Preparation, properties, and Li-ion battery application of EC plus PC-modified PVdF-HFP gel polymer electrolyte films

摘要

Based on poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) and lithium tetrafluoroborate (LiBF4) salt along with blending plasticizers, ethylene carbonate (EC) and propylene carbonate (PC), high Li-ion-conducting gel polymer electrolyte films are developed. Their properties are characterized by various techniques. The ambient temperature ionic conductivity of the 85PVdF-HFP:15LiBF(4) + 150(EC + PC) electrolyte film has a high value of 8.1 x 10(-4) S cm(-1). Its crystallinity, melting point, and electrochemical stability window are 9.5%, 115 A degrees C, and 4.6 V, respectively. The mechanical testing shows that the Young's modulus, yield strength, and breaking strain of this electrolyte film are 36.8 MPa, 3.4 MPa, and 320%, respectively. Lithium-ion batteries based on the gel polymer electrolyte film exhibit remarkable charge-discharge and cycling performances. The initial discharge capacity of this battery is as high as 165.1 mAh g(-1) at 0.1 C and just shows a small capacity fading of 4.8% after 120 cycles, indicating that the 85PVdF-HFP:15LiBF(4) + 150(EC + PC) system is an excellent electrolyte candidate for lithium-ion battery applications. The charge-discharge performance of the Li-ion cell fabricated with this gel polymer electrolyte film is apparently better than that of the previously reported Li-ion cells fabricated with other PVdF-HFP-based gel polymer electrolyte films.