Electrospinning preparation of NiO/ZnO composite nanofibers for photodegradation of binary mixture of rhodamine B and methylene blue in aqueous solution: Central composite optimization

摘要

One-dimensional nanofiber of p-type NiO/n-type ZnO heterojunctions with various molar ratios of Ni to Zn at different calcination temperatures were successfully synthesized using the electrospinning method, and they were fully characterized. The photocatalysts thus obtained were applied in aqueous solutions for rhodamine B (RDB) and methylene blue (MB) degradation. The p-n heterojunctions built among the cubic structure NiO and hexagonal structure ZnO in the composite nanofiber are responsible for generation of electrons and holes and subsequently superoxide and hydroxyl radical production by carriers which lead to degradation of the dyes in solution. The composite nanofibers (ZnNi1) calcined at 550 degrees C for 3h showed the highest photocatalytic activity for degradation of the dyes in aqueous solution. The optimum values were found to be 180min, 7.0, 1gl(-1) and 3.0 and 3.0mgl(-1) for irradiation time, pH, photocatalyst dosage and initial concentration of RDB and MB, respectively. For these optimum conditions, the photocatalytic degradation of RDB and MB was found to be 99.37 and 98.44%, respectively. The maximum photodegradation of RDB and MB using ZnNi1 was 59.41 and 65.43%, respectively. First-order kinetics based on the Langmuir-Hinshelwood model successfully fitted the experimental data.