A Cost‐Effective and Scaleable Approach for the In‐Situ Synthesis of Porous Carbon‐Coated Micrometer‐Sized AlSi Particles as Anode for Lithium‐Ion Batteries

Li Cheng; Li Xitao; Zheng Yan‐Zhen; Wu Jiaojiao; Ding Haiyang; Tao Xia

摘要

Abstract > Silicon is intensively investigated as one of the most promising lithium‐ion battery anode material due to its high theoretical capacity. Here, spherical micro‐sized porous AlSi coated by a carbon layer (AlSi@C) are fabricated from low‐cost commercial AlSi alloy by delicately controlling an acid etching period, followed by polymerization and carbonization. A small amount of residual Al is beneficial to maintain the spherical morphology and enhance the electrical conductivity of the AlSi anode. Profiting from the porous structure and carbon coating layer, micro‐sized porous AlSi@C exhibits a high initial coulombic efficiency of 84.2?%, delivers an initial specific discharge capacity of 1650?mA?h?g ?1 at a current density of 0.50?A?g ?1 , and still retains 824?mA?h?g ?1 after 300 cycles. This work provides a facile and scalable synthetic strategy for the preparation of porous Si‐based anode materials from low‐cost AlSi alloy, and it is expected to realize the industrialization of preparation of porous Si‐based anode materials. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 由于其高理论能力，硅集中被调查为最有前途的锂离子电池阳极材料之一。这里，通过精致地控制酸蚀刻周期，由低成本的商业Alsi合金制成碳层（Alsi @ C）的球形微尺寸多孔铝，然后通过聚合和碳化。少量残留的Al有利于保持球形形态，增强Alsi阳极的电导率。从多孔结构和碳涂层中兴起，微尺寸多孔Alsi @ C表现出高初始的库仑效率为84.2μm，初始特定放电容量为1650？m？？1 </ sup> 电流密度为0.50？a？g ？1 </ sup> ，并仍然保留824？H？G. ？1 </ sup> 300次循环后。该工作提供了一种容易和可扩展的合成策略，用于制备来自低成本Alsi合金的多孔Si的阳极材料，预计将实现多孔Si基阳极材料的制备的产业化。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16042/'>《ChemElectroChem》</a> <b style="margin: 0 2px;">|</b><span>2019年第9期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Cheng&option=202" target="_blank" rel="nofollow">Li Cheng;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Xitao&option=202" target="_blank" rel="nofollow">Li Xitao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zheng Yan‐Zhen&option=202" target="_blank" rel="nofollow">Zheng Yan‐Zhen;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wu Jiaojiao&option=202" target="_blank" rel="nofollow">Wu Jiaojiao;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ding Haiyang&option=202" target="_blank" rel="nofollow">Ding Haiyang;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tao Xia&option=202" target="_blank" rel="nofollow">Tao Xia;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Organic-Inorganic Composites College of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029 P. R. China;</p> <p>State Key Laboratory of Organic-Inorganic Composites College of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029 P. R. China;</p> <p>State Key Laboratory of Organic-Inorganic Composites College of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029 P. R. China;</p> <p>State Key Laboratory of Organic-Inorganic Composites College of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029 P. R. China;</p> <p>General Research Institute of Nonferrous MetalsBeijing 100088 P. R. China;</p> <p>State Key Laboratory of Organic-Inorganic Composites College of Chemical EngineeringBeijing University of Chemical TechnologyBeijing 100029 P. R. China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=AlSi alloy&option=203" rel="nofollow">AlSi alloy;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=composite materials&option=203" rel="nofollow">composite materials;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=lithium-ion batteries&option=203" rel="nofollow">lithium-ion batteries;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=porous structures&option=203" rel="nofollow">porous structures;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=silicon anode&option=203" rel="nofollow">silicon anode;</a> </p> <div class="translation"> 机译：Alsi合金;复合材料;锂离子电池;多孔结构;硅阳极; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022062016.html">A Cost‐Effective and Scaleable Approach for the In‐Situ Synthesis of Porous Carbon‐Coated Micrometer‐Sized AlSi Particles as Anode for Lithium‐Ion Batteries</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Cheng&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Cheng,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Xitao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Xitao,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zheng Yan‐Zhen&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zheng Yan‐Zhen,</a> <a href="/journal-foreign-16042/" target="_blank" rel="nofollow" class="tuijian_authcolor">ChemElectroChem .</a> <span>2019</span><span>,第9期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：一种成本效益和可扩展的方法，用于原位合成多孔碳涂覆的微米尺寸的Alsi颗粒作为锂离子电池的阳极</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704023799092.html">A novel approach to synthesize micrometer-sized porous silicon as a high performance anode for lithium-ion batteries</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jia Haiping&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jia Haiping,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zheng Jianming&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zheng Jianming,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Song Junhua&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Song Junhua,</a> <a href="/journal-foreign-25507/" target="_blank" rel="nofollow" class="tuijian_authcolor">Nano Energy .</a> <span>2018</span><span>,第期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：一种基于锂离子电池的高性能阳极合成微米尺寸多孔硅的新方法</span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-foreign_journal-power-sources_thesis/0204113722911.html">Novel design and synthesis of carbon-coated porous silicon particles as high-performance lithium-ion battery anodes</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhao Tianting&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhao Tianting,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zhu Delun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zhu Delun,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Wenrong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Li Wenrong,</a> <a href="/journal-foreign-1286/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of power sources .</a> <span>2019</span><span>,第Nova1期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：碳包覆多孔硅颗粒作为高性能锂离子电池阳极的新颖设计与合成</span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-274852_thesis/0705015243840.html">MONOLITHIC, FUSED SILICA PARTICLES AS TEMPLATES FOR THE SYNTHESIS OF HIERARCHICALLY POROUS CARBONS AND THEIR PERFORMANCE AS ANODE MATERIAL IN LITHIUM ION BATTERIES</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=P. 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱以华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,朱以华</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=赵寒青&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,赵寒青</a> <span> <a href="/journal-cn-57464/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 功能材料与器件学报 </a> </span> <span> . 2009</span><span>,第4期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-34008_thesis/020221010129.html">一种测试颗粒尺寸的方法</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=朱友益&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 朱友益</a> <span> <a href="/conference-cn-34008/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第五届全国颗粒制备与处理学术大会 </a> <span> <span> . 1997</span> </span> </div> </li> <li> <div> <b>7. </b><a 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secondary battery anode and lithium ion secondary battery</a> <b>[P]</b> . <span> 外国专利：  JP6412520B2 </span> <span> . 2018-10-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：用于锂离子二次电池负极材料，锂离子二次电池负极和锂离子二次电池的碳质包覆石墨颗粒 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130404932596.html">MANUFACTURING METHOD OF CARBONACEOUS COATED GRAPHITE PARTICLE, CARBONACEOUS COATED GRAPHITE PARTICLE, ANODE FOR LITHIUM ION SECONDARY BATTERY, AND LITHIUM ION SECONDARY BATTERY</a> <b>[P]</b> . <span> 外国专利：  JP2019019048A </span> <span> . 2019-02-07</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：碳包覆石墨颗粒，碳包覆石墨颗粒，锂离子二次电池的阳极和锂离子二次电池的制造方法 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130419178907.html">Cobalt oxide-carbon composite useful as anode material for lithium-based energy storage device, preferably e.g. lithium-ion battery, lithium polymer battery and lithium-ion capacitor, comprises carbon coated cobalt monoxide particles</a> <b>[P]</b> . <span> 外国专利：  DE102011057015A1 </span> <span> . 2013-06-27</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：氧化钴-碳复合材料可用作锂基储能装置的阳极材料，最好是例如锂离子电池，锂聚合物电池和锂离子电容器，包括碳涂层的一氧化钴颗粒 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" 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