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Evaluation of Mechanical Properties of Polymer-Clay Nanocomposites Subjected To Different Environmental Conditions

机译:聚合物黏土纳米复合材料在不同环境条件下的力学性能评价

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Polymer composites have been found striking due to high strength-to-weight ratio, high stiffness-to-weight ratio, corrosion and fatigue resistance. Polymer composites packed with nanometre size particles encounter further properties augmentation to a great extent. Degradation in mechanical properties due to environmental factors such as temperature, moisture and load has also been observed. In this study an attempt is made to scrutinize the deterioration of nanocomposites under natural and accelerated moisture conditions. Epoxy/clay nanocomposites have been fabricated using bidirectional E-glass fiber as reinforcement and epoxy mixed with cloisite 30B as matrix using hand layup method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used for the characterisation of the nano composites. The XRD results validated the intercalation of polymers in clay particles. SEM images showed proper dispersion of clay but clay clusters were found in 5 wt% samples. Tensile strength and hardness increases by 33% and 22% respectively by adding 3 wt% of cloisite 30B nanoclay in epoxy. Modified epoxies showed better resistance to both moisture and temperature under longevity studies. Nanocomposites showed only 36% degradation in strength and hardness deteriorated by 22% when subjected to accelerated conditions.
机译:由于高强度重量比,高刚度重量比,耐腐蚀和耐疲劳性,聚合物复合材料被发现引人注目。填充有纳米尺寸颗粒的聚合物复合材料在很大程度上会进一步提高性能。还已经观察到由于环境因素(例如温度,湿度和负载)导致的机械性能下降。在这项研究中,人们试图研究在自然和加速水分条件下纳米复合材料的变质。环氧树脂/粘土纳米复合材料的制备是使用双向E-玻璃纤维作为增强材料,并通过手工铺层法将环氧树脂与多氯苯磺酸盐30B混合作为基质。 X射线衍射(XRD)和扫描电子显微镜(SEM)用于表征纳米复合材料。 XRD结果证实了聚合物在粘土颗粒中的嵌入。 SEM图像显示了粘土的适当分散,但是在5重量%的样品中发现了粘土团簇。通过在环氧树脂中添加3 wt%的堇青石30B纳米粘土,拉伸强度和硬度分别增加33%和22%。在长寿命研究中,改性环氧树脂对水分和温度的抵抗力都更好。在加速条件下,纳米复合材料的强度仅降低36%,硬度降低22%。

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