Halogen bonding of the aldehyde oxygen atom in cocrystals of aromatic aldehydes and 1,4-diiodotetrafluorobenzene

Nemec Vinko; Fotovic Luka; Vitasovic Toni; Cincic Dominik

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Halogen bonding of the aldehyde oxygen atom in cocrystals of aromatic aldehydes and 1,4-diiodotetrafluorobenzene

机译：芳香族醛和1,4-二碘四氟苯甲酸烯酮中醛氧原子的卤素键合

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摘要

Novel halogen bonded cocrystals with 1,4-diiodotetrafluorobenzene and aromatic aldehydes have been synthesized. We present the halogen bond acceptor potential of the aldehyde group oxygen atom in competition with the hydroxy, methoxy and pyridine groups.

机译：已经合成了具有1,4-二碘四氟苯甲苯和芳香族醛的新型卤素键合的酰基。我们在与羟基，甲氧基和吡啶基团的竞争中呈现醛基氧原子的卤素键受体潜力。

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来源
《CrystEngComm 》 |2019年第21期| 共5页
作者
Nemec Vinko; Fotovic Luka; Vitasovic Toni; Cincic Dominik;
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Univ Zagreb Fac Sci Dept Chem Horvatovac 102a HR-10000 Zagreb Croatia;

Univ Zagreb Fac Sci Dept Chem Horvatovac 102a HR-10000 Zagreb Croatia;

Univ Zagreb Fac Sci Dept Chem Horvatovac 102a HR-10000 Zagreb Croatia;

Univ Zagreb Fac Sci Dept Chem Horvatovac 102a HR-10000 Zagreb Croatia;

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正文语种 eng
中图分类化学工业 ; 晶体学 ;
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专利

1. Halogen bonding of the aldehyde oxygen atom in cocrystals of aromatic aldehydes and 1,4-diiodotetrafluorobenzene [J] . Nemec Vinko, Fotovic Luka, Vitasovic Toni, CrystEngComm . 2019 ,第21期

机译：芳香族醛和1,4-二碘四氟苯甲酸烯酮中醛氧原子的卤素键合
2. Effect of N-methyl and ethyl on phosphorescence of carbazole in cocrystals assembled by C-I center dot center dot center dot pi halogen bond, pi-hole center dot center dot center dot pi bond and other interactions using 1,4-diiodotetrafluorobenzene as donor [J] . Zhu Qing, Gao Yuan Jun, Gao Hai Yue, Journal of Photochemistry and Photobiology, A. Chemistry . 2014 ,第Null期

机译：N-甲基和乙基对C-I中心点中心点中心点π型卤素键，pi孔中心点中心点中心π型键和以1,4-二碘四氟苯为供体的其他相互作用组装的共晶体中咔唑磷光的影响
3. Cocrystal Assembled by Pyrene Derivative and 1,4-Diiodotetrafluorobenzene via a C=O···I Halogen Bond [J] . Qi Feng, Wenhui Huan, Jiali Wang, Crystals . 2018 ,第10期

机译：yr衍生物与1,4-二碘四氟苯经C = O··I卤素键组装的共晶体
4. Mechanism of Solid Acid Catalyzed C-C Bond Formation and Oxygen Removal from Aldehydes [C] . Fan Lin, Ya-Huei (Cathy) Chin AIChE annual meeting . 2012

机译：固体酸催化醛键形成C-C键和除氧机理
5. Part I: Copper(I) iodide dimethyl sulfide catalyzed 1,4-addition of alkenyl groups from alkenylzirconium and alkenylzinc reagents and their application toward the total synthesis of azaspirene, and, Part II: Aqueous Wittig chemistry employing stabilized ylides and aldehydes [D] . El-Batta, Amer Adnan 2007

机译：第一部分：碘化亚铜（I）二甲基硫醚从烯基锆和烯基锌试剂中催化烯基的1，4-加成反应及其在氮杂螺碳烯的全合成中的应用，第二部分：采用稳定化的乙炔和醛的水维蒂希化学
6. An atom-economical addition of methyl azaarenes with aromatic aldehydes via benzylic C(sp3)–H bond functionalization under solvent- and catalyst-free conditions [O] . Divya Rohini Yennamaneni, Vasu Amrutham, Krishna Sai Gajula, 2020

机译：通过苄基C（SP3）-H键官能化在溶剂和催化剂条件下与芳香族醛进行原子经济的加入甲基α1azaarenes
7. Cocrystal Assembled by Pyrene Derivative and 1,4-Diiodotetrafluorobenzene via a C=O···I Halogen Bond [O] . Qi Feng, Wenhui Huan, Jiali Wang, 2018

机译：通过芘衍生物和1,4-二碘四氟苯并组装的Cocrystal通过C = O ...... I卤素键组装

Halogen bonding of the aldehyde oxygen atom in cocrystals of aromatic aldehydes and 1,4-diiodotetrafluorobenzene

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