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Adsorption of Heavy Metals on Coal-based Activated Carbons

机译:煤基活性炭对重金属的吸附

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Zinc chloride-activated and steam-activated carbons were prepared from Maghara coal (Sinai, Egypt). The surface properties of these carbons were determined from nitrogen adsorption isotherm studies at 77 K and of carbon dioxide at 298 K. The adsorption of Methylene Blue from aqueous solution at 308 K was also investigated. The removal of heavy metals (Hg2+, Cd2+ and Pb2+) from aqueous solution was investigated at pH < 7.0 and at 308 K. The prepared activated carbons exhibited high adsorption capacities for Methylene Blue. The maximum capacity amounted to 83 mg dye per g of carbon, which is equivalent to a surface area of 500 m2/g. The capacity for the removal of heavy metals from their aqueous solutions depends on the pH and the extent of activation, i.e., on the amount of zinc chloride used for chemical activation or on the percentage burn-off during physical activation with steam.
机译:氯化锌活化的碳和蒸汽活化的碳是从Maghara煤炭(埃及西奈)制备的。这些碳的表面性质由研究在77 K下的氮吸附等温线和在298 K下的二氧化碳进行了测定。还研究了在308 K下亚甲基蓝从水溶液中的吸附。在pH <7.0和308 K的条件下,研究了从水溶液中去除重金属(Hg2 +,Cd2 +和Pb2 +)的方法。制得的活性炭对亚甲基蓝具有很高的吸附能力。每克碳的最大容量为83毫克染料,相当于500平方米/克的表面积。从其水溶液中去除重金属的能力取决于pH和活化程度,即取决于用于化学活化的氯化锌的量或取决于在用蒸汽进行物理活化过程中的燃尽百分比。

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