Decoration of 1,3-oxazole by alkyl substituents via CH activation (microreview)

Slobodyanyuk Evgeniy Yu.; Volochnyuk Dmitriy M.

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Decoration of 1,3-oxazole by alkyl substituents via CH activation (microreview)

机译：烷基取代基通过CH激活装饰1,3-氧唑（MicrooreView）

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Microreview describes recent advances in the synthesis of alkyl-substituted 1,3-oxazoles via CH activation reaction. The latest selected examples (2008-2018) on the synthesis of alkyl-substituted oxazoles by transition metal-catalyzed CH activation reactions as well as metalation with subsequent alkylation are summarized.

机译：MicroVevieView描述了通过CH活化反应合成烷基取代的1,3-氧唑的最新进展。总结了通过过渡金属催化的CH激活反应合成烷基取代的恶唑以及随后的烷基化的金属化的最新选择的实施例（2008-2018）。

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《Chemistry of heterocyclic compounds》 |2019年第3期|共3页
作者
Slobodyanyuk Evgeniy Yu.; Volochnyuk Dmitriy M.;
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Natl Acad Sci Ukraine Inst Organ Chem 5 Murmanska St UA-02660 Kiev Ukraine;

Natl Acad Sci Ukraine Inst Organ Chem 5 Murmanska St UA-02660 Kiev Ukraine;

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正文语种 eng
中图分类杂环化合物;
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1. Decoration of 1,3-oxazole by alkyl substituents via CH activation (microreview) [J] . Slobodyanyuk Evgeniy Yu., Volochnyuk Dmitriy M. Chemistry of heterocyclic compounds . 2019,第3期

机译：烷基取代基通过CH激活装饰1,3-氧唑（MicrooreView）
2. Synthesis of 4-Alkyl-2-aryl-1,3-oxazole[5,4-d]pyrimidine- 7(4H)-thiones and 6-Alkyl-2-aryl-1,3- oxazole[5,4-d]pyrimidin-7(6H)-ones from 2-Aroylamino-3,3-dichloroacrylonitriles [J] . A. P. Kozachenko, O. V. Shablykin, V. S. Brovarets Russian Journal of General Chemistry . 2012,第4期

机译：4-烷基-2-芳基-1,3-恶唑[5,4-d]嘧啶-7（4H）-硫酮和6-烷基-2-芳基-1,3-恶唑[5,4-d]的合成2-芳酰基氨基-3,3-二氯丙烯腈的] pyrimidin-7（6H）-ones
3. Substituent effects on singlet-triplet gaps and mechanisms of 1,2-rearrangements of 1,3-oxazol-2-ylidenes to 1,3-oxazoles [J] . Freeman F, Lau DJ, Patel AR, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第37期

机译：取代基对单线态-三重态态的影响以及1,3-恶唑-2-亚基1,2-重排列为1,3-恶唑的机理
4. Effect on the 2-Heteroaryl Substituents as a Directing Group for thePalladium-catalyzed C-H Activation Arylation of Azulenes at the 1,3-Positions [C] . Yoshihiro Ogasawara, Takuya Nagasawa, Tomoaki Yatsu 日本化学会春季年会 . 2020

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5. The cobalt-mediated [2+2+2] cycloaddition of alkynes to heterocycles: I. The total synthesis of (+/-)-strychnine II. The activation of pyridones, oxazoles, and thiazoles. [D] . Eichberg, Michael Joseph. 2001

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6. Nickel-Catalyzed Alkyl–Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds that Bear a Perfluoroalkyl Substituent [O] . Yufan Liang, Prof. Gregory C. Fu -1

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7. Influence of Donor and Acceptor Substituents in 1,3-Oxazole Derivatives and Their Anti-Cancer Activity [O] . Nataliya V Obernikhina 2019

机译：1,3-氧唑衍生物中供体和受体取代基的影响及其抗癌活性

Decoration of 1,3-oxazole by alkyl substituents via CH activation (microreview)

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