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Effects of Fluoropolymer Binders on the Mechanical Properties of TATB‐Based PBX

机译：含氟聚合物粘合剂对TATB基PBX力学性能的影响

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摘要

Abstract >The relationship between the molecular structure of polymeric binders and mechanical properties of a TATB‐based polymer bonded explosive (PBX) were studied by using five different fluoropolymers as binders to compare the quati‐stastic and dynamic mechanical property, as well as the three‐point bending creep property of the PBX. F‐ binder A, which was composed of vinylidene fluoride (VDF) and chlorotrifluoroethylene (CTFE), endowed the PBX?A with the best mechanical strength and creep resistance ability. The fracture surfaces of the PBXs after the Brazilian tests were investigated by a field emission‐scanning electron microscope (FE‐SEM). The rupture mode in PBX?A and PBX?B was transcrystalline fracture together with interfacial debonding, but only interfacial debonding in PBX?C and PBX?D. It was explained that the C?Cl bond in CTFE played the key role to keep the polymeric binder rigid and increase the strength of the PBX. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> 通过使用五种不同的含氟聚合物作为粘合剂，研究了聚合物粘合剂的分子结构与TATB基聚合物键合炸药（PBX）的关系，以比较Quati-stastic和动态的机械性能，以及PBX的三点弯曲蠕变性能。 F-粘合剂A，由偏二氟乙烯（VDF）和氯二氟乙烯（CTFE）组成，赋予了最佳机械强度和抗蠕变性能力的PBXαa。通过场发射扫描电子显微镜（Fe-SEM）研究了巴西测试之后PBX的断裂表面。 PBX中的破裂模式α和PBX？B与界面剥离一起被复古骨折，但只有在PBX？C和PBX中的界面剥离。解释说CTFE中的C？Cl键在CTFE中发挥关键作用，以保持聚合物粘合剂刚性并增加PBX的强度。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2018年第7期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Jia‐Hui&option=202" target="_blank" rel="nofollow">Liu Jia‐Hui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yang Zhi‐Jian&option=202" target="_blank" rel="nofollow">Yang Zhi‐Jian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Shi‐Jun&option=202" target="_blank" rel="nofollow">Liu Shi‐Jun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Jian‐Hu&option=202" target="_blank" rel="nofollow">Zhang Jian‐Hu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Yong‐Gang&option=202" target="_blank" rel="nofollow">Liu Yong‐Gang;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>China Academy of Engineering PhysicsInstitute of Chemical Materials64 mianshan Road Mianyang Sichuan 621900 P.R. China;</p> <p>China Academy of Engineering PhysicsInstitute of Chemical Materials64 mianshan Road Mianyang Sichuan 621900 P.R. China;</p> <p>China Academy of Engineering PhysicsInstitute of Chemical Materials64 mianshan Road Mianyang Sichuan 621900 P.R. China;</p> <p>China Academy of Engineering PhysicsInstitute of Chemical Materials64 mianshan Road Mianyang Sichuan 621900 P.R. China;</p> <p>China Academy of Engineering PhysicsInstitute of Chemical Materials64 mianshan Road Mianyang Sichuan 621900 P.R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=TATB-based PBX&option=203" rel="nofollow">TATB-based PBX;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fluoropolymer&option=203" rel="nofollow">fluoropolymer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mechanical property&option=203" rel="nofollow">mechanical property;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fracture mechanism&option=203" rel="nofollow">fracture mechanism;</a> </p> <div class="translation"> 机译：基于TATB的PBX;含氟聚合物;力学性质;骨折机制; </div> </li> <li> <span class="lefttit">入库时间</span> <span>2022-08-20 06:41:17</span> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024626345.html">Effects of Fluoropolymer Binders on the Mechanical Properties of TATB‐Based PBX</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu 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C.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Martin, E. C.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yee, R. Y.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yee, R. Y. </a> <span>1984</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：pBXs（塑料粘结炸药）表面相互作用和力学性能对爆炸敏感性的影响</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangzhou-chemical-industry_thesis/0201275749616.html">造型粉制备工艺对TATB基PBX力学性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姜继勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 姜继勇</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张建虎&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张建虎</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘佳辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘佳辉</a> <span> <a href="/journal-cn-9125/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广州化工 </a> </span> <span> . 2019</span><span>,第021期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangzhou-chemical-industry_thesis/0201246551173.html">粘结剂增强对TATB基PBX力学性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=林聪妹&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 林聪妹</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘世俊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘世俊</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张娟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张娟</a> <span> <a href="/journal-cn-9125/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广州化工 </a> </span> <span> . 2012</span><span>,第014期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-nanjing-university-science-technology-natural-edition_thesis/0201298334914.html">MD模拟温度对TATB和TATB/F_(2311) PBX力学性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱伟</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖继军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,肖继军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄辉</a> <span> <a href="/journal-cn-50249/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 南京理工大学学报 </a> </span> <span> . 2007</span><span>,第2期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-chimica-sinica_thesis/0201272159031.html">TATB基PBX结合能和力学性能的理论研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖继军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 肖继军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谷成刚&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,谷成刚</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=方国勇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,方国勇</a> <span> <a href="/journal-cn-53859/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学学报 </a> </span> <span> . 2005</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-chimica-sinica_thesis/0201272160384.html">分子动力学模拟浓度和温度对TATB/PCTFE PBX力学性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马秀芳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 马秀芳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=肖继军&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,肖继军</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄辉</a> <span> <a href="/journal-cn-53859/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学学报 </a> </span> <span> . 2005</span><span>,第022期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-41963_thesis/020222499267.html">TATB基PBX材料力学性能的粗粒化计算</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=WANG Li-li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . WANG Li-li</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王丽莉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王丽莉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=JIN Zhao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,JIN Zhao</a> <span> <a href="/conference-cn-41963/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第九届国际分子模拟与信息技术应用学术会议（ICMSI2018） </a> <span> <span> . -1</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313038580.html">HMX、TATB基PBX沿不同晶面力学性能和结合能的理论研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄玉成&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 黄玉成</a> <span> . 2005</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204291572.html">力-热作用下表征TATB基PBX内应力的方法</a> <b>[P]</b> . <span> 中国专利： CN109470577B </span> <span> . 2021.03.16</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120100339409.html">力-热作用下表征TATB基PBX内应力的方法</a> <b>[P]</b> . <span> 中国专利： CN109470577A </span> <span> . 2019-03-15</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130427015566.html">COMPOSITION OF A TRANSPARENT ORGANIC INSULATING LAYER, WHICH INCLUDES A POLYCYANURATE-BASED POLYMER BINDER, HAVING IMPROVED MECHANICAL PROPERTIES, HEAT RESISTANCE, AND INSULATING PROPERTIES</a> <b>[P]</b> . <span> 外国专利： <!-- 韩国专利： --> KR20100078303A </span> <span> . 2010-07-08</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：透明有机绝缘层的组成，其中包括基于聚氰酸盐的聚合物粘合剂，具有改善的机械性能，耐热性和绝缘性能 </span> </p> </li> <li> <div> <b>4. </b><a 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