Geochronology, geochemistry, and zircon Hf isotopes of the Mo‐bearing granitoids in the eastern Jilin‐Heilongjiang provinces, NE China: Petrogenesis and tectonic implications

摘要

> In order to investigate their precise geochronological framework, petrogenesis, and tectonic implications, whole‐rock major and trace elements, together with zircon U–Pb and Hf isotope data, are reported for the Mo‐bearing granitoids from the eastern Jilin‐Heilongjiang provinces in the eastern segment of the Central Asian Orogenic Belt. Zircon U–Pb dating by LA–ICP–MS yields crystallization ages for the Liushengdian monzogranite porphyry (252.2?±?1.6?Ma), the Luming monzogranite porphyry (197.1?±?1.6?Ma), and the Baoshan granodiorite (164.4?±?1.9?Ma) and quartz diorite (165.2?±?1.7?Ma), respectively. This zircon U–Pb data, combined with previous ages, indicate that the eastern Jilin‐Heilongjiang provinces is dominated by 2 stages of ore‐related granitic magmatism and associated Mo mineralization, that is, Late Permian (259–252?Ma) and Early‐Middle Jurassic (200–165?Ma). Geochemically, these Mo‐bearing granitoids have high SiO ₂ (60.78–74.67?wt.%) and K ₂ O (2.85–6.23?wt.%), low MgO (0.17–2.85?wt.%) and CaO (0.66–4.38?wt.%) contents, with A/NCK and δEu values of 0.87–1.08 and 0.19–1.07, respectively; we infer that they belong to high‐K calc‐alkaline series and are metaluminous to peraluminous in nature. They are characterized by enrichment in large ion lithophile elements and light rare earth elements, and weak depletion in high field strength elements and heavy rare earth elements, consistent with the geochemical signatures of subduction‐related genesis. In addition, in situ Hf isotopic analyses of zircons from 4 dated samples reveal that they have ε _Hf (t) values of ?0.4 to +10.3, with 2‐stage model ages varying from 551 to 1,261?Ma, indicating that they probably originated from the partial melting of a dominantly Mesoproterozoic–Neoproterozoic cru