Solvent‐Templated Block Ionomers for Base‐ and Acid‐Gas Separations: Effect of Humidity on Ammonia and Carbon Dioxide Permeation

Ansaloni Luca; Dai Zhongde; Ryan Justin J.; Mineart Kenneth P.; Yu Qiang; Saud Keara T.; H?gg May‐Britt; Spontak Richard J.; Deng Liyuan

摘要

Abstract > As energy needs continue to drive the development of biogas and fossil‐fuel technologies, methods by which to selectively remove basic (NH <sub>3</sub> ) and acidic (CO <sub>2</sub> ) gases are becoming increasingly important, especially in light of global climate change. Block copolymers are considered as suitable membrane candidates in gas separations due to the ability of such copolymers to microphase‐separate and spontaneously form nanoscale morphologies that exhibit spatially modulated chemical specificity. Incorporation of charged moieties along the midblock of a thermoplastic elastomeric multiblock copolymer yields an amphiphilic block ionomer possessing a flexible molecular network stabilized by rigid endblocks. The presence of hydrophilic microdomains introduces an important consideration regulating molecular transport: humidity. In this study, solvent‐templating paradigms are employed to control the morphologies of midblock‐sulfonated pentablock ionomers, as discerned by electron microscopy and X‐ray scattering. The effect of humidity on the permeation of NH <sub>3</sub> , CO <sub>2</sub> , and N <sub>2</sub> is then investigated through the resulting membranes. As expected, NH <sub>3</sub> permeates significantly faster than N <sub>2</sub> , especially under humid conditions. Although not as pronounced, similar behavior is observed for CO <sub>2</sub> , thereby establishing that this block ionomer is generally selective to humidified polar gases. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 随着能源需求不断推动沼气和化石燃料技术的发展，可以选择性地去除基本的方法（NH <sub> 3 </ sub> ）和酸性（CO <sub> 2 </ sub> ）气体变得越来越重要，特别是在全球气候变化。由于这种共聚物与微相和自发地形成纳米级形态的能力，嵌段共聚物被认为是气体分离中的合适膜候选。沿热塑性弹性体多嵌段共聚物的中间块掺入带电部分，得到两亲嵌段离聚物，其具有由刚性端口稳定的柔性分子网络。亲水性微米的存在引入了调节分子运输的重要考虑因素：湿度。在该研究中，使用溶剂模板范式来控制中块磺化的五才聚合物离聚物的形态，如电子显微镜和X射线散射辨别。湿度对NH渗透的影响 <sub> 3 </ sub> ，CO. <sub> 2 </ sub> 和n <sub> 2 </ sub> 然后通过所得膜研究。正如预期的那样，NH <sub> 3 </ sub> 渗透得明显快于n <sub> 2 </ sub> ，特别是在潮湿的条件下。虽然没有像明显的那样明显的，但有效的类似行为 <sub> 2 </ sub> 因此，建立该嵌段离聚物通常是选择性的，以潮湿的极性气体。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-18063/'>《Advanced materials interfaces》</a> <b style="margin: 0 2px;">|</b><span>2017年第22期</span><b style="margin: 0 2px;">|</b><span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ansaloni Luca&option=202" target="_blank" rel="nofollow">Ansaloni Luca;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dai Zhongde&option=202" target="_blank" rel="nofollow">Dai Zhongde;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ryan Justin J.&option=202" target="_blank" rel="nofollow">Ryan Justin J.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mineart Kenneth P.&option=202" target="_blank" rel="nofollow">Mineart Kenneth P.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yu Qiang&option=202" target="_blank" rel="nofollow">Yu Qiang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Saud Keara T.&option=202" target="_blank" rel="nofollow">Saud Keara T.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=H?gg May‐Britt&option=202" target="_blank" rel="nofollow">H?gg May‐Britt;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Spontak Richard J.&option=202" target="_blank" rel="nofollow">Spontak Richard J.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Deng Liyuan&option=202" target="_blank" rel="nofollow">Deng Liyuan;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemical EngineeringNorwegian University of Science and TechnologyTrondheim 7491 Norway;</p> <p>Department of Chemical EngineeringNorwegian University of Science and TechnologyTrondheim 7491 Norway;</p> <p>Department of Materials Science and EngineeringNorth Carolina State UniversityRaleigh NC 27695 USA;</p> <p>Department of Chemical and Biomolecular EngineeringNorth Carolina State UniversityRaleigh NC 27695 USA;</p> <p>Department of Chemical EngineeringNorwegian University of Science and TechnologyTrondheim 7491 Norway;</p> <p>Department of Materials Science and EngineeringNorth Carolina State UniversityRaleigh NC 27695 USA;</p> <p>Department of Chemical EngineeringNorwegian University of Science and TechnologyTrondheim 7491 Norway;</p> <p>Department of Materials Science and EngineeringNorth Carolina State UniversityRaleigh NC 27695 USA;</p> <p>Department of Chemical EngineeringNorwegian University of Science and TechnologyTrondheim 7491 Norway;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/6960.html" title="特种结构材料">特种结构材料;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=block ionomer&option=203" rel="nofollow">block ionomer;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=carbon capture&option=203" rel="nofollow">carbon capture;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=charged polymer membrane&option=203" rel="nofollow">charged polymer membrane;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=gas separation membrane&option=203" rel="nofollow">gas separation membrane;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=thermoplastic elastomer&option=203" rel="nofollow">thermoplastic elastomer;</a> </p> <div class="translation"> 机译：块离聚物;碳捕获;带电聚合物膜;气体分离膜;热塑性弹性体; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022434008.html">Solvent‐Templated Block Ionomers for Base‐ and Acid‐Gas Separations: Effect of Humidity on Ammonia and Carbon Dioxide Permeation</a> <b>[J]</b> . <span> <a 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Pei Ma</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马培&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,马培</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jichun You&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Jichun You</a> <span> <a href="/conference-cn-2110/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第九届全国高聚物分子与结构表征学术讨论会 </a> <span> <span> . 2014</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020314896683.html">负载化离子液体用于酸性气体的分离</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张正敏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张正敏</a> <span> . 2008</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061203893777.html">用于酸性气体分离的可再生溶剂混合物</a> <b>[P]</b> . <span> 中国专利： CN104271219B </span> <span> . 2020.08.21</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120111625326.html">用于酸性气体分离的可再生溶剂混合物</a> <b>[P]</b> . <span> 中国专利： CN111974166A </span> <span> . 2020-11-24</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130427912753.html">Method and apparatus for extracting ethanol from ethanol-water solution, including mixing solution with first solvent, the first solvent includes sterilized fatty acid, solvent separation, solvent dissolving with carbon dioxide phase, and converting carbon dioxide into fifth order. Apper releases ethanol.</a> <b>[P]</b> . <span> 外国专利：  CL2009001960A1 </span> <span> . 2010-06-11</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：从乙醇-水溶液中提取乙醇的方法和装置，包括与第一溶剂的混合溶液，第一溶剂包括灭菌的脂肪酸，分离溶剂，将溶剂溶解在二氧化碳相中，并将二氧化碳转化为第五级。 Apper释放乙醇。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130416004521.html">Carbon dioxide selective permeation composite type zeolite separation membrane, production method thereof, and carbon dioxide selective permeation separation membrane element</a> <b>[P]</b> . <span> 外国专利：  JP5759786B2 </span> <span> . 2015-08-05</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：二氧化碳选择渗透复合型沸石分离膜，其生产方法和二氧化碳选择渗透分离膜元件 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130471275847.html">method for separation of pure and pure carbon dioxide from a ausgangsgemisch ammonia from ammonia, carbon dioxide and water</a> <b>[P]</b> . <span> 外国专利：  DE2748639C2 </span> <span> . 1986-09-25</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：从氨，二氧化碳和水中分离出奥氏体氨中纯净和纯净二氧化碳的方法 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022434008','4',7,2,1,'',this,24)" class="delivery" prompt="010401" 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