Design of novel three-dimensional coordination polymers based on triangular trinuclear copper 1,2,4-triazolate units

摘要

By controlling the molar ratios of copper dichloride dihydrate and 1,2,4-triazole (trz), we generated a series of novel three-dimensional coordination polymers constructed from mu(3)-oxo or mu(3)- Cl triangular copper units, exhibiting six-connected porous self-penetrating net, graphite layer, and inorganic-organic hybrid network structures, respectively.