Clarity and brilliance: antimony in colourless natron glass explored using Roman glass found in Britain

摘要

This paper discusses the development of Roman antimony decolourised natron glass, its dominance, and subsequent decline, using new trace element data for colourless glass found in Britain. Experimental glasses are used to investigate the influence of different proportions of raw materials (particularly the ratio of natron to calcium carbonate) on the resulting transparency or opacity of glass when antimony is added. Focusing on the 1st to 3rd centuries AD, the study has found that (1) There are chronological differences in antimony colourless glass compositions including (a) some early vessels have abnormally low calcium, aluminium and barium levels; (b) 1st/mid-2nd-century AD vessels in Britain may also contain up to 0.6wt% lead oxide whereas mid-2nd/3rd-century AD vessels contain less than 300ppm, and (c) the antimony content tends to decline over time. (2) These developments can be linked to production and recycling practices; but trace elements suggest that all of these antimony colourless glasses share an origin, probably Egypt. (3) Crucially, production of experimental glasses illustrates the inherent suitability of a sodium-rich, calcium-poor base glass composition for making antimony colourless glass, as it readily dissolves added antimony; conversely lower-sodium, higher-calcium glasses start to form opacifying calcium-antimonate crystals with the same quantities of antimony. Thus, the sodium-rich, calcium-poor glass composition from Egypt was ideally suited for decolourising with antimony and formed a water-clear glass. The calcium-rich Syro-Palestine glasses were more easily opacified with antimony to make opaque glass, but were decolourised with manganese, not antimony.