Phase Inversion Strategy to Fabricate Porous Carbon for Li‐S Batteries via Block Copolymer Self‐Assembly

Choudhury Soumyadip; Fischer Dieter; Formanek Petr; Stamm Manfred; Ionov Leonid

摘要

Abstract >In this paper, an easy, facile way of preparing porous carbon cathode for lithium–sulfur batteries with superior cycle stability is demonstrated. The highly porous cathode is fabricated by using self‐assembled nanostructured block copolymer as template. The block copolymer template is formed via phase inversion route followed by filling the empty spaces by oligomeric phenolic resin, thermopolymerization of the resin, and finally by carbonization. Semi‐gelled film of self‐assembled block copolymer is immersed in solution of nonsolvent mixture. After washing away of low molecular additive, a highly porous mat is generated. After successful filling with carbon precursor inside the template, crosslinking and carbonization under inert atmosphere result in a highly porous carbon material, which is further hybridized with sulfur via melt diffusion of elemental sulfur. This new fabrication route of template formation by phase inversion requires no solvent/thermal annealing step to generate nanostructure aided by block copolymer. The cathode material shows excellent cycle stability over 240 charging–discharging cycles, rate handling over 100 cycles. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> 在本文中，证实了一种易于，适用于具有优异循环稳定性的锂 - 硫电池的多孔碳阴极。通过使用自组装的纳米结构嵌段共聚物作为模板来制造高度多孔的阴极。通过相转化途径形成嵌段共聚物模板，然后通过寡聚酚醛树脂，树脂的热聚合，最后通过碳化填充空间。将自组装嵌段共聚物的半凝胶化膜浸入非溶剂混合物的溶液中。在洗涤低分子添加剂后，产生高度多孔垫。在成功填充模板内的碳前体之后，在惰性气氛下的交联和碳化导致高度多孔的碳材料，其与元素硫的熔体扩散进一步杂交。通过相位转化的模板形成的新制造途径不需要溶剂/热退火步骤以通过嵌段共聚物产生纳米结构。阴极材料显示出优异的循环稳定性超过240充电放电循环，速率处理超过100个循环。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2018年第5期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Choudhury Soumyadip&option=202" target="_blank" rel="nofollow">Choudhury Soumyadip;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fischer Dieter&option=202" target="_blank" rel="nofollow">Fischer Dieter;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Formanek Petr&option=202" target="_blank" rel="nofollow">Formanek Petr;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Stamm Manfred&option=202" target="_blank" rel="nofollow">Stamm Manfred;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ionov Leonid&option=202" target="_blank" rel="nofollow">Ionov Leonid;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Leibniz‐Institut für Polymerforschung Dresden e.V.Hohe Strasse 6 01069 Dresden Germany;</p> <p>Leibniz‐Institut für Polymerforschung Dresden e.V.Hohe Strasse 6 01069 Dresden Germany;</p> <p>Leibniz‐Institut für Polymerforschung Dresden e.V.Hohe Strasse 6 01069 Dresden Germany;</p> <p>Leibniz‐Institut für Polymerforschung Dresden e.V.Hohe Strasse 6 01069 Dresden Germany;</p> <p>School of EngineeringUniversity of GeorgiaAthens GA 30602 USA;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=block copolymers&option=203" rel="nofollow">block copolymers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cathode&option=203" rel="nofollow">cathode;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium–sulfur batteries&option=203" rel="nofollow">lithium–sulfur batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=phase inversion&option=203" rel="nofollow">phase inversion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=porous carbon&option=203" rel="nofollow">porous carbon;</a> </p> <div class="translation"> 机译：嵌段共聚物;阴极;锂 - 硫磺电池;相反转;多孔碳; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022435838.html">Phase Inversion Strategy to Fabricate Porous Carbon for Li‐S Batteries via Block Copolymer Self‐Assembly</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Choudhury Soumyadip&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Choudhury Soumyadip,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fischer Dieter&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fischer Dieter,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Formanek Petr&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Formanek Petr,</a> <a href="/journal-foreign-18063/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advanced materials interfaces .</a> <span>2018</span><span>,第5期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过嵌段共聚物自组装制造Li-S电池多孔碳的相复转策略</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_thin-solid-films_thesis/020411306993.html">Superhydrophobic porous surface fabricated via phase separation between polyhedral oligomeric silsesquioxane-based block copolymer and polyethylene glycol</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jin Yun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jin Yun,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Peng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Peng,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hou Kun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hou Kun,</a> <a href="/journal-foreign-1112/" target="_blank" rel="nofollow" class="tuijian_authcolor">Thin Solid Films .</a> <span>2018</span><span>,第MARa1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过多面体低聚倍半硅氧烷基嵌段共聚物与聚乙二醇相分离制备的超疏水多孔表面</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070407864084.html">Replication of lyotropic block copolymer mesophases into porous silica by nanocasting: Learning about finer details of polymer self-assembly</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thomas A.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Thomas A.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Schlaad H.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Schlaad H.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Smarsly B.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Smarsly B.,</a> <a href="/journal-foreign-26251/" target="_blank" rel="nofollow" class="tuijian_authcolor">Langmuir: The ACS Journal of Surfaces and Colloids .</a> <span>2003</span><span>,第10期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过纳米浇铸将溶致嵌段共聚物中间相复制到多孔二氧化硅中：了解聚合物自组装的更详细信息</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-265351_thesis/0705017172368.html">Structured Electrochemical Materials Fabricated from Directed Self-Assembly of Block Copolymers and Advanced Lithography</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=L. 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2021</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-2110_thesis/02022397783.html">反应性嵌段共聚物和刷形嵌段共聚物的多级自组装</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈永明&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陈永明</a> <span> <a href="/conference-cn-2110/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第九届全国高聚物分子与结构表征学术讨论会 </a> <span> <span> . 2014</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311517942.html">聚乙烯硅氮烷与三嵌段共聚物自组装制备含纳米相的陶瓷</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王晗&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王晗</a> <span> . 2014</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120109595412.html">控制包含至少一个非极性嵌段和至少一个极性嵌段的嵌段共聚物的合成的方法和这样的嵌段共聚物通过直接自组装在纳米光刻应用中的用途</a> <b>[P]</b> . <span> 中国专利： CN107108824A </span> <span> . 2017-08-29</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061202273628.html">嵌段共聚物及其制造方法、以及使用该嵌段共聚物的高分子电解质材料、高分子电解质成型体及固体高分子型燃料电池</a> <b>[P]</b> . <span> 中国专利： CN103748137B </span> <span> . 2016.12.21</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130405950897.html">- Porous Polymer Membranes Fabricated by the Combination Method of Phase Inversion and Roll-Press and Redox-Flow Battery Comprising the Same</a> <b>[P]</b> . <span> 外国专利：  KR101814716B1 </span> <span> . 2018-01-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-通过相转化和辊压结合的方法制造的多孔聚合物膜和包含该膜的氧化还原液流电池 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130406104323.html">- Porous Polymer Membranes Fabricated by the Combination Method of Phase Inversion and Roll-Press and Redox-Flow Battery Comprising the Same</a> <b>[P]</b> . <span> 外国专利：  KR20170131857A </span> <span> . 2017-12-01</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：-通过相转化和辊压结合的方法制造的多孔聚合物膜和包含该膜的氧化还原液流电池 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130406109925.html">- Carbon electrode for lithium battery using porous carbon black-carbon composite and method for fabricating the same</a> <b>[P]</b> . <span> 外国专利：  KR20170126204A </span> <span> . 2017-11-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> 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