Design, synthesis and application of chiral tetraoxacalix[2]arene[2]triazine‐based organocatalysts in asymmetric Michael addition reactions

机译：手性四氧基碱[2]芳烃[2]三嗪类有机催化剂的设计，合成及应用在不对称迈克尔加法反应中

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Abstract > A novel type of oxacalix[2]arene[2]triazine‐based organocatalysts for asymmetric Michael reactions are reported for the first time. Chiral subunits were attached to the heteroatom‐bridged calixaromatic platform by a reaction of ( R )‐ and ( S )‐1‐aminotetraline with tetraoxacalix[2]arene[2]triazine in both enantiomeric forms. To evaluate the catalytic efficiency of the novel organocatalysts, isobutyraldehyde reacted with various substituted and unsubstituted aromatic trans ‐β‐nitrostyrenes in tetrahydrofuran (THF), leading to Michael adducts in excellent yields and enantioselectivites (up to 97% yield and 99% ee). </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>摘要</ title> >一种新型的氧化碱[2] arene [2]非对称Michael的有机催化剂反应是第一次报告。通过（ R） - 和（ s / i>）-1- aminotetraline，具有四氧基alix [2]芳烃的反应，将手性亚基连接到杂原子 - 桥接的卡芯芳族平台上[2] 三嗪在映体形式中。为了评估新型有机催化剂的催化效率，异丁醛与四氢呋喃（THF）中的各种取代和未取代的芳族芳香族 - 反式 - β-硝化丁烯反应，导致Michael加合物以优异的产率和映射（高达97％）产量和99％EE）。 </ p> </ abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16290/'>《Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry》</a> <b style="margin: 0 2px;">|</b><span>2019年第4期</span><b style="margin: 0 2px;">|</b><span>共8页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Genc Hayriye Nevin&option=202" target="_blank" rel="nofollow">Genc Hayriye Nevin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ozgun Ummu&option=202" target="_blank" rel="nofollow">Ozgun Ummu;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sirit Abdulkadir&option=202" target="_blank" rel="nofollow">Sirit Abdulkadir;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Science Education Ahmet Kelesoglu Education FacultyNecmettin Erbakan UniversityKonya Turkey;</p> <p>Department of Chemistry Ahmet Kelesoglu Education FacultyNecmettin Erbakan UniversityKonya Turkey;</p> <p>Department of Chemistry Ahmet Kelesoglu Education FacultyNecmettin Erbakan UniversityKonya Turkey;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/4812.html" title="结构化学">结构化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=asymmetric synthesis&option=203" rel="nofollow">asymmetric synthesis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Michael addition&option=203" rel="nofollow">Michael addition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organocatalysis&option=203" rel="nofollow">organocatalysis;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=stereoselectivity&option=203" rel="nofollow">stereoselectivity;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=tetraoxacalix2arene2triazine&option=203" rel="nofollow">tetraoxacalix2arene2triazine;</a> </p> <div class="translation"> 机译：不对称合成;迈克尔加法;有机成分分析;立体溶胶;四氧化碱[2]芳烃[2]三嗪; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022113505.html">Design, synthesis and application of chiral tetraoxacalix[2]arene[2]triazine‐based organocatalysts in asymmetric Michael addition reactions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Genc Hayriye Nevin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Genc Hayriye Nevin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ozgun Ummu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ozgun Ummu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sirit Abdulkadir&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sirit Abdulkadir </a> <a href="/journal-foreign-16290/" target="_blank" rel="nofollow" class="tuijian_authcolor">Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry .</a> <span>2019</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：手性四氧基碱[2]芳烃[2]三嗪类有机催化剂的设计，合成及应用在不对称迈克尔加法反应中</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704020341369.html">Chiral tetraoxacalix[2]arene[2]triazine-based organocatalysts for Enantioselective Aldol reactions</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Genc Hayriye Nevin&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Genc Hayriye Nevin,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ozgun Ummu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ozgun Ummu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sirit Abdulkadir&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sirit Abdulkadir </a> <a href="/journal-foreign-30441/" target="_blank" rel="nofollow" class="tuijian_authcolor">Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry .</a> <span>2019</span><span>,第27期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：手性四氧化碱[2]芳烃[2]三嗪类有机催化剂用于对映选择性的醛醇反应</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070403439604.html">An Alternative Synthesis of Chiral (5)-Proline Derivatives that Contain a Thiohydantoin Moiety and Their Application as Organocatalysts in the Asymmetric Michael Addition Reaction under Solvent-Free Conditions.</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Alberto Vega-Penaloza&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Alberto Vega-Penaloza,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Omar Sanchez-Antonio&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Omar Sanchez-Antonio,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=C. Gabriela Avila-Ortiz&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">C. Gabriela Avila-Ortiz </a> <a href="/journal-foreign-19765/" target="_blank" rel="nofollow" class="tuijian_authcolor">Asian Journal of Organic Chemistry .</a> <span>2014</span><span>,第4期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：包含硫代乙内酰脲部分的手性（5）-脯氨酸衍生物的替代合成及其在无溶剂条件下在不对称迈克尔加成反应中作为有机催化剂的应用。</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-252588_thesis/0705010370375.html">A Synthesis of Newly Designed Polymer-supported Chiral Catalyst and Its Application to Highly Stereoselective Asymmetric Cyclopropanation Reactions</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=A. Mohamed Abu-Elfotoh&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">A. Mohamed Abu-Elfotoh,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kesiny Phomkeona&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kesiny Phomkeona,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kazutaka Shibatomi&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Kazutaka Shibatomi </a> <a href="/conference-foreign-252588/" target="_blank" rel="nofollow" class="tuijian_authcolor">Symposium on Organometallic Chemistry .</a> <span>2008</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：新设计的聚合物支持的手性催化剂的合成及其在高度立体选择性不对称环丙烷反应中的应用</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061130952.html">Part I. Asymmetric synthesis of bicyclic analogues of risedronate as molecular probes of the mechanism of action of bisphosphonate antiosteoporotic drugs and potentially more efficacious antiosteoporotic agents. Part II. Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using the Bestmann ylide and their use in Wittig reactions. Part III. Asymmetric organocatalysis: 1. An investigation of alpha-hydroxylation of aldehydes; 2. Synthesis of a novel camphor-based alpha-aminotetrazole organocatalyst.</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song, Xinyi.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Song, Xinyi. </a> <span>2007</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：第一部分：利塞膦酸盐双环类似物的不对称合成，作为双膦酸盐类抗骨质疏松药和潜在更有效的抗骨质疏松药作用机理的分子探针。第二部分使用Bestmann内酯从常见手性助剂轻松制备和官能化手性稳定化的叶基及其在Wittig反应中的用途。第三部分不对称有机催化：1.醛的α-羟基化研究； 2.合成新的基于樟脑的α-氨基四唑有机催化剂。</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040003500457.html">Synthesis of new pyrrolidine-based organocatalysts and study of their use in the asymmetric Michael addition of aldehydes to nitroolefins</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Alejandro Castán&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Alejandro Castán,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ramón Badorrey&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ramón Badorrey,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=José A Gálvez&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">José A Gálvez,</a> <span>2017</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：新型吡咯烷基有机催化剂的合成及其在醛不对称加成至硝基烯烃中的研究</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000126829928.html">Chiral Thiazolidine based Organocatalysts: Synthesis and Application in Asymmetric Aldol Reactions</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ana Rita G. Félix&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Ana Rita G. Félix,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Pedro R.D. Simões&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Pedro R.D. Simões,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Francisco J.P.M. Sousa&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Francisco J.P.M. Sousa,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：基于手性噻唑烷基的有机催化剂：在不对称醛醇反应中的合成和应用</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-synthetic-chemistry_thesis/0201234466398.html">新型手性双功能有机催化剂的合成及其催化不对称Henry反应合成(R)-aegeline</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宿亮&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 宿亮</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=匡永清&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,匡永清</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨昊宇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨昊宇</a> <span> <a href="/journal-cn-11569/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成化学 </a> </span> <span> . 2009</span><span>,第004期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-synthetic-chemistry_thesis/0201234460759.html">新型手性Schiff碱的合成及其在硫醚不对称氧化反应中的应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=唐红艳&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 唐红艳</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=曾庆乐&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,曾庆乐</a> <span> <a href="/journal-cn-11569/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 合成化学 </a> </span> <span> . 2010</span><span>,第005期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201231586161.html">金鸡纳生物碱衍生手性双胺配体的合成及其在不对称氢转移反应中的催化作用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=何炜&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 何炜</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张邦乐&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张邦乐</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=刘鹏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,刘鹏</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 2006</span><span>,第006期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-applied-chemistry_thesis/0201272090653.html">手性席夫碱-铜(Ⅱ)与-钒氧(Ⅱ)配合物的合成及其在不对称氧化反应中的应用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=周超&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 周超</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陆维敏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陆维敏</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=夏云超&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,夏云超</a> <span> <a href="/journal-cn-54377/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 应用化学 </a> </span> <span> . 2005</span><span>,第002期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201231593663.html">一种新型手性席夫碱的合成及其在不对称环丙烷化反应中的催化性能</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=李琛&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 李琛</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张维萍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,张维萍</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=姚小泉&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,姚小泉</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 2000</span><span>,第003期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-12010_thesis/02022526188.html">手性硫脲有机催化剂在催化不对称Michael加成反应中的应用</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=林鹏&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 林鹏</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=宋宝安&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,宋宝安</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨松&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,杨松</a> <span> <a href="/conference-cn-12010/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学会第三届全国分子手性学术研讨会 </a> <span> <span> . 2010</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313866406.html">二茂铁类手性膦硫脲有机催化剂的合成及其在不对称MBH反应中的应用研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=马鹏飞&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 马鹏飞</a> <span> . 2013</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061201009610.html">一类C<Sub>1</Sub>对称的手性二烯配体、合成方法及其在不对称反应中的应用</a> <b>[P]</b> . <span> 中国专利： CN101845056B </span> <span> . 2012.08.29</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120106028785.html">一类C<Sub>1</Sub>对称的手性二烯配体、合成方法及其在不对称反应中的应用</a> <b>[P]</b> . <span> 中国专利： CN101845056A </span> <span> . 2010-09-29</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130449572610.html">CHIRAL METALLIC CATALYST AND ASYMMETRIC MICHAEL ADDITION REACTION PROCESS OF THIOL</a> <b>[P]</b> . <span> 外国专利：  JP2001252567A </span> <span> . 2001-09-18</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：硫醇的手性金属催化剂与不对称迈克尔加成反应过程 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130422103390.html">Cinchona-based bifucntional organocatalysts and method for preparing chiral hemiesters by asymmetric ring opening reaction of meso-cyclic acid anhydrides using the same</a> <b>[P]</b> . <span> 外国专利：  KR101098335B1 </span> <span> . 2011-12-26</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：Cinchona基双功能有机催化剂和使用该催化剂的中环酸酐的不对称开环反应制备手性半酯的方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130421980166.html">MANUFACTURING METHOD OF CHIRAL GAMMA-NITROTHIOESTER THROUGH CATALYTIC ENANTIOSELECTIVE MICHAEL ADDITION REACTIONS WITH REMARKABLY HIGH OPTICAL SELECTIVITY AND YIELD</a> <b>[P]</b> . <span> 外国专利：  KR20120120683A </span> <span> . 2012-11-02</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：通过具有显着高的光学选择性和产率的催化对映选择性迈克尔加成反应制备手性γ-亚硝基硫酯 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022113505','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);">回到顶部</a> </li> <li class="shouye"> <a href="/">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html">关于掌桥</a></li> <li><a href="/help/helpmap.html">资源导航</a></li> <li><a href="/help/helpguide.html">新手指南</a></li> <li><a href="/help/helpcenter.html">常见问题</a></li> <li><a href="/sitemap.html">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704022113505down" data-source="7," data-out-id="e82YCPxJeWEPVH2UizxOayYZ8a0sw45G5JgpvsVJ8YK+m0bMOMTGBzBI+wa1oeaN," data-f-source-id="7" data-title="Design, synthesis and application of chiral tetraoxacalix[2]arene[2]triazine‐based organocatalysts in asymmetric Michael addition reactions" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="16290" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Design, synthesis and application of chiral tetraoxacalix[2]arene[2]triazine‐based organocatalysts in asymmetric Michael addition reactions"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.7"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.7"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.7"></script> </body> <script> $(function(){ var weiPuStatus = getCookie('WeiPuStatus'); if(weiPuStatus){ tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if((sourcetype ==1||sourcetype==4)&&inyn_provide_service_level!=4){ getJournal(); } }) </script> </html>