Polyaniline Enriched Flexible Carbon Nanofibers with Core–Shell Structure for High‐Performance Wearable Supercapacitors

Iqbal Nousheen; Wang Xianfeng; Babar Aijaz Ahmed; Yan Jianhua; Yu Jianyong; Park Soo‐Jin; Ding Bin

摘要

Abstract > High performance lightweight and flexible supercapacitors with superior electrochemical performance are in extremely high demand for wearable electronic device applications. Herein, a novel synthesis process is reported for developing highly flexible supercapacitor electrodes from carbon black doped carbon nanofiber/polyaniline core–shell nanofibers via electrospinning followed by carbonization and electrospray techniques. Resultant supercapacitor electrodes offer exceptional specific capacitance (SC) of 501.6 F g ?1 at 0.5 A g ?1 , excellent capacitance retention of 91% even after 5000 cycles, demonstrating a long and stable life of the fabricated device. Moreover, solid state supercapacitor shows no obvious change in SC when subjected to various bending angles up to 180°. This simple three step (i.e., electrospinning, carbonization, and electrospray) fabrication technique paves new insights into the development of lightweight flexible supercapacitors. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 具有卓越电化学性能的高性能轻型和柔性超级电容器对可穿戴电子设备应用的需求极高。在此，据报道了一种新的合成方法，用于通过静电纺丝随后通过透明纺丝和电喷雾技术从炭黑掺杂的碳纳米纤维/聚苯胺核 - 壳纳米纤维上显影高度柔性超级电容器电极。得到的超级电容器电极提供优异的特定电容（SC）为501.6 f g ？1 </ sup> 在0.5克？1 </ sup> 即使在5000次循环之后，优异的电容保留为91％，展示了制造装置的长且稳定的寿命。此外，当经受多达180°的各种弯曲角度时，固态超级电容器显示出SC的明显变化。这种简单的三步（即，静电纺丝，碳化和电喷雾）制造技术对轻质柔性超级电容器的开发铺平了新的见解。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2017年第24期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Iqbal Nousheen&option=202" target="_blank" rel="nofollow">Iqbal Nousheen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Xianfeng&option=202" target="_blank" rel="nofollow">Wang Xianfeng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Babar Aijaz Ahmed&option=202" target="_blank" rel="nofollow">Babar Aijaz Ahmed;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan Jianhua&option=202" target="_blank" rel="nofollow">Yan Jianhua;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Jianyong&option=202" target="_blank" rel="nofollow">Yu Jianyong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Park Soo‐Jin&option=202" target="_blank" rel="nofollow">Park Soo‐Jin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ding Bin&option=202" target="_blank" rel="nofollow">Ding Bin;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsDonghua UniversityShanghai 201620 China;</p> <p>State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsDonghua UniversityShanghai 201620 China;</p> <p>State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsDonghua UniversityShanghai 201620 China;</p> <p>Key Laboratory of Textile Science &</p> <p>TechnologyDonghua UniversityShanghai 201620 China;</p> <p>Innovation Center for Textile Science and TechnologyDonghua UniversityShanghai 200051 China;</p> <p>Department of ChemistryInha University100 Inharo Incheon 402‐751 South Korea;</p> <p>State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsDonghua UniversityShanghai 201620 China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon nanofibers&option=203" rel="nofollow">carbon nanofibers;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrospray&option=203" rel="nofollow">electrospray;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=flexibility&option=203" rel="nofollow">flexibility;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyaniline&option=203" rel="nofollow">polyaniline;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polybenzoxazine&option=203" rel="nofollow">polybenzoxazine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=wearable supercapacitors&option=203" rel="nofollow">wearable supercapacitors;</a> </p> <div class="translation"> 机译：碳纳米纤维;电喷雾;柔韧性;聚苯胺;聚苯苯胺胺;可穿戴超级电容器; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> 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A.,</a> <span>2013</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于硅涂层垂直排列碳纳米纤维核壳异质结构的高性能锂离子电池正极。</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-shanghai-polytechnic-university_thesis/0201280051314.html">聚苯胺/碳纳米纤维超级电容器电极材料的制备及其性能</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=石俊峰&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 石俊峰</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何陈&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,何陈</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李靖&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李靖</a> <span> <a href="/journal-cn-7450/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 上海第二工业大学学报 </a> </span> <span> . 2020</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-tianjin-polytechnic-university_thesis/0201210628793.html">柔性自支撑介孔碳纳米纤维的制备及其在超级电容器电极上的应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=时志强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 时志强</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=靳国强&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,靳国强</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王静</a> <span> <a href="/journal-cn-7614/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 天津工业大学学报 </a> </span> <span> . 2017</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_computer-engineering-applications_thesis/0201241487637.html">一种适用于服务器的具有高可靠性可扩展性高性能的新一代I/O体系结构</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵振龙&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵振龙</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李之棠&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李之棠</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄辉龙&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄辉龙</a> <span> <a href="/journal-cn-8897/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 计算机工程与应用 </a> </span> <span> . 2002</span><span>,第010期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-7084_thesis/020221847677.html">具有高能量密度的石墨烯/三氧化钼/聚苯胺三体系超级电容器材料</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xia Xifeng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 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