruthenocenyl Phosphine Designed as Novel Class of Phosphine-Arene Ligand: Application to Suzuki-Miyaura Reaction of Electronically and Sterically Deactivated Aryl Halides with Aryl Boronic Acids [C] . Takashi Hoshi, Taichi Nakazawa, Toshio Suzuki Symposium on Organometallic Chemistry . 2006

机译：设计为新型膦 - 芳烃配体的钌烯基膦：用芳族硼酸的电子和空间去激活的芳基卤化物的铃木 - 咪糕的反应应用
5. Synthesis and application of sterically flexible and water-soluble phosphine ligands in palladium catalysis. [D] . Moore, Jane Nathanielle. 2014

机译：空间柔性和水溶性膦配体的合成及在钯催化中的应用。
6. Enhanced quantum yields by sterically demanding aryl-substituted β-diketonate ancillary ligands [O] . Rebecca Pittkowski, Thomas Strassner 2018

机译：通过空间要求的芳基取代的β-二酮酮酸酯辅助配体提高量子产率
7. Saturated and unsaturated triruthenium clusters containing three sterically demanding phosphine ligands : synthesis and structure of [Ru₃(CO)₉(PCy₃)₃] and [Ru₃H₂(CO)₆(PCy₃)₃] [O] . Süss-Fink, Georg, Godefroy, Isabelle, Ferrand, Vincent, 2006

机译：包含三个空间要求的膦配体的饱和和不饱和三钌簇：[Ru _{3 （CO）_{9 （PCy _{3 ）_{3 ]和[Ru _{3 H _{2 （CO）_{6 （PCy _{3 ）< sub> 3 ]}}}}}}}}

Recent Advances in the Buchwald-Hartwig Amination Reaction Enabled by the Application of Sterically Demanding Phosphine Ancillary Ligands

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