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首页> 外文期刊>Fuel cells >Corrosion Resistant Al‐Cr‐Mo Alloy Coating on Type 316L Stainless Steel Bipolar Plates for Proton Exchange Membrane Fuel Cell Applications
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Corrosion Resistant Al‐Cr‐Mo Alloy Coating on Type 316L Stainless Steel Bipolar Plates for Proton Exchange Membrane Fuel Cell Applications

机译:用于质子交换膜燃料电池应用的316L不锈钢双极板耐腐蚀Al-Cr-Mo合金涂层

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摘要

Abstract > The most important issues that plague wider use of polymer electrolyte membrane fuel cells (PEMFCs) are insufficient corrosion resistance, electrical conductivity and wettability of metallic bipolar plates (BPPs). To address these issues, an amorphous Al‐Cr‐Mo ternary alloy coating is applied on type 316L stainless steel using direct current magnetron sputtering. The electrochemical corrosion behavior of bare and alloy coated specimens has been investigated by polarization and electrochemical impedance spectroscopy techniques under simulated fuel cell working environment consisting of 0.5M?H <sub>2</sub> SO <sub>4</sub> at 70 ± 2?°C. The results indicate that the corrosion current density of the alloy coated specimen is approximately 0.2 μA cm ?2 showing a reduction of two orders of magnitude. The polarization resistance increased by an order of magnitude and the interfacial contact resistance (ICR) is reduced significantly (45 and 48 mΩ cm 2 in the simulated anode and cathode environments, respectively) due to the application of the coating. The chromium and molybdenum enrichment on the surface of coated specimen, as revealed by X‐ray photoelectron spectroscopy, is proposed to be responsible for the improved corrosion resistance. Further, the coating is expected to show significantly better water management due to high hydrophobicity than the bare stainless steel. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><Abstract Type =“Main”XML:Lang =“en”> <标题类型=“main”>抽象</ title> > 瘟疫更广泛地使用聚合物电解质膜燃料电池(PEMFC)的最重要问题是金属双极板(BPPS)的耐腐蚀性,导电性和润湿性不足。为了解决这些问题,使用直流磁控溅射在316L不锈钢中施加无定形AL-CR-MO三元合金涂层。通过偏振和电化学阻抗谱技术在模拟燃料电池加工环境下由0.5米的模拟燃料电池工作环境进行研究,研究了裸露和合金涂层标本的电化学腐蚀行为 <sub> 2 </ sub> 所以 <sub> 4 </ sub> 在70±2?°C时。结果表明,合金涂层样本的腐蚀电流密度约为0.2μAcm ?2 </ sup> 显示减少两个数量级。偏振电阻增加了幅度和界面接触电阻(ICR)显着减小(45和48mΩcm 2 </ sup> 在模拟的阳极和阴极环境中分别是由于涂层的施加。提出了X射线光电子能谱所揭示的涂覆样品表面上的铬和钼富集,以负责改进的耐腐蚀性。此外,预期涂层由于高疏水性而比裸露不锈钢显着显示出显着更好的水管理。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24199/'>《Fuel cells》</a> <b style="margin: 0 2px;">|</b><span>2019年第6期</span><b style="margin: 0 2px;">|</b><span>共16页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ingle A. V.&option=202" target="_blank" rel="nofollow">Ingle A. V.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Raja V. S.&option=202" target="_blank" rel="nofollow">Raja V. S.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rangarajan J.&option=202" target="_blank" rel="nofollow">Rangarajan J.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mishra P.&option=202" target="_blank" rel="nofollow">Mishra P.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Metallurgical Engineering and Materials ScienceIndian Institute of Technology Bombay400076 Mumbai India;</p> <p>Department of Metallurgical Engineering and Materials ScienceIndian Institute of Technology Bombay400076 Mumbai India;</p> <p>Department of Metallurgical Engineering and Materials ScienceIndian Institute of Technology Bombay400076 Mumbai India;</p> <p>Materials Processing and Corrosion Engineering DivisionBhabha Atomic Research Centre Trombay400085 Mumbai India;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1817.html" title="电化学工业">电化学工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Alloy&option=203" rel="nofollow">Alloy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bipolar Plates&option=203" rel="nofollow">Bipolar Plates;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Coating&option=203" rel="nofollow">Coating;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Corrosion Resistance&option=203" rel="nofollow">Corrosion Resistance;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fuel Cells&option=203" rel="nofollow">Fuel Cells;</a> </p> <div class="translation"> 机译:合金;双极板;涂层;耐腐蚀性;燃料电池; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023515076.html">Corrosion Resistant Al‐Cr‐Mo Alloy Coating on Type 316L Stainless Steel Bipolar Plates for Proton Exchange Membrane Fuel Cell Applications</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ingle A. 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href="/patent-detail/06120764579.html">质子交换膜燃料电池316L不锈钢双极板的表面改性方法</a> <b>[P]</b> . <span> 中国专利: CN101393991B </span> <span> . 2011.06.08</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061201502233.html">一种用于质子交换膜燃料电池不锈钢双极板防护的有序介孔碳-钨涂层的制备方法</a> <b>[P]</b> . <span> 中国专利: CN102978617B </span> <span> . 2014.11.05</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130411189933.html">Multilayer coating for a corrosion-resistant metal bipolar plate for a proton exchange membrane fuel cell (PEMFC)</a> <b>[P]</b> . <span> 外国专利: <!-- 德国专利: --> DE102016102179A1 </span> <span> . 2016-08-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:用于质子交换膜燃料电池(PEMFC)的耐腐蚀金属双极板的多层涂层 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130411190020.html">CORROSION-RESISTANT METAL BIPOLAR PLATE FOR A PROTON EXCHANGE MEMBRANE FUEL CELL (PEMFC) WITH RADICAL RECEIVER</a> <b>[P]</b> . <span> 外国专利: <!-- 德国专利: --> DE102016102393A1 </span> <span> . 2016-08-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:具有自由基接收器的质子交换膜燃料电池(PEMFC)的耐腐蚀金属双极板 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130449004802.html">Proton exchange membrane fuel cell for bipolar separator plate as increased water permeability relative to electronic conductivity; crush strength of plate; functionality of the plate to its ability to maintain water absorption capabilities and increased thermocycling between frozen and thawed state</a> <b>[P]</b> . <span> 外国专利: <!-- --> NZ501432A </span> <span> . 2001-02-23</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:用于双极隔板的质子交换膜燃料电池,相对于电子电导率提高了水的渗透性;板的抗压强度;板的功能性使其能够保持吸水能力并增强冷冻和解冻状态之间的热循环 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704023515076','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p 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