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Multilayer coating for a corrosion-resistant metal bipolar plate for a proton exchange membrane fuel cell (PEMFC)

机译:用于质子交换膜燃料电池(PEMFC)的耐腐蚀金属双极板的多层涂层

摘要

The present disclosure includes a fuel cell bipolar plate having a coating and methods of forming the coating. The bipolar plate may comprise a steel substrate and a coating in contact with the steel substrate. The coating may comprise a plurality of alternating oxide-forming layers and elution-resistant layers. The oxide-forming layers may comprise pure titanium, doped titanium or a titanium alloy (eg doped / alloyed with niobium, zirconium, vanadium, silver, tantalum, yttrium, scandium or nitrogen) and the elution resistant layers may be a noble metal or tantalum (e.g. B. gold, iridium, ruthenium or tantalum). There may be 2 to 20 layers each of the oxide-forming layers and the elution-resistant layers. The coating can prevent elution of iron ions from the steel substrate, for example, by forming oxide plugs in defects or pinholes in the oxide-forming and / or elution-resistant layers. The coating can also reduce the overall consumption of precious metals, such as gold.
机译:本公开包括具有涂层的燃料电池双极板和形成涂层的方法。双极板可包括钢基底和与钢基底接触的涂层。该涂层可以包括多个交替的氧化物形成层和耐洗脱层。形成氧化物的层可以包括纯钛,掺杂的钛或钛合金(例如掺杂/合金化的铌,锆,钒,银,钽,钇,scan或氮),并且耐洗脱层可以是贵金属或钽。 (例如B.金,铱,钌或钽)。氧化物形成层和耐洗脱层中的每一个可以有2至20层。该涂层可以例如通过在氧化物形成和/或耐洗脱层中的缺陷或小孔中形成氧化物塞来防止铁离子从钢基底上洗脱。涂层还可以减少贵金属(例如金)的总体消耗。

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