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Thermochromie und die Funktionsweise von Thermopapier

机译：热敏纸的热量和功能

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Zusammenfassung >Thermopapiere werden zum schnellen Ausdruck von Belegen eingesetzt. Sie enthalten ein thermochromes Dreikomponentengemisch aus Leukofarbstoff und einem sauren phenolischen Entwickler, eingearbeitet in einen langkettigen Alkohol, das Solvens. Der Entwickler ist wegen der Verkapselung des Leukofarbstoffs im Solvens nicht in der Lage, diesen zu protonieren und damit in seine farbige Form überzuführen. Erst durch Einwirkung von Hitze schmilzt das Solvens, wodurch die Farbreaktion des Entwicklers mit dem Leukofarbstoff erm?glicht wird. In diesem Beitrag werden thermochrome Dreikomponentengemische aus Kristallviolettlacton (CVL) als Leukofarbstoff, Alkylgallat als Entwickler und 1‐Tetradecanol als Solvens vorgestellt, die sich sehr gut dazu eignen, den Einfluss der L?slichkeit vom Entwickler im Solvens in Abh?ngigkeit der Alkylkettenl?ngendifferenz ihrer Moleküle auf das thermochrome Verhalten experimentell zu zeigen. Auch der Einfluss hoher bzw. geringer Solvensanteile auf den Farbkontrast wird deutlich. Wir untersuchen, weshalb hei?es Wasser Thermopapier schwarz f?rbt, hei?es ?l hingegen keine Farbreaktion ausl?st, womit die Thematik um thermochrome Gemische für die Schule in einen interessanten Kontext mit starkem Alltagsbezug gesetzt wird. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract type =“main”xml：lang =“de”> <标题类型=“main”XML：lang =“de”>摘要</ title> >热纸用于快速表达文件。它们含有来自Leuco染料和酸性酚类显影剂的热彩色三组分混合物，其掺入长链醇中，溶剂。由于在溶剂中的封装Leuco染料的封装，显影剂不能质子化它们，从而克服其彩色形状。只有通过热量的影响，溶剂熔体才能使显影剂与亮染料染料的颜色反应。在本文中，热量以晶体紫色内酯（CV1）的三分组分混合物作为光染料，作为显影剂和1-四癸醇作为溶剂的烷基酯，其非常适合于来自溶剂的影响溶剂中的显影剂取决于烷基链长度差，以实验显示其分子在热致变色行为上。高溶剂股对颜色对比的影响也很清楚。我们调查，这就是为什么黑色热水纸的原因，它 </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16109/'>《Chemie in Unserer Zeit》</a> <b style="margin: 0 2px;">|</b><span>2020年第3期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jonas Albert&option=202" target="_blank" rel="nofollow">Jonas Albert;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Rubner Isabel&option=202" target="_blank" rel="nofollow">Rubner Isabel;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Oetken Marco&option=202" target="_blank" rel="nofollow">Oetken Marco;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Institut für Chemie Physik Technik und ihre DidaktikenP?dagogische Hochschule FreiburgKunzenweg 21 D‐79117 Freiburg;</p> <p>Institut für Chemie Physik Technik und ihre DidaktikenP?dagogische Hochschule FreiburgKunzenweg 21 D‐79117 Freiburg;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/159.html" title="化学">化学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thermopapier&option=203" rel="nofollow">Thermopapier;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Thermochromie&option=203" rel="nofollow">Thermochromie;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Leukofarbstoff&option=203" rel="nofollow">Leukofarbstoff;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Kristallviolettlacton&option=203" rel="nofollow">Kristallviolettlacton;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Alkylgallat&option=203" rel="nofollow">Alkylgallat;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dreikomponentengemisch&option=203" rel="nofollow">Dreikomponentengemisch;</a> </p> <div class="translation"> 机译：热纸;Thermochromy;leuco染料;水晶紫色内酯;烷基芳酯;三组分混合物; </div> </li> <li> <span 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