New compounds with 4-azatricyclo[4.3.1.1(3,8)]undecane framework

Nurieva Evgeniya V.; Alexeev Alexander A.; Grishin Yuri K.; Tafeenko Victor A.; Zefirova Olga N.

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New compounds with 4-azatricyclo[4.3.1.1(3,8)]undecane framework

机译：具有4-Azatricyclo的新化合物[4.3.1.1（3,8）]少女框架

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摘要

Reactions of 1-[(endo-bicyclo[3.3.1]non-6-en-3-yl)methyl]-3-X tert-butylthiourea with I-2/(BuOOH)-O-t and I-2/K2CO3 afforded 4-azatri-cyclo[4.3.1.13,8]undecane based products via intramolecular cyclization, as determined by X-ray analysis and NMR spectroscopy.

机译：1 - [（endo-双环[3.3.1]非6-烯-3-基）的反应] -3-x叔丁基脲，其具有I-2 /（BuOOH）-ot和I-2 / K2CO3 通过X射线分析和NMR光谱法通过分子内环化进行4-氮杂-CICSO [4.3.1.1.1,8,8]未甲烷基于分子化的产物。

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《Mendeleev Communications 》 |2020年第2期| 共2页
作者
Nurieva Evgeniya V.; Alexeev Alexander A.; Grishin Yuri K.; Tafeenko Victor A.; Zefirova Olga N.;
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作者单位

Moscow MV Lomonosov State Univ Dept Chem Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem Moscow 119991 Russia;

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原文格式 PDF
正文语种 eng
中图分类化学 ;
关键词
N-(endo-bicyclo3.3.1non-6-en-3-yl)methylthiourea; intramolecular cyclization; bridged tricyclic compounds; ureas; thioureas; azahomoadamantanes; electrophilic addition;

机译：n - [（endo-bicyclo [3.3.1]非6-en-3-yl）甲基]硫脲;分子内环化;桥接三环化合物;尿素;硫脲;亚扎莫罗丹;亲电子加法;

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1. New compounds with 4-azatricyclo[4.3.1.1(3,8)]undecane framework [J] . Nurieva Evgeniya V., Alexeev Alexander A., Grishin Yuri K., Mendeleev Communications . 2020 ,第2期

机译：具有4-Azatricyclo的新化合物[4.3.1.1（3,8）]少女框架
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机译：合成五环（5.4.0.0（2,6）.0（3,10）.O（5,9））十一烷-4,8,11-三酮，五环（6.3.0.0（2,6）.0（ 3,10）.0（5,9））十一烷-4,7,11-三酮（D3-Trishomocubanetrione）和4,4,7,7,11,11-Hexanitro（6.3.0.0（2,6）） .0（3,10）.0（5,9）undecane（

New compounds with 4-azatricyclo[4.3.1.1(3,8)]undecane framework

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