Semicompletion time of carbon dioxide uptake in the process of gas hydrate formation in presence and absence of SDS and silver nanoparticles

摘要

Carbon dioxide emission to the atmosphere is one of the main causes of the current global warming. Therefore, capturing this greenhouse gas is very important. The effect of sodium dodecyl sulfate (SDS) and silver nanoparticles on semicompletion time (t(95%)) of carbon dioxide uptake in the process of gas hydrate formation is investigated in this communication. The tests were performed at temperatures of 273.65 and 275.65K and initial pressures of 2 and 3MPa in a 460 cm(3) stirred batch reactor. Experimental measurements show that utilization of SDS and silver nanoparticles decreases the semicompletion time of carbon dioxide uptake considerably. The addition of SDS with concentration of 500ppm and silver nanoparticles with concentration of 45M at p = 2MPa and T = 275.65K, respectively, decreases the semicompletion time of carbon dioxide uptake 136.09% and 152.88%, compared to pure water. Investigating the effect of temperature on the amount of t(95%) in the presence and absence of tested additives shows that this kinetic parameter decreases by increasing the temperature from 273.65 to 275.65 K.