Surface Passivation toward Highly Stable Mn        <sup >4+4+        ‐Activated Red‐Emitting Fluoride Phosphors and Enhanced Photostability for White LEDs

Zhou Yayun; Song Enhai; Deng Tingting; Wang Yuanjing; Xia Zhiguo; Zhang Qinyuan

摘要

Abstract > Mn 4+ ‐activated red‐emitting fluoride phosphors are indispensable candidates for white light emitting diodes (WLEDs) with enhanced color rendition, however, their intrinsic hydrolysis characteristics seriously restricted the durability applications. Here, a facile and general postsynthetic hydrogen peroxide (H <sub>2</sub> O <sub>2</sub> ) surface passivation strategy is proposed to treat the K <sub>2</sub> XF <sub>6</sub> :Mn 4+ (KXF, X = Ti, Si, Ge) phosphors, in which a Mn 4+ ‐rare surface protective layer appears and further covers the corresponding particles. The environment moisture can be effectively isolated by the Mn 4+ ‐rare surface passivation layer with low solubility, which will be sacrificed to protect the phosphor particles even if under extreme hydrolysis conditions. The relative external quantum efficiency of the optimized phosphors still maintains over 96% after the passivation treatment, and the relative luminous intensity still remain 97% even when soaked in water after 12 h. The correlated color temperature of high‐power WLEDs fabricated by the passivated phosphors has no remarkable change during aging process (100 days) in the high temperature (85 °C) and high humidity atmosphere (85%). It is expected that such a surface‐redox strategy can be expanded to other doped materials systems, and also opening a new perspective for the development of luminescence materials with enhanced surface stability and device duration. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > MN. 4 + </ sup> - 活化的红色发光氟化物磷光体是白光发光二极管（WLED）的不可或缺的候选候选者，然而，它们的内在水解特性严重限制了耐久性应用。在这里，一个容易和一般的后合成氢过氧化氢（h <sub> 2 </ sub> O. <sub> 2 </ sub> ）建议表面钝化策略来治疗k <sub> 2 </ sub> XF. <sub> 6 </ sub> ：Mn. 4 + </ sup> （kxf，x = ti，si，ge）磷光体，其中一个mn 4 + </ sup> -Rare表面保护层出现并进一步覆盖相应的颗粒。锰可以有效地分离环境水分 4 + </ sup> -Rare具有低溶解度的表面钝化层，即使在极端水解条件下，也会处死以保护磷光体颗粒。优化磷光体的相对外部量子效率仍保持在钝化处理后超过96％，即使在12小时后浸泡在水中，相对发光强度仍然保持97％。由钝化磷光体制造的高功率WLED的相关色温在高温（85℃）和高湿度气氛（85％）中老化过程（100天）无显着变化。预计这种表面氧化还原策略可以扩展到其他掺杂的材料系统，并且还开辟了具有增强的表面稳定性和装置持续时间的发光材料的新视角。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2019年第9期</span><b style="margin: 0 2px;">|</b><span>共15页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Yayun&option=202" target="_blank" rel="nofollow">Zhou Yayun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Enhai&option=202" target="_blank" rel="nofollow">Song Enhai;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Deng Tingting&option=202" target="_blank" rel="nofollow">Deng Tingting;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Yuanjing&option=202" target="_blank" rel="nofollow">Wang Yuanjing;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Xia Zhiguo&option=202" target="_blank" rel="nofollow">Xia Zhiguo;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Qinyuan&option=202" target="_blank" rel="nofollow">Zhang Qinyuan;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510641 P. R. China;</p> <p>State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510641 P. R. China;</p> <p>State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510641 P. R. China;</p> <p>State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510641 P. R. China;</p> <p>State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510641 P. R. China;</p> <p>State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510641 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mn 4+ ‐activated phosphors&option=203" rel="nofollow">Mn 4+ ‐activated phosphors;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=moisture resistance&option=203" rel="nofollow">moisture resistance;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photostability&option=203" rel="nofollow">photostability;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=surface passivation&option=203" rel="nofollow">surface passivation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=white light‐emitting diodes&option=203" rel="nofollow">white light‐emitting diodes;</a> </p> <div class="translation"> 机译：Mn 4+ - 活化的磷光体;耐湿性;光稳定性;表面钝化;白色发光二极管; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022434526.html">Surface Passivation toward Highly Stable Mn <sup >4+4+ ‐Activated Red‐Emitting Fluoride Phosphors and Enhanced Photostability for White LEDs</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhou Yayun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhou Yayun,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Enhai&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Song Enhai,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Deng Tingting&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Deng Tingting,</a> <a href="/journal-foreign-18063/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advanced materials interfaces .</a> <span>2019</span><span>,第9期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：表面钝化朝高稳定的Mn 4 + </ sup> 4+ - 用于白色LED的增强的红色发光荧光磷光体和增强的光稳定性</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704025682007.html">Moisture-resistant and highly efficient narrow-band red-emitting fluoride phosphor K2NaGaF6:Mn4+ for warm white LED application</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gao Jun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gao Jun,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Haomiao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhu Haomiao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Renfu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Renfu,</a> <a href="/journal-foreign-35178/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Materials Chemistry, C. materials for optical and electronic devices .</a> <span>2019</span><span>,第26期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：耐湿且高效的窄带红发射氟化物K2NAGAF6：MN4 +用于暖白LED应用</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020052235.html">Mn4+-activated Li3Mg2SbO6 as an ultrabright fluoride-free red-emitting phosphor for warm white light-emitting diodes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wang Shaoying&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wang Shaoying,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sun Qi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sun Qi,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Devakumar Balaji&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Devakumar Balaji,</a> <a href="/journal-foreign-27299/" target="_blank" rel="nofollow" class="tuijian_authcolor">RSC Advances .</a> <span>2019</span><span>,第6期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：MN4 +活化的Li3mg2SbO6作为无氟化物的无氟红发磷，用于温暖的白色发光二极管</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-288386_thesis/0705016972591.html">Orange-Red Emitting Phosphors Sm3+-Activated Borosilicate for near UV-based White LEDs</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hong Yu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hong Yu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jinlei Chen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jinlei Chen </a> <a href="/conference-foreign-288386/" target="_blank" rel="nofollow" class="tuijian_authcolor">International Conference on Logistics, Engineering, Management and Computer Science .</a> <span>2015</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：橙红色发射磷光体SM3 +近紫外线白色LED的致死硼硅酸盐</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061581836.html">Electrophoretic Deposition of Highly Efficient Phosphors for White Solid State Lighting using near UV-Emitting LEDs.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Choi, Jae Ik.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Choi, Jae Ik. </a> <span>2014</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用近紫外发光LED电泳沉积用于白色固态照明的高效荧光粉。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040005225564.html">Large Negative-Thermal-Quenching Effect in Phonon-InducedLight Emissions in Mn4+-Activated Fluoride Phosphor forWarm-White Light-Emitting Diodes</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fei Tang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Fei Tang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=§&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">§,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhicheng Su&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhicheng Su,</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：声子诱导的大负热猝灭效应Mn4 +活化的氟化物荧光粉的发光暖白色发光二极管</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000127793552.html">Highly Stable Mn4+-Activated Red-Emitting Fluoride Phosphors and Enhanced moisture stability for White LEDs</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wenting Cai&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Wenting Cai </a> <span>2021</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：高度稳定的MN4 +活化的红发氟化物磷光体，并为白光LED提高了水分稳定性</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/ntis-science-report_de_thesis/0207150696.html">Solid State Lighting Program, Final Report, Phosphors for Near UV-Emitting LEDs for Efficacious Generation of White Light.</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=McKittrick, J.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">McKittrick, J. </a> <span>2013</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：固态照明计划，最终报告，近紫外发光LED用于有效产生白光的荧光粉。</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_nonferrous-metals-science-engineering_thesis/0201281906047.html">阳离子引入对CsPF6:Mn^4+红色荧光粉发光性能的影响</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何盛安&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 何盛安</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐范范&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,徐范范</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=吴迪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,吴迪</a> <span> <a href="/journal-cn-22444/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 有色金属科学与工程 </a> </span> <span> . 2020</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_science-technology-journal-electronic-edition_thesis/0201294868135.html">红色荧光粉Ba6Y2W3O18:Mn^4+的制备及发光性能的研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=于文静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 于文静</a> <span> <a href="/journal-cn-52168/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 科教导刊：电子版 </a> </span> <span> . 2019</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_science-technology-journal-electronic-edition_thesis/0201294765436.html">新型红色荧光粉Sr9Y2W4O24:Mn^4+的制备及发光性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陆盈盈&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 陆盈盈</a> <span> <a href="/journal-cn-52168/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 科教导刊：电子版 </a> </span> <span> . 2019</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-physica-sinica_thesis/0201297116437.html">深红色Mg_(1+y)Al_(2-x)O_4:xMn^(4+),yMg^(2+)荧光粉的合成与发光性质</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=彭玲玲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 彭玲玲</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=曹仕秀&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,曹仕秀</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵聪&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵聪</a> <span> <a href="/journal-cn-15096/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 物理学报 </a> </span> <span> . 2018</span><span>,第18期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-yunnan-nationalities-university-natural-science-edition_thesis/0201297689228.html">白光LED用K_(2)TaF_(7)∶Mn^(4+)红色发光晶体发光性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=汪正良&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 汪正良</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李童&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李童</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=袁俊恒&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,袁俊恒</a> <span> <a href="/journal-cn-51017/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 云南民族大学学报:自然科学版 </a> </span> <span> . 2021</span><span>,第5期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-6815_thesis/020221761889.html">葡萄糖水浴处理用于CdTe量子点的荧光性和稳定性增强</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Wenfeng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Zhu Wenfeng</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱文凤&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱文凤</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Xiaoheng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Liu Xiaoheng</a> <span> <a href="/conference-cn-6815/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十届全国博士生学术年会 </a> <span> <span> . 2012</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314743386.html">用于单芯片红蓝双光LED的BaMgSiO：Eu，Mn荧光体的荧光增强效应的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘凌云&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘凌云</a> <span> . 2009</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120112014799.html">一种Mn<Sup>4+</Sup>激活的铝磷酸盐红色荧光粉及其制备方法和在植物生长发光二极管中的应用</a> <b>[P]</b> . <span> 中国专利： CN111996003A </span> <span> . 2020-11-27</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120100174151.html">合成和制造具有高量子效率和显著增强的热和光稳定性的混合发光磷光体的基于前体的方法</a> <b>[P]</b> . <span> 中国专利： CN109311913A </span> <span> . 2019-02-05</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130415660637.html">White phosphors, methods of making white phosphors, white light emitting LEDS, methods of making white light emitting LEDS, and light bulb structures</a> <b>[P]</b> . <span> 外国专利：  US9157584B2 </span> <span> . 2015-10-13</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：白磷，制造白磷的方法，发白光的LED，制造白光的LED的方法以及灯泡结构 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130415542037.html">WHITE PHOSPHORS, METHODS OF MAKING WHITE PHOSPHORS, WHITE LIGHT EMITTING LEDS, METHODS OF MAKING WHITE LIGHT EMITTING LEDS, AND LIGHT BULB STRUCTURES</a> <b>[P]</b> . <span> 外国专利：  US2015123536A1 </span> <span> . 2015-05-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：白磷，白磷的制造方法，白光发光二极管，白光发光二极管的制造方法和灯泡结构 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130415387747.html">White phosphors, methods of making white phosphors, white light emitting LEDs, methods of making white light emitting LEDs, and light bulb structures</a> <b>[P]</b> . <span> 外国专利：  US9011717B2 </span> <span> . 2015-04-21</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：白磷，制造白磷的方法，发白光的LED，制造白光的LED的方法以及灯泡结构 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022434526','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704022434526down" data-source="7," data-out-id="ve1y+fNd9JbuyF0rQVpaxnVom9/veGD+Vg/l40qgRqy1y3dwb9YyAgb7uD+5/2rB," data-f-source-id="7" data-title="Surface Passivation toward Highly Stable Mn <sup >4+4+ ‐Activated Red‐Emitting Fluoride Phosphors and Enhanced Photostability for White LEDs" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="0704022434526" id="docid"> <input type="hidden" value="18063" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Surface Passivation toward Highly Stable Mn <sup >4+4+ ‐Activated Red‐Emitting Fluoride Phosphors and Enhanced Photostability for White LEDs"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/page.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/reference.js?v=5.8.0"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.8.0"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.8.0"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>

Surface Passivation toward Highly Stable Mn 4+4+ ‐Activated Red‐Emitting Fluoride Phosphors and Enhanced Photostability for White LEDs

摘要

Surface Passivation toward Highly Stable Mn ^{4+4+ ‐Activated Red‐Emitting Fluoride Phosphors and Enhanced Photostability for White LEDs}