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首页> 外文期刊>Polymer Composites >Organic/inorganic hybrid nanostructured composites of liquid nitrile rubber‐based quaternary ammonium salt‐modified montmorillonite and epoxy resin: preparation and tribological behaviors
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Organic/inorganic hybrid nanostructured composites of liquid nitrile rubber‐based quaternary ammonium salt‐modified montmorillonite and epoxy resin: preparation and tribological behaviors

机译：有机/无机杂化纳米结构复合材料的液态丁腈橡胶型季铵盐改性蒙脱石和环氧树脂：制备和摩擦学行为

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摘要

Abstract > A new type of polymer derivative, carboxyl‐terminated butadiene nitrile rubber‐based quaternary ammonium salt (CTBN‐QAS), has been synthesized and used for the functionalization of sodium montmorillonite (MMT‐Na) via a cationic exchange process. The resulting CTBN‐QAS‐modified MMT (CTBN‐QAS‐MMT) exhibits exfoliated and/or intercalated structures as indicated by X‐ray diffraction (XRD) analysis. Further CTBN‐QAS‐MMT was incorporated into diglycidyl ether of bisphenol A (DGEBA) with different loadings to produce organic/inorganic hybrid epoxy nanocomposites. Studies were conducted on tribological behavior and dynamic mechanical properties by ring‐on‐block wear tester and dynamic mechanical analysis, respectively. The results show that as‐prepared nanostructured epoxy has better wear resistance and lower friction coefficient than pure epoxy polymer (EP), and the best wear resistance is obtained at 6 phr (parts per hundred) CTBN‐QAS‐MMT‐modified EP. Wear surface morphology analysis shows that the friction mechanism is abrasive wear. Additionally, the good friction resistance and decreased wear loss are correlated with higher glassy storage modulus and lower tan <fi>δ</fi> . The improved tribological behavior is due to the formation of hybrid organic/inorganic nanostructured epoxy material. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 已经合成了一种新型的聚合物衍生物，羧基封端的丁二烯腈橡胶基季铵盐（CTBN-QAs）并通过阳离子交换过程来用于蒙脱石（MMT-NA）的官能化。由此产生的CTBN-QAS改性MMT（CTBN-QAS-MMT）表现出X射线衍射（XRD）分析所示的剥离和/或插层结构。将进一步的CTBN-QAS-MMT掺入双酚A（DGEBA）的二缩水甘油醚中，具有不同的载荷，以产生有机/无机杂交环氧纳米复合材料。通过环形磨损测试仪和动态力学分析对摩擦学行为和动态力学性能进行研究。结果表明，制备的纳米结构环氧树脂具有比纯环氧聚合物（EP）更好的耐磨性和较低的摩擦系数，并且在6phr（份数份）CTBN-QAS-MMT改性EP中获得最佳耐磨性。磨损表面形态学分析表明摩擦机制是磨料磨损。此外，良好的摩擦阻力和耐磨性降低与较高的玻璃状储存模量和低棕褐色有关 <fi>Δ</ fi> 。改善的摩擦学行为是由于形成杂种有机/无机纳米结构环氧材料。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29566/'>《Polymer Composites》</a> <b style="margin: 0 2px;">|</b><span>2020年第5期</span><b style="margin: 0 2px;">|</b><span>共10页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/7852.html" title="增强塑料、填充塑料">增强塑料、填充塑料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=epoxy&option=203" rel="nofollow">epoxy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=montmorillonite&option=203" rel="nofollow">montmorillonite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=nitrile rubber&option=203" rel="nofollow">nitrile rubber;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organic/inorganic hybrid&option=203" rel="nofollow">organic/inorganic hybrid;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=quaternary ammonium salt&option=203" rel="nofollow">quaternary ammonium salt;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tribological behaviors&option=203" rel="nofollow">tribological behaviors;</a> </p> <div class="translation"> 机译：环氧树脂;蒙脱石;丁腈橡胶;有机/无机杂交;季铵盐;摩擦学行为; </div> </li> <li> <span class="lefttit">入库时间</span> <span>2022-08-20 06:28:00</span> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704024545745.html">Organic/inorganic hybrid nanostructured composites of liquid nitrile rubber‐based quaternary ammonium salt‐modified montmorillonite and epoxy resin: preparation and tribological behaviors</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-29566/" target="_blank" rel="nofollow" class="tuijian_authcolor">Polymer Composites .</a> <span>2020</span><span>,第5期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：有机/无机杂化纳米结构复合材料的液态丁腈橡胶型季铵盐改性蒙脱石和环氧树脂：制备和摩擦学行为</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704014660161.html">Tribological Properties of Hydroxyl-Terminated Liquid Nitrile Rubber-Modified Polyurethane/Epoxy Interpenetrating Polymer Network Composites</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=SHOUBING CHEN&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">SHOUBING CHEN,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=QIHUA WANG&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">QIHUA WANG,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=TINGMEI WANG&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">TINGMEI WANG </a> <a href="/journal-foreign-35053/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Macromolecular Science. 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