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首页> 外文期刊>Adsorption Science & Technology >Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells
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Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells

机译:杏壳中活性炭去除某些染料的色谱柱

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Activated carbons (ACs) were prepared from apricot stone shells impregnated with H_3PO_4, followed by carbonization at 400-500℃ . Fixed-bed removal of two dyestuffs, i.e. Direct Red 99 (DR) and Reactive Orange 11 (RO) was followed at constant bed height and flow rate. Several column characteristics were evaluated from the breakthrough curves obtained including: the volume and loading at breakpoint, the height of the mass transfer zone, the bed service time, the time and loading at exhaustion, and the fractional bed loadings at various stages. The bed performance with RO was better than for DR, which was ascribed to a screening effect towards the large DR molecules and to enhanced adsorption arising from the polyhalogenated nature of the RO molecule. The removal of colour was favoured as the porosity of the AC developed, being particularly related to its mesoporosity and total pore volume.
机译:活性炭(ACs)是由浸有H_3PO_4的杏壳制成的,然后在400-500℃下碳化。在恒定的床高度和流速下,固定床去除两种染料,即直接红99(DR)和活性橙11(RO)。从获得的穿透曲线评估了几个色谱柱的特性,包括:断点处的体积和负载,传质区的高度,床服务时间,排气时间和负载以及各个阶段的分馏床负载。 RO的床性能优于DR,这归因于对大DR分子的筛选作用以及由于RO分子的多卤代性质引起的吸附增强。随着AC孔隙率的提高,颜色的去除受到了青睐,尤其与它的介孔率和总孔体积有关。

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