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The Oxidation and Combustion Properties of Gas Atomized Aluminum?Boron?Europium Alloy Powders

机译:气体雾化铝的氧化和燃烧性能α硼罐α铕合金粉末

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摘要

Abstract > In this paper, the Aluminum?boron?europium ternary alloy fuels with boron content of 1.5~4.85?wt.?% and europium content of 3?wt.?% were prepared by the close‐coupled gas atomization. XRD, SEM, TG‐DTA and oxygen bomb test were used to analyze the phase constituents, morphology, thermal oxidation behavior and combustion exothermic property of powders, respectively. The functions of boron and europium on the combustion of metal fuels were studied, and a reasonable oxidation model of the alloy particles was proposed. The results show that there are Al, AlB <sub>2</sub> , Al <sub>4</sub> Eu and B <sub>6</sub> Eu in the alloy. When the europium content is constant, the combustion enthalpy of the Al?B?Eu alloy powder firstly increases and then decreases as the boron content increases. Additionally, at oxygen pressure of 3.0?MPa, the Al?3.5B?3Eu ternary alloy powder burned completely with the maximum combustion enthalpy of 33324.5?J?g ?1 . This increases by 11?% compared with theoretical combustion enthalpy of aluminum powder (31.1?kJ?g ?1 ). Al?3.5B?3Eu undergoes a dramatic oxidation exothermal phenomenon at 1110?°C with the weight increase efficiency of 53.66?%, which is 1.7 times that of aluminum. Due to the synergistic effects between the phase of B <sub>6</sub> Eu and AlB <sub>2</sub> inside the alloy particles, the Al?3.5B?3Eu alloy powder shows excellent exothermic performance. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> > 在本文中,铝合金?硼?铕三元合金燃料,硼含量为1.5〜4.85≤≤%和铕含量为3〜wt。Δ%通过牢固的气体雾化制备。 XRD,SEM,TG-DTA和氧炸弹试验用于分别分析粉末的相成分,形态,热氧化行为和燃烧放热性。研究了硼和铕对金属燃料燃烧的功能,提出了合金颗粒的合理氧化模型。结果表明有AL,ALB <sub> 2 </ sub> ,al. <sub> 4 </ sub> 欧盟和B. <sub> 6 </ sub> 欧盟在合金中。当铕含量恒定时,Alβb的燃烧焓首先增加然后随着硼含量的增加而降低。另外,在3.0α的氧气压力下,Al?3.5b?3eu三元合金粉完全燃烧,最大燃烧焓为33324.5?J?G ?1 </ sup> 。与铝粉末的理论燃烧焓相比,这增加了11?%(31.1?KJ?G. ?1 </ sup> )。 Al?3.5b?3eu在1110Ω℃下经历剧烈的氧化现象,其重量增加53.66Ω·%,这是铝的1.7倍。由于B的阶段之间的协同效应 <sub> 6 </ sub> 欧盟和alb. <sub> 2 </ sub> 在合金颗粒内部,Alα3.5b?3eu合金粉末显示出优异的放热性能。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29946/'>《Propellants, Explosives, Pyrotechnics》</a> <b style="margin: 0 2px;">|</b><span>2019年第6期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Wei&option=202" target="_blank" rel="nofollow">Wang Wei;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zou Hui&option=202" target="_blank" rel="nofollow">Zou Hui;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cai Shuizhou&option=202" target="_blank" rel="nofollow">Cai Shuizhou;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Material Processing and Die and Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074 PR China;</p> <p>State Key Laboratory of Material Processing and Die and Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074 PR China;</p> <p>State Key Laboratory of Material Processing and Die and Mould TechnologyHuazhong University of Science and TechnologyWuhan 430074 PR China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1837.html" title="爆炸物工业、火柴工业">爆炸物工业、火柴工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Metal fuel&option=203" rel="nofollow">Metal fuel;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Al?B?Eu alloy powder&option=203" rel="nofollow">Al?B?Eu alloy powder;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Combustion characteristic&option=203" rel="nofollow">Combustion characteristic;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Oxidation properties&option=203" rel="nofollow">Oxidation properties;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Metallographic compounds&option=203" rel="nofollow">Metallographic compounds;</a> </p> <div class="translation"> 机译:金属燃料;Al?B?欧盟合金粉;燃烧特性;氧化特性;金相化合物; 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href="/academic-conference-cn_meeting-59916_thesis/020222846674.html">由氧化铝、氧化硼和活性碳合成碳硼化铝的反应过程研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cui Peng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 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href="/patent-detail/061201376998.html">一种氧化锂-氧化铝-二氧化硅-氧化硼、氧化钙-氧化铝-二氧化硅-氧化硼可析晶玻璃低温共烧复合材料及其制备方法</a> <b>[P]</b> . <span> 中国专利: CN102898145B </span> <span> . 2014.06.04</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120101560613.html">一种氧化锂-氧化铝-二氧化硅-氧化硼、氧化钙-氧化铝-二氧化硅-氧化硼可析晶玻璃低温共烧复合材料及其制备方法</a> <b>[P]</b> . <span> 中国专利: CN102898145A </span> <span> . 2013-01-30</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130475641593.html">SELECTIVE OXIDATION OF ATOMIZED POWDER OF COPPER ALLOY CONTAINING ALUMINUM</a> <b>[P]</b> . <span> 外国专利: <!-- 日本专利: --> JPS5891138A </span> <span> . 1983-05-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:含铜铜合金粉末的选择性氧化 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130443674832.html">Cylinder made from an aluminum alloy used for a combustion engine has an inner wall surface galvanically treated in a bath containing an iron plating solution containing a boron mixture</a> <b>[P]</b> . <span> 外国专利: <!-- 德国专利: --> DE10248164A1 </span> <span> . 2003-05-08</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:由用于内燃机的铝合金制成的气缸的内壁表面在镀液中进行了电镀处理,该镀液中含有含硼混合物的镀铁溶液 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130405838640.html">BRASS ALLOY, INCLUDING CERAMIC NANOPARTICLES OF ALUMINUM OXIDE, WHICH HAS IMPROVED PROPERTIES REGARDING MECHANICAL PROCESSING</a> <b>[P]</b> . <span> 外国专利: <!-- 俄罗斯专利: --> RU2016120842A </span> <span> . 2017-12-19</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:黄铜合金,包括氧化铝的陶瓷纳米粒子,与机械加工有关的性能得到改善 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704024626091','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉,该期刊暂不可订阅,敬请期待!</p> <p class="current">目前支持订阅全部北京大学中文核心(2020)期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" 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