Structural Changes of Binary/Ternary Spinel Oxides During Ethanol Anaerobic Decomposition

摘要

Abstract > Several M‐modified iron oxides of the spinel family have proven to be effective electron and O 2? vectors for the production of hydrogen in the chemical‐loop reforming of bio‐alcohols. The present work is specifically focused on investigation of ethanol anaerobic decomposition over spinel oxides, which results in significant structural changes of the oxygen carrier material itself and corresponds to a first step of the chemical‐loop reforming process. In particular, a series of binary/ternary M‐modified ferrospinels were prepared by a co‐precipitation method and tested in terms of both redox properties and intrinsic catalytic activity in addition to a complex ex situ study that encompasses the solid‐state chemistry investigations of the fresh and reduced oxygen carrier materials. It was found that Co/Cu incorporation facilitates total/partial oxidation of ethanol, giving rise to high yields of H <sub>2</sub> , CO <sub> x </sub> , and H <sub>2</sub> O; whereas Mn incorporation predominantly favored dehydrogenation and condensation reactions, leading to the formation of acetaldehyde and acetone. In addition, the incorporation of Mn contributed to significantly reduce the amount of coke formed; however, it caused a lower intrinsic reducibility, which was explained by the formation of a thermodynamically stable and hardly reducible layer of Mn <sub> x </sub> Fe <sub> y </sub> O solid solution. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 尖晶石家族的几种M改良的氧化铁已被证明是有效的电子和o 2？</ sup> 生物醇化学回合中氢的生产载体。本作本作专门针对尖晶石氧化物的乙醇厌氧分解研究，这导致氧载体材料本身的显着结构变化，并对应于化学回路重整过程的第一步。特别地，通过共沉淀方法制备了一系列二元/三元M-修饰的铁螺旋藻，并且在氧化还原性能和内在催化活性方面进行测试，除了包括固态化学研究的复杂的EXITU研究新鲜和减少的氧气载体材料。发现CO / Cu掺入促进乙醇的总氧化，从而产生高产H. <sub> 2 </ sub> ，CO. <sub> x </ i> </ sub> 和h. <sub> 2 </ sub> O;虽然Mn掺入主要是有利于脱氢和缩合反应，导致乙醛和丙酮的形成。此外，Mn的掺入有助于显着减少所形成的焦炭量;然而，它引起了较低的内在还原性，这是通过形成热力学稳定的和难以降低的Mn <sub> x </ i> </ sub> Fe. <sub> Y </ I> </ sub> O固溶体。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem》</a> <b style="margin: 0 2px;">|</b><span>2017年第12期</span><b style="margin: 0 2px;">|</b><span>共12页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=alcohol decomposition&option=203" rel="nofollow">alcohol decomposition;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=iron&option=203" rel="nofollow">iron;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=reduction&option=203" rel="nofollow">reduction;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=spinel&option=203" rel="nofollow">spinel;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=transition metals&option=203" rel="nofollow">transition metals;</a> </p> <div class="translation"> 机译：酒精分解;铁;减少;尖晶石;过渡金属; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022057625.html">Structural Changes of Binary/Ternary Spinel Oxides During Ethanol Anaerobic Decomposition</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> </a> <a href="/journal-foreign-16041/" target="_blank" rel="nofollow" class="tuijian_authcolor">ChemCatChem .</a> <span>2017</span><span>,第12期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：乙醇厌氧分解期间二元/三元尖晶石氧化物的结构变化</span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704019216420.html">In Situ DRIFTS-MS Study of the Anaerobic Oxidation of Ethanol over Spinel Mixed Oxides</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Juliana Velasquez Ochoa&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Juliana Velasquez Ochoa,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Cristian Trevisanut&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Cristian Trevisanut,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jean-Marc M. 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