Effect of dopant and oxidant  on the electrochemical properties of polyaniline/graphite nanoplate composites

Zhao Xueyan; Gr?tz Olga; Pionteck Jürgen

摘要

Abstract > Optimizing the synthesis parameters of polyaniline/graphite nanoplate (PANI/GNP) composite is essential to the final electrochemical performance. Herein, the electrochemical properties of PANI/GNP composites, prepared by in situ chemical polymerization using varying amounts of different oxidants, with or without the addition of 4‐dodecylbenzenesulfonic acid (DBSA) as dopant, were investigated. Cyclic voltammetric results suggested that a stoichiometric amount of the oxidant iron chloride (FeCl <sub>3</sub> ) was beneficial to the electrochemical properties of the composites. The use of ammonium persulfate (APS) instead of FeCl <sub>3</sub> as oxidant largely increased the actual PANI content, conductivity and specific capacitance of the PANI/GNP composites. The dopant DBSA increased the conductivity of the PANI/GNP composites but did not show a positive effect on the electrochemical behavior. The cyclic voltammograms of the PANI/GNP composites indicated that the pseudocapacitance of PANI contributes more than the electrical double‐layer capacitance of GNP to the capacitance of the composites, while the presence of GNP plays an essential role in the rate capability of the composites. In this study, PANI/GNP (1:1) composite synthesized with an APS to aniline molar ratio of 1 showed a balanced combination of high specific capacitance (180.5 F g ?1 at 20 mV s ?1 ) and good rate capability (78% retention at 100 mV s ?1 ). ? 2018 Society of Chemical Industry </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract XMLNS =“http://www.wiley.com/namespaces/wiley”type =“main”xml：lang =“en”> <标题类型=“main”>抽象</ title> > 优化聚苯胺/石墨纳米板（PANI / GNP）复合材料的合成参数对最终电化学性能至关重要。在此，由PANI / GNP复合材料的电化学性质原位</ i> 研究了利用不同量的不同氧化剂，具有或不添加4-十二烷基苯磺酸（DBSA）作为掺杂剂的化学聚合。循环伏安结果表明，化学计量的氧化剂氯化铁（FECL） <sub> 3 </ sub> ）有益于复合材料的电化学性质。使用过硫酸铵（APS）代替FECL <sub> 3 </ sub> 随着氧化剂的大部分增加了PANI / GNP复合材料的实际PANI含量，电导率和特定电容。掺杂剂DBSA增加了PANI / GNP复合材料的导电性，但没有对电化学行为显示积极影响。 PANI / GNP复合材料的循环伏型图表明PANI的假码耦合的比GNP的电气双层电容贡献到复合材料的电容中，而GNP的存在在复合材料的速率能力中起着重要作用。在该研究中，用APS合成的PANI / GNP（1：1）复合材料与苯胺摩尔比为1的平衡组合（180.5 f g ？1 </ sup> 在20 mv s ？1 </ sup> ）和良好的速率能力（在100 mV s的78％保留？1 </ sup> ）。还2018年化学工业学会 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29710/'>《Polymer international 》</a> <b style="margin: 0 2px;">|</b><span>2018年第10期</span><b style="margin: 0 2px;">|</b> <span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Xueyan&option=202" target="_blank" rel="nofollow">Zhao Xueyan;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gr?tz Olga&option=202" target="_blank" rel="nofollow">Gr?tz Olga;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pionteck Jürgen&option=202" target="_blank" rel="nofollow">Pionteck Jürgen;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Functional Nanocomposites and BlendsLeibniz Institute of Polymer Research DresdenDresden Germany;</p> <p>Department of Nanostructured MaterialsLeibniz Institute of Polymer Research DresdenDresden Germany;</p> <p>Department of Functional Nanocomposites and BlendsLeibniz Institute of Polymer Research DresdenDresden Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1185.html" title="高分子化学（高聚物）">高分子化学（高聚物） ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyaniline (PANI)&option=203" rel="nofollow">polyaniline (PANI);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphite nanoplate (GNP)&option=203" rel="nofollow">graphite nanoplate (GNP);</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrochemical property&option=203" rel="nofollow">electrochemical property;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=conductivity&option=203" rel="nofollow">conductivity;</a> </p> <div class="translation"> 机译：聚苯胺（PANI）;石墨纳米板（GNP）;电化学性质;电导率; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024575493.html">Effect of dopant and oxidant on the electrochemical properties of polyaniline/graphite nanoplate composites</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Xueyan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhao Xueyan,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gr?tz Olga&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gr?tz Olga,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pionteck Jürgen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Pionteck Jürgen </a> <a href="/journal-foreign-29710/" target="_blank" rel="nofollow" class="tuijian_authcolor">Polymer international .</a> <span>2018</span> <span>,第10期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：掺杂剂和氧化剂对聚苯胺/石墨纳米板复合材料电化学性能的影响</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704018733216.html">Polyaniiine/graphite nanosheet, polyaniline/Ag/graphite nanosheet, polyaniline/Ni/graphite nanosheet composites and their electromagnetic properties</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xinming Wu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xinming Wu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Shuhua Qi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Shuhua Qi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guocheng Duan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guocheng Duan </a> <a href="/journal-foreign-28763/" target="_blank" rel="nofollow" class="tuijian_authcolor">Synthetic Metals .</a> <span>2012</span> <span>,第17a18期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：聚苯胺/石墨纳米片，聚苯胺/银/石墨纳米片，聚苯胺/镍/石墨纳米片复合材料及其电磁性能</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_detail_thesis/0204117115353.html">Effect of Microwave Treatment of Graphite on the Electrical Conductivity and Electrochemical Properties of Polyaniline/Graphene Oxide Composites</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yanjun Tang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yanjun Tang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xiulan Hu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xiulan Hu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dongdong Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dongdong Liu,</a> <a href="/journal-foreign-30284/" target="_blank" rel="nofollow" class="tuijian_authcolor">Polymers .</a> <span>2016</span> <span>,第11期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：微波处理石墨对聚苯胺/氧化石墨复合材料电导率和电化学性能的影响</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-280772_thesis/0705017361616.html">A study on the Synthesis, Characterization and Properties of Polyaniline Nanofibers using Ferric Chloride as both Oxidant and Dopant</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hangjun Ding&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hangjun Ding,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Yang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhou Yang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Huai Yang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Huai Yang </a> <a href="/conference-foreign-280772/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Conference on Advances in Energy and Environmental Science .</a> <span>2013</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：氯化铁作为氧化剂和掺杂剂的二苯胺纳米纤维合成，表征和性能研究</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061378749.html">Effect of electrochemical deposition parameters on the synthesis, structure and properties of polyaniline-polypyrrole composite coatings on steel.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rajagopalan, Ramakrishnan.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Rajagopalan, Ramakrishnan. </a> <span>2002</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：电化学沉积参数对钢上聚苯胺-聚吡咯复合涂层的合成，结构和性能的影响。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040002146179.html">Effect of Microwave Treatment of Graphite on the Electrical Conductivity and Electrochemical Properties of Polyaniline/Graphene Oxide Composites</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yanjun Tang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yanjun Tang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xiulan Hu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xiulan Hu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dongdong Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dongdong Liu,</a> <span>2016</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：微波处理石墨对聚苯胺/氧化石墨复合材料电导率和电化学性能的影响</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/0100098417294.html ">Effect of Microwave Treatment of Graphite on the Electrical Conductivity and Electrochemical Properties of Polyaniline/Graphene Oxide Composites</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yanjun Tang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yanjun Tang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xiulan Hu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Xiulan Hu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dongdong Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dongdong Liu,</a> <span>2016</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：微波处理石墨对聚苯胺/氧化石墨烯复合材料导电性和电化学性能的影响</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201292526523.html">石墨烯的种类对剑麻纳米纤维素/石墨烯/聚苯胺复合材料电化学性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈梓润&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈梓润</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=韦春&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,韦春</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=龚永洋&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,龚永洋</a> <span> <a href="/journal-cn-56862/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 高分子材料科学与工程 </a> </span> <span> . 2017</span><span> ,第7期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-hunan-university-natural-sciences_thesis/0201249692900.html">高电化学性能聚苯胺纳米纤维/石墨烯复合材料的合成∗</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=钟文斌&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 钟文斌</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李士超&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李士超</a> <span> <a href="/journal-cn-4634/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 湖南大学学报（自然科学版） </a> </span> <span> . 2015</span><span> ,第006期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201298241628.html">磁场环境下氧化剂和掺杂剂浓度对聚苯胺性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杜新胜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杜新胜</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈秀娣&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈秀娣</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马利&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,马利</a> <span> <a href="/journal-cn-57273/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 胶体与聚合物 </a> </span> <span> . 2008</span><span> ,第2期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-beijing-university-science-technology_thesis/0201247810525.html">反应物中氧化剂和掺杂剂浓度对聚苯胺性能与结构的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=康茹珍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 康茹珍</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨善武&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨善武</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=贺信莱&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,贺信莱</a> <span> <a href="/journal-cn-4503/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 北京科技大学学报 </a> </span> <span> . 2005</span><span> ,第001期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201293266028.html">纳米纤维结构对石墨/纳米碳纤维复合材料电化学性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=谢吉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 谢吉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李向辉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李向辉</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=左振民&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,左振民</a> <span> <a href="/journal-cn-56955/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 人工晶体学报 </a> </span> <span> . 2016</span><span> ,第11期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-4973_thesis/020221209816.html">三元铁酸钴/石墨烯/聚苯胺纳米复合材料的制备及其电化学性能研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pan Xiong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Pan Xiong</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=熊攀&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,熊攀</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chenyao Hu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Chenyao Hu</a> <span> <a href="/conference-cn-4973/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第30届全国化学与物理电源学术年会 </a> <span> <span> . 2013</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311373800.html">石墨烯/镍钴氧化物/聚苯胺纳米复合材料的制备及其电化学性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李秀蓉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李秀蓉</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120106914144.html">固相法制备聚苯胺/石墨烯复合材料及其电化学性能</a> <b>[P]</b> . <span> 中国专利： CN102732028A </span> <span> . 2012-10-17</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061203139723.html">氧化石墨烯/聚苯胺/二氧化钛纳米复合材料及聚苯胺纳米防腐涂料的制备方法</a> <b>[P]</b> . <span> 中国专利： CN106398206B </span> <span> . 2019.01.04</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130443530746.html">Composition for conductive polyaniline films and composites, used e.g. in optoelectronic or transparent electrodes, comprises emeraldine base polyaniline and a functionalized sulfonic, phosphonic or phosphoric acid dopant</a> <b>[P]</b> . <span> 外国专利：  FR2830535A1 </span> <span> . 2003-04-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于导电聚苯胺薄膜和复合材料的组合物，例如用于在光电或透明电极中，包含翡翠碱聚苯胺和功能化的磺酸，膦酸或磷酸掺杂剂 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130432951205.html">Sulphonic acids as dopants for polyaniline and for conductive polyaniline-based composite materials</a> <b>[P]</b> . <span> 外国专利：  US7390439B2 </span> <span> . 2008-06-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：磺酸作为聚苯胺和导电性聚苯胺基复合材料的掺杂剂 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130434031170.html">The use of sulfonic -, phosphoric acid phone - and phosphorus - acids as dopants of polyanilines and polyanilines conductive composite materials</a> <b>[P]</b> . <span> 外国专利：  DE60208649T2 </span> <span> . 2006-11-16</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：磺酸，磷酸电话和磷酸作为聚苯胺和聚苯胺导电复合材料的掺杂剂的用途 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704024575493','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704024575493down" data-source="7," data-out-id="FcSXzEukcXg6irrmbP8eEw==," data-f-source-id="7" data-title="Effect of dopant and oxidant on the electrochemical properties of polyaniline/graphite nanoplate composites" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="29710" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Effect of dopant and oxidant on the electrochemical properties of polyaniline/graphite nanoplate composites"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.9"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.9"></script> </body> <script> function kefu(customization) { var from = GetQueryString("from"); if (from == null || from == "") { from = "other"; } var url = getWxWorkQrCode(55, from, customization); if (url == "" || typeof url == 'undefined') { url = "https://wework.qpic.cn/wwpic/994838_0LUTS-VqR0quT1N_1675665967/0"; } tipDocGuidance(url, '人工辅助获取外文期刊材料'); } $(function () { var weiPuStatus = getCookie('WeiPuStatus'); if (weiPuStatus) { tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if ((sourcetype == 1 || sourcetype == 4) && inyn_provide_service_level != 4) { getJournal(); } }) </script> </html>