Improved Cyclohexane Oxidation Catalyzed by a Heterogenized Iron (II) Complex on Hierarchical Y Zeolite through Surfactant Mediated Technology

Van‐Dúnem Vanmira; Carvalho Ana P.; Martins Luísa M. D. R. S.; Martins Angela

摘要

Abstract > The hydrotris (pyrazol‐1‐yl) methane iron (II) complex [FeCl <sub>2</sub> (Tpm)] [Tpm=HC(C <sub>3</sub> N <sub>2</sub> H <sub>3</sub> ) <sub>3</sub> ] was successfully immobilized, by the incipient wetness impregnation method, in parent and hierarchical Y zeolite modified through surfactant mediated methodology using different bases (NH <sub>4</sub> OH, NaOH or TPAOH). The catalytic performance and recyclability of supported Fe complex was evaluated in the oxidation of cyclohexane with hydrogen peroxide to cyclohexanol and cyclohexanone under mild conditions and two distinct behaviors were observed: using commercial Y and modified Y with NaOH the complex is anchored mainly at the outer surface of the zeolite supports, resulting in high lixiviation after the first catalytic cycle. When NH <sub>4</sub> OH and TPAOH are used during the zeolite treatments the particular textural parameters exhibited by these two supports are able to effectively retain the complex molecules, resulting in a high recyclability observed after three consecutive cycles, especially when NH <sub>4</sub> OH treated zeolite was used as support. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 水溶式（吡唑-1-基）甲烷铁（II）复合物[FECL <sub> 2 </ sub> （TPM）] [TPM = HC（C <sub> 3 </ sub> N. <sub> 2 </ sub> H <sub> 3 </ sub> 的） <sub> 3 </ sub> 通过使用不同的碱基（NH <sub> 4 </ sub> 哦，naoh或tpaoh）。在将过氧化氢与环己醇的环己烷氧化中评价负载的Fe络合物的催化性能和可再循环性在温和条件下，观察到两个不同的行为：使用商业Y并用NaOH改性Y堆叠主要在外表面上锚定沸石载体中，在第一催化循环后导致高亮度。当NH. <sub> 4 </ sub> 在沸石处理期间使用oh和tpaoh，这两个支持物呈现的特定纹理参数能够有效地保留复杂的分子，从而在连续三个周期后观察到的高可回收性，特别是当nh时 <sub> 4 </ sub> OH处理的沸石用作载体。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-16041/'>《ChemCatChem》</a> <b style="margin: 0 2px;">|</b><span>2018年第18期</span><b style="margin: 0 2px;">|</b><span>共9页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Van‐Dúnem Vanmira&option=202" target="_blank" rel="nofollow">Van‐Dúnem Vanmira;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Carvalho Ana P.&option=202" target="_blank" rel="nofollow">Carvalho Ana P.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Martins Luísa M. D. R. S.&option=202" target="_blank" rel="nofollow">Martins Luísa M. D. R. S.;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Martins Angela&option=202" target="_blank" rel="nofollow">Martins Angela;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>ADEQ Instituto Superior de Engenharia de Lisboa IPLRua Conselheiro Emídio Navarro 1 1959-007 Lisboa Portugal;</p> <p>Centro de Química e Bioquímica and Centro de Química Estrutural Faculdade de CiênciasUniversidade de Lisboa1749-016 Lisboa Portugal;</p> <p>Centro de Química Estrutural Instituto Superior TécnicoUniversidade de LisboaAv. Rovisco Pais 1049-001 Lisboa Portugal;</p> <p>ADEQ Instituto Superior de Engenharia de Lisboa IPLRua Conselheiro Emídio Navarro 1 1959-007 Lisboa Portugal;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1186.html" title="物理化学（理论化学）、化学物理学">物理化学（理论化学）、化学物理学;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=scorpionate iron catalyst&option=203" rel="nofollow">scorpionate iron catalyst;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=hierarchical zeolite&option=203" rel="nofollow">hierarchical zeolite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=oxidation&option=203" rel="nofollow">oxidation;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=recyclable&option=203" rel="nofollow">recyclable;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=cyclohexane&option=203" rel="nofollow">cyclohexane;</a> </p> <div class="translation"> 机译：蝎铁催化剂;等级沸石;氧化;可回收;环己烷; </div> </li> </ul> </div> </div> <div class="literature cardcommon" id="literaturereference" style="display:none"> <div class="similarity "> <h3 class="all_title" id="enpatent111">引文网络</h3> <div class="referencetab clearfix"> <ul id="referencedaohang"> <li dataid="referenceul">参考文献</li> <li dataid="citationul">引证文献</li> <li dataid="commonreferenceul">共引文献</li> <li dataid="commoncitationul">同被引文献</li> <li dataid="tworeferenceul">二级参考文献</li> <li dataid="twocitationul">二级引证文献</li> </ul> </div> <div class="reference_details" id="referenceList"> <ul id="referenceul"></ul> <ul id="citationul"></ul> <ul id="commonreferenceul"></ul> <ul id="commoncitationul"></ul> <ul id="tworeferenceul"></ul> <ul id="twocitationul"></ul> </div> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704022057561.html">Improved Cyclohexane Oxidation Catalyzed by a Heterogenized Iron (II) Complex on Hierarchical Y Zeolite through Surfactant Mediated Technology</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Van‐Dúnem Vanmira&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Van‐Dúnem Vanmira,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Carvalho Ana P.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Carvalho Ana P.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Martins Luísa M. 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href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蔡光宇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,蔡光宇</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 1992</span><span>,第1期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201296795431.html">合成气在铁锰/沸石催化剂上合成低碳烯烃的研究 Ⅲ.碱改性ZSM-5沸石担载Fe-MnO催化剂的强碱作用及MnO助剂的作用</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐龙伢&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐龙伢</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈国权&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈国权</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蔡光宇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,蔡光宇</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 1990</span><span>,第6期</span> </span> </div> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-catalysis_thesis/0201295757006.html">合成气在铁锰/沸石催化剂上合成低碳烯烃的研究——Ⅰ.不同沸石分子筛担载Fe-MnO催化剂反应性能的考察</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=徐龙伢&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 徐龙伢</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=陈国权&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,陈国权</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=蔡光宇&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,蔡光宇</a> <span> <a href="/journal-cn-28399/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 催化学报 </a> </span> <span> . 1990</span><span>,第5期</span> </span> </div> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-58968_thesis/020222568502.html">Zn和过渡金属改性ZRP沸石催化剂上催化裂化汽油芳构化反应的研究</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=杨萍华&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 杨萍华</a> <span> <a href="/conference-cn-58968/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第十二届全国催化学术会议 </a> <span> <span> . 2004</span> </span> </div> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020315590563.html">12-磷钨酸铯盐催化剂上的丙烷氧化脱氢反应以及Cu-zeolite催化剂上的以分子氧为氧化剂的气相条件下苯羟基化反应的研究</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=张际哲&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . 张际哲</a> <span> . 2009</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/061202343649.html">使用N‑酰基氨基酸表面活性剂或对应的酸酐作为催化剂生产N‑酰基氨基酸表面活性剂的方法</a> <b>[P]</b> . <span> 中国专利： CN104640839B </span> <span> . 2017.02.15</span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06120107147893.html">使用N-酰基氨基酸表面活性剂或对应的酸酐作为催化剂生产N-酰基氨基酸表面活性剂的方法</a> <b>[P]</b> . <span> 中国专利： CN104640839A </span> <span> . 2015-05-20</span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130420332491.html">Use of iron(iii)-polymaltose complex compounds or iron(iii) complex compounds with an oxidation product of one or more maltodextrins in the preparation of a medicament for improving immune defence and/or brain performance in patients without iron deficiency anaemia or iron deficiency</a> <b>[P]</b> . <span> 外国专利：  IL185020A </span> <span> . 2013-10-31</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铁（iii）-聚麦芽糖复合物或铁（iii）复合物与一种或多种麦芽糊精的氧化产物在制备药物中的用途，所述药物用于改善无铁缺乏性贫血或铁缺乏症的患者的免疫防御和/或脑功能 </span> </p> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/patent-detail/06130406764289.html">process for preparing iron hydroxide (iii) and activated glucose syrup complexes, iron (iii) hydroxide complex and glucose syrup complexes, and pharmaceutical composition.</a> <b>[P]</b> . <span> 外国专利：  BR112017005614A2 </span> <span> . 2018-01-23</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：制备氢氧化铁（iii）和活性葡萄糖浆复合物的方法，氢氧化铁（iii）氢氧化物复合物和葡萄糖浆复合物以及药物组合物。 </span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/patent-detail/06130406781231.html">iron (iii) - b - ketoamide complex compounds or pharmaceutically tolerable salts thereof, process for producing iron (iii) complex compounds, use of iron (iii) complex compounds, drug containing iron (iii) complex compounds and composition containing complex iron compounds (iii)</a> <b>[P]</b> . <span> 外国专利：  BR112012023780A2 </span> <span> . 2018-07-24</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：铁（iii）-b-酮酰胺配合物或其药学上可接受的盐，制备铁（iii）配合物的方法，铁（iii）配合物的用途，含铁（iii）配合物的药物和包含配合物铁化合物的组合物（ iii） </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704022057561','4',7,2,1,'',this,24)" class="delivery" prompt="010401" 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