Crystal Structure and Luminescence of the [DyCl2(H2O)(6)]Cl Complex

摘要

The crystal structure of the [DyCl2(H2O)(6)]Cl complex is studied by X-ray diffraction analysis. The crystals are constructed of complex cations [DyCl2(H2O)(6)](+) and outer-sphere Cl-1 ions. The structure is represented by separate [DyCl2(H2O)(6)] complexes bound by a dense network of hydrogen bonds. The coordination polyhedron of Dy(III) with coordination number 8 is represented by a weakly distorted square antiprism. The results of investigation of the luminescent properties of the complex are presented.