High-performance fiberglass/epoxy reinforced by functionalized CNTs for vehicle applications with less fuel consumption and greenhouse gas emissions

摘要

Carbon Nanotubes (CNTs) is among the most promising nanofiller materials that could be used for enhancing the properties of fiberglass/epoxy laminates for vehicle industries with less CO2 emission (the key player in the climate change). However, usually the commercialized CNTs are supplied in the shape of heavily entangled tubes what leads to random dispersion of CNTs in the polymer matrix and decrease in their performance, especially at industrial scale. Within this frame, the chemical functionalization process was used in the present research to avoid this problem and to modify the surface properties of CNTs at the same time, thus improving compatibility and solubility of CNTs in epoxy solutions. Afterwards, probe sonicator (pre-dispersion), ultrasonic path (main dispersion), mechanical mixer (mixed CNTs/Epoxy solutions with hardener), and vacuum infiltration (to remove air bubbles) were used to disperse functionalized CNTs with different concentrations (in the range 0.05-0.4 wt%) in the epoxy-hardener solutions. Then, vacuum-assisted resin transfer technique followed by curing process were used to prepare 4 layers-fiberglass/CNTs/epoxy panels. The mechanical and impact properties of the prepared panels were tested according to ASTM D7025 and ISO 6603-2 standards, respectively. Also, thermal behavior of the panels was investigated using thermogravimetric (TG-DTG). Finally, the environmental performance in terms of greenhouse gas emission (GHGE) was evaluated according to ISO-14040 standard, taking the resulting strength and changes in density into account. The results showed that 0.35 wt% of FCNTs were enough to improve the strength of panels by similar to 60%, compared to pure sample. Which means that weight structure of vehicles can decrease by 23%. Also, fuel consumption and GHGE can decrease significantly by 16% and similar to 26%, respectively. In addition, thermal stability and energy impact absorption at the same concentration of CNTs were improved by 5% and 31%, respectively.