Anion Exchange at the Liquid/Solid Interface of Ultrathin Ionic Liquid Films on Ag(111)

Lexow Matthias; Heller Bettina S. J.; Maier Florian; Steinrück Hans‐Peter

摘要

Abstract > Thin ionic liquid (IL) films play an important role in many applications. To obtain a better understanding of the ion distribution within IL mixture films, we sequentially deposited ultrathin layers of two ILs with the same cation but different anions onto Ag(111), and monitored their dynamic behaviour by angle‐resolved X‐ray photoelectron spectroscopy. Upon depositing [C <sub>8</sub> C <sub>1</sub> Im][PF <sub>6</sub> ] on top of a wetting layer of [C <sub>8</sub> C <sub>1</sub> Im][Tf <sub>2</sub> N] at room temperature (RT), we found a pronounced enrichment of the [Tf <sub>2</sub> N] ? anions at the IL/vacuum interface, due to a rapid anion exchange at the IL/solid interface. In contrast, at 90?K, the [Tf <sub>2</sub> N] ? anions remain at the IL/solid interface. Upon heating, we observe a rearrangement of the cations between 140 and 160?K, such that the octyl chains preferentially point towards the vacuum. Above 170?K, the ions start to become mobile, and at 220?K, the anion exchange is completed, with the [Tf <sub>2</sub> N] ? anions enriched at the IL/vacuum interface in the same way as found for deposition at RT. The temperature range for the anion exchange corresponds well to glass transition temperatures reported in literature. We propose two driving forces to be cooperatively responsible for the replacement/exchange of [Tf <sub>2</sub> N] ? at the IL/solid interface and its enrichment at the IL/vacuum interface. First, the adsorption energy of [C <sub>8</sub> C <sub>1</sub> Im][PF <sub>6</sub> ] is significantly </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>摘要</标题> >薄离子液体（IL）薄膜在许多应用中起重要作用。为了更好地理解IL混合物膜内的离子分布，我们顺序地将两种IL的超薄层沉积在同一阳离子，但在Ag（111）上的不同阴离子，并通过角度分辨的X射线光电子能谱监测它们的动态行为。在[C <sub> 8 </ sub的润湿层的顶部上沉积[c <sub> 8 </ sub> c <sub> 1 </ sub>] > C <sub> 1 </ sub> IM] [TF <sub> 2 </ sub> n]在室温（RT），我们发现[TF <sub> 2 </ sub> n]的发音富集IL /真空接口处的</ sup>阴离子，由于IL / solid界面处的快速混乱。相反，在90Ω·k处，[tf <sub> 2 </ sub> n] Δb</ sup>阴离子保留在IL / solid界面处。在加热时，我们观察到140和160？K之间的阳离子的重新排列，使得辛基链优先朝向真空点。高于170？k，离子开始变动，并且在220？k处，完成阴离子交换，具有[TF <sub> 2 </ sub> n] </ sup>阴离子富集IL /真空界面以与室温沉积相同的方式。阴离子交换的温度范围对应于文献中报告的玻璃化转变温度。我们提出了两个驱动力，可以合作负责IL /固体界面处的[TF <sub> 2 </ sub> n] 及其富集在IL /真空界面的富集。首先，[C <sub> 8 </ sub> c <sub> 1 </ sub> im] [pf <sub> 6 </ sub>]的吸附能量显着 </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16300/'>《Chemphyschem: A European journal of chemical physics and physical chemistry》</a> <b style="margin: 0 2px;">|</b><span>2018年第22期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lexow Matthias&option=202" target="_blank" rel="nofollow">Lexow Matthias;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heller Bettina S. J.&option=202" target="_blank" rel="nofollow">Heller Bettina S. J.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Maier Florian&option=202" target="_blank" rel="nofollow">Maier Florian;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Steinrück Hans‐Peter&option=202" target="_blank" rel="nofollow">Steinrück Hans‐Peter;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Lehrstuhl für Physikalische Chemie 2Friedrich-Alexander-Universit?t Erlangen-NürnbergEgerlandstr. 3 91058 Erlangen Germany;</p> <p>Lehrstuhl für Physikalische Chemie 2Friedrich-Alexander-Universit?t Erlangen-NürnbergEgerlandstr. 3 91058 Erlangen Germany;</p> <p>Lehrstuhl für Physikalische Chemie 2Friedrich-Alexander-Universit?t Erlangen-NürnbergEgerlandstr. 3 91058 Erlangen Germany;</p> <p>Lehrstuhl für Physikalische Chemie 2Friedrich-Alexander-Universit?t Erlangen-NürnbergEgerlandstr. 3 91058 Erlangen Germany;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ionic liquids&option=203" rel="nofollow">ionic liquids;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=ion pairs&option=203" rel="nofollow">ion pairs;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silver&option=203" rel="nofollow">silver;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=wetting&option=203" rel="nofollow">wetting;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=X-ray photoelectron spectroscopy&option=203" rel="nofollow">X-ray photoelectron spectroscopy;</a> </p> <div class="translation"> 机译：离子液体;离子对;银;润湿;X射线光电子体光谱; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022114667.html">Anion Exchange at the Liquid/Solid Interface of Ultrathin Ionic Liquid Films on Ag(111)</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lexow Matthias&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Lexow Matthias,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Heller Bettina S. 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