Nitrogen‐Doped Hierarchical Porous Carbon Architecture Incorporated with Cobalt Nanoparticles and Carbon Nanotubes as Efficient Electrocatalyst for Oxygen Reduction Reaction

Zhu Chunyu; Kim Cheong; Aoki Yoshitaka; Habazaki Hiroki

摘要

Abstract >Hierarchical porous carbon has attracted great interest because of its distinctive structure and superior properties for designing electrochemical energy storage and conversion devices. In this work, a novel method to fabricate nitrogen‐doped hierarchical porous carbon (NHPC) is reported, which is incorporated with Co nanoparticles and carbon nanotubes (CNTs). The NHPC is prepared using a facile and scalable MgO–Co template method. Metal nitrate–glycine solution combustion synthesis, followed by a high temperature calcination, is used to prepare MgO–Co/N‐doped carbon precursor. CNTs are formed by the in situ Co‐catalytic growth during heat treatment; at the same time, localized graphitic layers are also formed around the Co nanoparticles. After acid washing, NHPC with hierarchical multipores and ultrafine Co nanoparticles is obtained. When applied as oxygen reduction reaction (ORR) catalyst, the NHPC displays high catalytic activity not only in terms of onset potential and current density, but also superior durability and tolerance to methanol crossover in alkaline electrolyte. The remarkable ORR activity is originated from the cooperative effects of high specific surface area, hierarchical pore structure, ultrasmall Co nanocrystals, localized graphitic layers, CNTs, and N‐doping. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >等级多孔碳由于其独特的结构和用于设计电化学能量存储和转换装置的优异性能而引起了极大的兴趣。在这项工作中，报道了一种制造氮掺杂分层多孔碳（NHPC）的新方法，其掺入Co纳米颗粒和碳纳米管（CNT）。使用舒适性和可伸缩的MgO-Co模板方法制备NHPC。金属硝酸盐 - 甘氨酸溶液燃烧合成，其次是高温煅烧，用于制备MgO-Co / N-掺杂的碳前体。通过在热处理期间原位助催化生长形成CNT;同时，局部的石墨层也在CO纳米颗粒周围形成。在酸洗后，获得具有分层多孔和超细Co纳米颗粒的NHPC。当施加氧还原反应（ORR）催化剂时，NHPC不仅在发作潜在和电流密度方面显示出高催化活性，而且在碱性电解质中的甲醇交叉的耐久性和耐受性优异。显着的ORR活性源自高比表面积，分层孔结构，超焦载体纳米晶体，局部石墨层，CNT和N-掺杂的协同效果。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2017年第19期</span><b style="margin: 0 2px;">|</b><span>共11页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Chunyu&option=202" target="_blank" rel="nofollow">Zhu Chunyu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kim Cheong&option=202" target="_blank" rel="nofollow">Kim Cheong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aoki Yoshitaka&option=202" target="_blank" rel="nofollow">Aoki Yoshitaka;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Habazaki Hiroki&option=202" target="_blank" rel="nofollow">Habazaki Hiroki;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Division of Applied Chemistry and Frontier Chemistry CenterHokkaido UniversitySapporo Hokkaido 060‐8628 Japan;</p> <p>Division of Applied Chemistry and Frontier Chemistry CenterHokkaido UniversitySapporo Hokkaido 060‐8628 Japan;</p> <p>Division of Applied Chemistry and Frontier Chemistry CenterHokkaido UniversitySapporo Hokkaido 060‐8628 Japan;</p> <p>Division of Applied Chemistry and Frontier Chemistry CenterHokkaido UniversitySapporo Hokkaido 060‐8628 Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon nanotubes&option=203" rel="nofollow">carbon nanotubes;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cobalt&option=203" rel="nofollow">cobalt;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=combustion synthesis&option=203" rel="nofollow">combustion synthesis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxygen reduction reaction&option=203" rel="nofollow">oxygen reduction reaction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=porous carbon&option=203" rel="nofollow">porous carbon;</a> </p> <div class="translation"> 机译：碳纳米管;钴;燃烧合成;氧还原反应;多孔碳; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022434319.html">Nitrogen‐Doped Hierarchical Porous Carbon Architecture Incorporated with Cobalt Nanoparticles and Carbon Nanotubes as Efficient Electrocatalyst for Oxygen Reduction Reaction</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Chunyu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhu Chunyu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kim Cheong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kim Cheong,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aoki Yoshitaka&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Aoki Yoshitaka,</a> <a href="/journal-foreign-18063/" target="_blank" rel="nofollow" class="tuijian_authcolor">Advanced materials interfaces .</a> <span>2017</span><span>,第19期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：掺杂钴纳米颗粒和碳纳米管的氮掺杂分层多孔碳结构，作为氧还原反应的有效电催化剂</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-energy-chemistry_thesis/0201278121622.html">Controllable active sites and facile synthesis of cobalt nanoparticle embedded in nitrogen and sulfur co-doped carbon nanotubes as efficient bifunctional electrocatalysts for oxygen reduction and evolution reactions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Taeseob Oh&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Taeseob Oh,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kwanwoo Kim&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kwanwoo Kim,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jooheon Kim&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jooheon Kim </a> <a href="/journal-foreign-17563/" target="_blank" rel="nofollow" class="tuijian_authcolor">能源化学：英文版 .</a> <span>2019</span><span>,第011期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：可嵌入氮和硫共掺杂碳纳米管中的钴纳米粒子的可控活性位点和合成简便，可作为有效的双功能电催化剂，用于氧还原和放出反应</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028133734.html">Hydrothermal Synthesis of Highly Dispersed Co3O4 Nanoparticles on Biomass-Derived Nitrogen-Doped Hierarchically Porous Carbon Networks as an Efficient Bifunctional Electrocatalyst for Oxygen Reduction and Evolution Reactions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guan Jianli&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guan Jianli,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhang Zhengping&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhang Zhengping,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ji Jing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ji Jing,</a> <a href="/journal-foreign-18786/" target="_blank" rel="nofollow" class="tuijian_authcolor">ACS applied materials & interfaces .</a> <span>2017</span><span>,第36期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：在生物质衍生的氮气掺杂的分层型多孔碳网络上高度分散的CO3O4纳米颗粒的水热合成作为氧还原和进化反应的有效双官能电催化剂</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-293806_thesis/0705018829099.html">Electrocatalysts Based on Cobalt- and Nitrogen-Doped Nanocarbon Composites for Oxygen Reduction Reaction and Anion Exchange Membrane Fuel Cells</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jaana Lilloja&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jaana Lilloja,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Elo Kibena-Poldsepp&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Elo Kibena-Poldsepp,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ave Sarapuu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ave Sarapuu,</a> <a href="/conference-foreign-293806/" target="_blank" rel="nofollow" class="tuijian_authcolor">Pacific Rim Meeting on Electrochemical and Solid-State Science .</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于钴和氮掺杂纳米碳复合材料的电催化剂用于氧还原反应和阴离子交换膜燃料电池</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061194410.html">Oxygen reduction reaction and supercapacitor studies of cobalt complexes/carbon nanotube composites and phosphorous, nitrogen doped carbon materials.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Nasini, Udaya Bhasker.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Nasini, Udaya Bhasker. </a> <span>2013</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：钴配合物/碳纳米管复合材料和磷，氮掺杂碳材料的氧还原反应和超级电容器研究。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040001806939.html">Novel Porous Nitrogen Doped Graphene/Carbon Black Composites as Efficient Oxygen Reduction Reaction Electrocatalyst for Power Generation in Microbial Fuel Cell</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yuan Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yuan Liu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhimei Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhimei Liu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hong Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hong Liu,</a> <span>2019</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：新型氮掺杂石墨烯/炭黑多孔复合材料作为微生物燃料电池发电中的高效氧还原反应电催化剂</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000129434059.html">Paper-derived cobalt and nitrogen co-doped carbon nanotube@porous carbon as a nonprecious metal electrocatalyst for the oxygen reduction reaction</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gaopeng Liu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gaopeng Liu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bin Wang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bin Wang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Xu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Xu,</a> <span>2018</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：纸衍生的钴和氮掺杂碳纳米管@多孔碳作为氧还原反应的非匮乏金属电催化剂</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201231561278.html">非贵金属钴、氮共掺杂碳纳米管负载纸衍生多孔碳电催化剂的制备及其氧还原性能研究</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘高鹏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘高鹏</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王彬&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王彬</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐丽&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,徐丽</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 2018</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201273767014.html">有机膦酸盐衍生的氮掺杂的磷酸钴/碳纳米管杂化材料作为高效氧还原电催化剂</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵挥&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 赵挥</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=翁晨晨&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,翁晨晨</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=任金涛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,任金涛</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 2020</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_acta-physico-chimica-sinica_thesis/0201251030036.html">氮、硫共掺杂的碳负载的钴@碳化钴:一种高效的非贵金属氧还原电催化剂</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=申海波&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 申海波</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=江浩&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,江浩</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘易斯&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘易斯</a> <span> <a href="/journal-cn-15102/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 物理化学学报 </a> </span> <span> . 2017</span><span>,第009期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_applied-chemical-industry_thesis/0201271063411.html">基于ZIF-8衍生氮掺杂多孔碳的高稳定性氧还原催化剂</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=薛师&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 薛师</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李静&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,李静</a> <span> <a href="/journal-cn-9217/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 应用化工 </a> </span> <span> . 2018</span><span>,第012期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_guangdong-chemical-industry_thesis/0201280176423.html">铁钴氮共掺杂中空碳纳米颗粒的制备及氧还原催化活性</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘学安&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 刘学安</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=金娜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,金娜</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋肖锴&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋肖锴</a> <span> <a href="/journal-cn-9122/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广东化工 </a> </span> <span> . 2020</span><span>,第017期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-41598_thesis/020222485838.html">氮钴双掺杂的石墨化碳封装高分散钴纳米颗粒催化析氢反应</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yao Wang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Yao Wang</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王尧&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,王尧</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zidong Wei&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Zidong Wei</a> <span> <a href="/conference-cn-41598/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 2016新能源新材料研究生论坛 </a> <span> <span> . -1</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314860692.html">钴、氮掺杂多孔碳作为氧还原催化剂的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=葛余俊&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 葛余俊</a> <span> . 2015</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06120100544413.html">一种CoP纳米颗粒嵌入的氮掺杂多孔碳纳米管电解水催化剂及其制备方法</a> <b>[P]</b> . <span> 中国专利： CN109746008A </span> <span> . 2019-05-14</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120111431615.html">一种封装金属钴纳米颗粒的氮掺杂碳纳米管复合型催化剂及其应用</a> <b>[P]</b> . <span> 中国专利： CN108923051A </span> <span> . 2018-11-30</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130403341769.html">Preparing method of nitrogen-iron doped porous carbon nanoparticle catalyst for oxygen reduction reaction</a> <b>[P]</b> . <span> 外国专利：  KR101932612B1 </span> <span> . 2018-12-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：氮铁掺杂的多孔碳纳米粒子用于氧还原反应的催化剂的制备方法 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130405956047.html">Preparing method of nitrogen-iron doped porous carbon nanoparticle catalyst for oxygen reduction reaction</a> <b>[P]</b> . <span> 外国专利：  KR20180119351A </span> <span> . 2018-11-02</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：氮铁掺杂的多孔碳纳米粒子用于氧还原反应的催化剂的制备方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130403317948.html">CATALYST FOR OXYGEN REDUCTION REACTION COMPRISING POROUS CARBON NANOFIBER CO-DOPED WITH TRANSITION METAL AND NITROGEN AND PREPARATION METHOD THEREOF</a> <b>[P]</b> . <span> 外国专利：  KR20190022161A </span> <span> . 2019-03-06</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：含过渡金属和氮共混的多孔碳纳米纤维的氧还原反应催化剂及其制备方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022434319','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704022434319down" data-source="7," data-out-id="NoL6P0+DDIizETyJ3WQjyoNcKPpMOkiqoJF/to2T3lGByNT4yxFBNrXU0GXNmWAX," data-f-source-id="7" data-title="Nitrogen‐Doped Hierarchical Porous Carbon Architecture Incorporated with Cobalt Nanoparticles and Carbon Nanotubes as Efficient Electrocatalyst for Oxygen Reduction Reaction" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="18063" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Nitrogen‐Doped Hierarchical Porous Carbon Architecture Incorporated with Cobalt Nanoparticles and Carbon Nanotubes as Efficient Electrocatalyst for Oxygen Reduction Reaction"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.8"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.8"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.8"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>