CdS-Nanoparticles-Decorated Perpendicular Hybrid of MoS2 and N-Doped Graphene Nanosheets for Omnidirectional Enhancement of Photocatalytic Hydrogen Evolution

摘要

A new hierarchical nanoarchitecture with integration of multiple active materials has been developed for highly efficient hydrogen evolution reaction (HER), by decorating a perpendicular hybrid of MoS2 and N-doped graphene nanosheets with CdS nanoparticles. The unique architecture promoted light trapping and absorption for highly efficient light harvesting and photocarrier generation, and offered an unblocked electron transport pathway for rapid charge separation/transport to suppress charge recombination. Its high surface area and high density of active sites result in highly efficient utilization of photogenerated carriers for productive HER. Significantly, without using noble metals as co-catalysts, the photocatalysts demonstrated rapid HER rates as high as 5.01mmolh(-1)g(-1) under visible-light irradiation, which was approximately 25times that of pure CdS. The hydrogen production remained stable after a continued test for 30h, showing an exceedingly high performance and superior stability.