A Controlled Carburization Process to Obtain Graphene–Fe        <sub >3</sub>3        C–Fe Composites

You Yi; Yoshimura Masamichi; Cholake Sagar; Lee Gwan‐Hyoung; Sahajwalla Veena; Joshi Rakesh

摘要

Abstract > Significant progresses have been made toward the understanding of graphene growth on metal substrates via chemical vapor deposition method. Cu and Ni are the most studied catalysts for producing high‐quality graphene. Among the transitional metal group, Fe also has the potential as a substrate for growth of graphene. However, the complexity of phase transformation in Fe and the thermodynamically preferable formation of iron carbide at the ambient temperature limit extensive use of Fe for graphene growth. Herein, the concurrent formation of graphene and Fe <sub>3</sub> C by optimizing the growth time and cooling rate in graphene growth on Fe substrate is reported. Also, the influence of Fe phases (ferrite and austenite) on the graphene growth is studied. Graphene grain growth on Fe substrate is observed via ultrahigh temperature confocal microscope. The in situ observation confirms that graphene grains are grown around the Fe grain boundaries during the cooling process. The systematic study provides a profound insight into graphene growth on Fe substrate and thus paves a way toward development of graphene‐based steel products for various applications. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 通过化学气相沉积法对金属基材上的石墨烯生长进行了重大进展。 Cu和Ni是用于生产高质量石墨烯的最常用催化剂。在过渡金属基团中，Fe也具有作为石墨烯生长的基材的潜力。然而，在环境温度极限在环境温度极限在环境温度下大量使用Fe进行石墨烯生长的“铁碳化铁的复杂性和热力学上变化的复杂性。在此，石墨烯和Fe的并发形成 <sub> 3 </ sub> C通过优化Fe衬底优化石墨烯生长中的生长时间和冷却速率。而且，研究了Fe阶段（铁氧体和奥氏体）对石墨烯生长的影响。通过超高温度共聚焦显微镜观察Fe衬底上的石墨烯颗粒生长。原位观察证实，在冷却过程中，石墨烯晶体在Fe晶界周围生长。系统研究提供了Fe衬底上石墨烯生长的深刻洞察力，从而为各种应用铺平了基于石墨烯的钢产品的发展。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2018年第16期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=You Yi&option=202" target="_blank" rel="nofollow">You Yi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yoshimura Masamichi&option=202" target="_blank" rel="nofollow">Yoshimura Masamichi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cholake Sagar&option=202" target="_blank" rel="nofollow">Cholake Sagar;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lee Gwan‐Hyoung&option=202" target="_blank" rel="nofollow">Lee Gwan‐Hyoung;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sahajwalla Veena&option=202" target="_blank" rel="nofollow">Sahajwalla Veena;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Joshi Rakesh&option=202" target="_blank" rel="nofollow">Joshi Rakesh;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>SMaRT CenterUniversity of New South WalesSydney 2052 Australia;</p> <p>Surface Science LaboratoryToyota Technological InstituteNagoya 468‐8511 Japan;</p> <p>SMaRT CenterUniversity of New South WalesSydney 2052 Australia;</p> <p>Department of Materials Science and EngineeringYonsei UniversitySeoul 03722 South Korea;</p> <p>SMaRT CenterUniversity of New South WalesSydney 2052 Australia;</p> <p>SMaRT CenterUniversity of New South WalesSydney 2052 Australia;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chemical vapor deposition&option=203" rel="nofollow">chemical vapor deposition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphene–Fe 3 C–Fe composites&option=203" rel="nofollow">graphene–Fe 3 C–Fe composites;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=graphene growth&option=203" rel="nofollow">graphene growth;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=in situ high temperature confocal microscope&option=203" rel="nofollow">in situ high temperature confocal microscope;</a> </p> <div class="translation"> 机译：化学气相沉积;石墨烯-FE 3 C-FE复合材料;石墨烯生长;原位高温共聚焦显微镜; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022434444.html">A Controlled Carburization Process to Obtain Graphene–Fe <sub >3</sub>3 C–Fe Composites</a> <b>[J]</b> . <span> <a 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href="/conference-cn-61473/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2016年全国特钢年会 </a> <span> <span> . 2016</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020311937017.html">RNA干扰技术阻断c-fes表达对HL-60细胞增殖、分化和凋亡的影响</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋婷婷&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 宋婷婷</a> <span> . 2010</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120103916692.html">一种航空渗碳零件渗碳过程受控方法</a> <b>[P]</b> . <span> 中国专利： CN111364000A </span> <span> . 2020-07-03</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/061202981882.html">帐篷型框架结构的石墨烯/FeSn-纳米棒阵列/石墨烯复合材料的合成方法</a> <b>[P]</b> . <span> 中国专利： CN105789591B </span> <span> . 2018.08.24</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130422024397.html">GRAPHENE - IRON OXIDE COMPOSITE AND A MANUFACTURING METHOD THEREOF CAPABLE OF EASILY CONTROLLING SPECIFIC SURFACE AREA, CONDUCTIVITY AND HEAVY METAL ELIMINATION CAPACITY OF THE GRAPHENE - FERRIC OXIDE COMPOSITE</a> <b>[P]</b> . <span> 外国专利：  KR20120076131A </span> <span> . 2012-07-09</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：石墨烯-氧化铁复合材料及其制造方法可轻松控制石墨烯-氧化铁复合材料的比表面积，电导率和重金属消除能力 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130417741168.html">SUBSTITUTED AMINO-THIOUREA COMPOSITES, COMPOSITION, METHODS FOR COMBATING OR CONTROLING INSECTS, ARACHIDS OR NEMATOIDS, TO PROTECT GROWING PLANTS FROM THE ATTACK OR INFESTATION BY INSECTS, ARACHNES AND NESTLES OF THE INSIDES AND NESTLES OF THE INSIDES AND NEMATOSES FOR THE INSECTS, NESTLES AND SOILS. OF SOIL INSECTS AND LEAVES AND TO TREAT, CONTROL, PREVENT OR PROTECT ANIMALS AGAINST INFESTATION OR INFECTION BY PARASITES, SEED, USE OF COMPOUNDS, AND, PROCESS FOR THE PREPARATION OF A COMPOSITION.</a> <b>[P]</b> . <span> 外国专利：  BRPI0811227A2 </span> <span> . 2014-10-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：取代的氨基-硫脲复合物，成分，防治或控制昆虫，花生或线虫的方法，以保护生长中的植物免受昆虫，蛛网和鼻孔的侵袭，侵袭和侵害。土壤。防止，控制，预防或保护动物免受寄生虫侵染或侵染，种子，化合物的使用以及制备组合物的过程。 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130475542155.html">Compound of ether difenilico process for the preparation of eteres difenilicos herbicide composition for desiccation of leaf composition process for the preparation of a composite herbicide or a coMposicao for desiccation of leaf process for controlling unwanted plant and process for the desiccation of leaf in plantacao Agricola or horticola</a> <b>[P]</b> . <span> 外国专利：  BR8206447A </span> <span> . 1983-09-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：醚二苯醚化合物的化合物，用于制备用于茎叶脱水的二苯醚二酯除草剂组合物，用于制备复合除草剂或用于叶片干燥的复方制剂的方法，用于控制不需要的植物的方法，以及用于在植物草中生长的方法。 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022434444','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> 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A Controlled Carburization Process to Obtain Graphene–Fe 33 C–Fe Composites

摘要

A Controlled Carburization Process to Obtain Graphene–Fe ₃3 C–Fe Composites