A modified vacuum stability test in the study of initiation reactivity of nitramine explosives

摘要

Graphical abstractLogarithmic relationship between detonation velocity and specific rate constant of zero order thermal decomposition of pure nitramines and of their PBXs with polydimethylsiloxane (silox), polyisobutylene (C4), hydroxyl-terminated polybutadiene (HTPB) and polystyrene-butadiene (form) binders.Display OmittedHighlights?Vacuum stability test has been used to study the decomposition of several PBXs.?Mechanical sensitivities and detonation parameters were presented.?The specific rate constants were compared with the explosive properties.?Polymeric binding systems have the main influence on the specific rate constants.?CL-20 has the highest detonation velocity with low specific rate constant.AbstractThe zero-order reaction rates (specific rate constants) of isothermal decomposition at 120°C of plastic bonded explosives (PBXs) in the first six hours of decomposition were measured by means of the Czech vacuum stability test, STABIL. The PBXs were filled by RDX (1,3,5-trinitro-1,3,5-triazinane), β?HMX (β?1,3,5,7-tetranitro-1,3,5,7-tetrazocane), BCHMX and ?-CL20 (?-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane, ?-HNIW) and, in one case, on a mixture of BCHMX and 3-nitro-1,2,4-triazol-5-one (NTO), in a 1:1wt. ratio. These nitramines were bonded by 9% by wt. of softened polyisobutylene matrix, 13% by wt. of softened polystyrene-butadiene matrix, 18% by wt. of crosslinked hydroxyl-terminated polybutadiene, 12% by wt. of polydimethylsiloxane and by 40% of TNT. The relationships of specific rate constants with experimental detonation velocities, impact and friction sensitivities of these PBXs are shown and discussed. It is postulated that this approach provides results which are applicable to studies of initiation reactivity of energetic materials and which are fully comparable with those of other methods of investigation in this area.]]>