Depression of lead-activated sphalerite by pyrite via galvanic interactions: Implications to the selective flotation of complex sulfide ores

摘要

Complex sulfide ores are typically mixtures of various sulfide minerals like sphalerite (ZnS), chalcopyrite (CuFeS2), galena (PbS), pyrite (FeS2), and barite (BaSO4) and processed by selective flotation to recover targetsulfide minerals like chalcopyrite and sphalerite. Some complex sulfide ores, however, contain anglesite (PbSO4), a mineral with relatively high solubility, that complicates selective flotation because its dissolution releases Pb2+ , which 'activates' co-existing sulfide minerals (e.g., ZnS). Because both target and non-target sulfide minerals are recovered when flotation is non-selective, another flotation stage to recover target minerals in froth products is required. Aside from anglesite, co-existing gangue sulfide minerals like pyrite also complicate selective flotation because of their strong effects on the floatability of target-sulfide minerals via electrochemical interactions.