Boron Subphthalocyanines and Silicon Phthalocyanines for Use as Active Materials in Organic Photovoltaics

Grant Trevor M.; Josey David S.; Sampson Kathleen L.; Mudigonda Thanmayee; Bender Timothy P.; Lessard Beno?t H.

摘要

Abstract >Organic photovoltaics (OPVs) have experienced continued interest over the last 25?years as a viable technology for the generation of power. Phthalocyanines are among the oldest commercial dyes and have been utilized in some of the earliest examples of OPVs. In recent years, the use of boron subphthalocyanines (BsubPcs) and silicon phthalocyanines (SiPcs) has attracted a flurry of interest with some examples of fullerene‐free devices reaching power conversion efficiencies 8?%. Unlike other more common divalent phthalocyanines such as copper or zinc, BsubPcs and SiPcs contain additional axial groups that can easily be functionalized without significantly affecting the optoelectronic properties of the macrocycle. This handle facilitates our ability to tune the solid‐state arrangement and other physical characteristics such as solubility ultimately giving us the ability to improve the thin film processing and final device performance. This review covers recent studies on the development of BsubPcs and SiPcs for use as active materials in organic photovoltaics. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> >有机光伏（OPV）在过去的25年度经历了持续的兴趣？多年作为可行技术用于产生权力。酞菁是最古老的商业染料，并且已被用于OPV的一些最早的实例中。近年来，使用硼邻苯二氰苯胺（Bsubpcs）和硅酞菁（SIPCs）的使用吸引了一种感兴趣的富含富烯装置的例子，达到功率转化效率和 8？％。与其他更多常见的二价酞菁如铜或锌，BSUBPC和SIPC含有额外的轴向基团，其可以容易地官能化，而不会显着影响宏循环的光电性质。这种手柄有助于我们调整固态布置和其他物理特性，例如溶解度最终使我们能够改善薄膜处理和最终装置性能的能力。该综述涵盖了最近关于BSUBPC和SIPC的开发的研究，用作有机光伏中的活性材料。</ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16132/'>《Chemical record》</a> <b style="margin: 0 2px;">|</b><span>2019年第6期</span><b style="margin: 0 2px;">|</b><span>共20页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Grant Trevor M.&option=202" target="_blank" rel="nofollow">Grant Trevor M.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Josey David S.&option=202" target="_blank" rel="nofollow">Josey David S.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sampson Kathleen L.&option=202" target="_blank" rel="nofollow">Sampson Kathleen L.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mudigonda Thanmayee&option=202" target="_blank" rel="nofollow">Mudigonda Thanmayee;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bender Timothy P.&option=202" target="_blank" rel="nofollow">Bender Timothy P.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lessard Beno?t H.&option=202" target="_blank" rel="nofollow">Lessard Beno?t H.;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Department of Chemical and Biological EngineeringUniversity of Ottawa161 Louis Pasteur Ottawa Ontario K1N 6N5 Canada;</p> <p>Department of Chemical Engineering and Applied ChemistryUniversity of Toronto200 College Street Toronto Ontario M5S 3E5 Canada;</p> <p>Department of Chemical Engineering and Applied ChemistryUniversity of Toronto200 College Street Toronto Ontario M5S 3E5 Canada;</p> <p>Department of Chemical Engineering and Applied ChemistryUniversity of Toronto200 College Street Toronto Ontario M5S 3E5 Canada;</p> <p>Department of Chemical Engineering and Applied ChemistryUniversity of Toronto200 College Street Toronto Ontario M5S 3E5 Canada;</p> <p>Department of Chemical and Biological EngineeringUniversity of Ottawa161 Louis Pasteur Ottawa Ontario K1N 6N5 Canada;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Boron&option=203" rel="nofollow">Boron;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=subphthalocyanine&option=203" rel="nofollow">subphthalocyanine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silicon&option=203" rel="nofollow">silicon;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=phthalocyanine&option=203" rel="nofollow">phthalocyanine;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=organic&option=203" rel="nofollow">organic;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=photovoltaics&option=203" rel="nofollow">photovoltaics;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=fullerene-free&option=203" rel="nofollow">fullerene-free;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solar&option=203" rel="nofollow">solar;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cells&option=203" rel="nofollow">cells;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=non-fullerene&option=203" rel="nofollow">non-fullerene;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=acceptor&option=203" rel="nofollow">acceptor;</a> </p> <div class="translation"> 机译：硼;亚酞菁;硅;酞菁;有机;光伏;无烯酮;无太阳能;细胞;非富勒烯;受体; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022079987.html">Boron Subphthalocyanines and Silicon Phthalocyanines for Use as Active Materials in Organic 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tuijian_authcolor">,杨维清</a> <span> <a href="/journal-cn-9125/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 广州化工 </a> </span> <span> . 2014</span><span>,第015期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-32000_thesis/02022491367.html">CEL溶液中二磺酸基二邻苯二甲酰亚胺甲基酞菁锌的电子吸收和荧光光谱</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=彭亦如&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 彭亦如</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=薛金萍&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,薛金萍</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=黄剑东&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,黄剑东</a> <span> <a href="/conference-cn-32000/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第七届原子光谱分析学术报告会 </a> <span> <span> . 2000</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020312671541.html">含苯并二噻吩、异靛、苯并噻二唑、三苯胺的有机光伏材料的合成及性能研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=王长伟&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 王长伟</a> <span> . 2013</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061204752614.html">一种邻苯二氰衍生物及其制备方法、一种金属酞菁衍生物及其制备方法和应用</a> <b>[P]</b> . <span> 中国专利： CN109651197B </span> <span> . 2021.11.02</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120100503602.html">一种邻苯二氰衍生物及其制备方法、一种金属酞菁衍生物及其制备方法和应用</a> <b>[P]</b> . <span> 中国专利： CN109651197A </span> <span> . 2019-04-19</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130421780613.html">Preparation of silicon-containing compound for manufacture of photovoltaic cell, involves grinding silicon raw material containing silica, ferric oxide, phosphorus pentoxide, alumina and boron trioxide in presence of grinding media</a> <b>[P]</b> . <span> 外国专利：  DE102010023590A1 </span> <span> . 2011-12-15</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于制造光伏电池的含硅化合物的制备涉及在研磨介质存在下研磨包含二氧化硅，氧化铁，五氧化二磷，氧化铝和三氧化硼的硅原料。 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130424199952.html">Electrode e.g. anode, for lithium-ion battery, has active material comprising silicon, whose surface is grafted by organic group bonded to silicon by silicon-carbide bond, where organic group is unubstituted monovalent hydrocarbon</a> <b>[P]</b> . <span> 外国专利：  FR2955709A1 </span> <span> . 2011-07-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：电极例如用于锂离子电池的负极，其活性材料包含硅，其表面被碳-碳键结合到硅上的有机基团接枝，其中有机基团是无取代的一价烃 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130460829660.html">The organicity metal ceramic outrider material null which designates boron, nitrogen and silicon as</a> <b>[P]</b> . <span> 外国专利：  JPH0649767B2 </span> <span> . 1994-06-29</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：有机金属陶瓷外层材料null，表示硼，氮和硅为 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> 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