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Chars and Activated Carbons Prepared from Asturian Apple Pulp

机译:从阿斯图里亚斯苹果浆制得的炭和活性炭

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Asturian apple pulp was carbonised under nitrogen at 400℃ and 750℃ and subsequently activated with CO_2 at 750℃. The resulting active carbon exhibited properties in line with those expected from precursors of vegetable origin, with the carbonisation stage appearing to have only a limited influence on the final porosity. In the case of carbonisation at 400℃, the initial micropore system of the char was accessible to dichloromethane, CO_2 and water, but presented a strong gate effect at ca. 0.35-0.40 nm. The pore volume, W_0, was equal to 0.13 cm~3/g and the average pore width 0.70 nm. The pore size distribution was obtained from CO_2 adsorption at 0℃, using isotherms derived from computer modelling. With the char prepared at 750℃, the initial porosity was only accessible to water and its presence was confirmed by extrapolation of W_0 for the activated carbons.
机译:阿斯图里亚斯苹果浆在氮气中分别在400℃和750℃碳化,然后在750℃用CO_2活化。所得的活性炭表现出与植物来源的前体所期望的特性一致的特性,并且碳化阶段似乎对最终孔隙率仅具有有限的影响。在400℃下碳化的情况下,焦炭的初始微孔系统易于与二氯甲烷,CO_2和水接触,但在约200℃时表现出很强的门效应。 0.35-0.40纳米。孔体积W_0等于0.13cm〜3 / g,平均孔宽度为0.70nm。孔径分布是利用计算机模拟得出的等温线,从0℃下的CO_2吸附获得的。在750℃制备的炭中,最初的孔隙率仅可通过水获得,并且通过将W_0外推到活性炭可以证实其存在。

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