Covalent Functionalization of Single-Walled Carbon Nanotubes Through the Fluorination Stage for Integration into an Epoxy Composite

摘要

The upper limit of the elastic modulus has been estimated for a polymer-carbon nanotube-epoxy matrix nanocomposite. This limit can be achieved if the nanotubes are integrated into the matrix, i.e., they form a continuous reinforcing network inside the matrix, and if the nanotubes are single-walled or double-walled carbon nanotubes. A technique for carbon nanotube functionalization via fluorination and fluorine substitution and a technique for calculating the degree of nanotube functionalization based on reaction yield measurements are proposed. For fluorine substitution by epoxy-diane resin and diaminodiphenylmethane, the degree of functionalization is C-(FG)(x) , x similar to 0.011-0.013 and the FG-molecular fragment containing the epoxy (amino) group corresponding to functionalization of similar to 5% of the surface D atoms of nanotubes. The control reaction showed that the epoxy groups preserve the chemical activity, while part of the amino groups are deactivated. The grafted epoxy(amino) groups ensure nanotube surface lyophilicity in epoxy composites and integrate the nanotubes into the epoxy matrix owing to the chemical bonds.